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REACTIONS WITH AMINO AND AMIDO COMPOUNDS 22-5 34. Gerneross, 0.s aad Bach, S.s Cdfegifow, 1922, 350-1; C. A... IT, 207:: Collegium, 1923 377-S5-
220 FORMALDEHYDE 97. SeieiEer, E, Trestle:, F.f sml Sehok, E., L cngeu, Ckm.t 41,1305-9 (192S); ft A., 23,2425. & Schiff, H., fler., 24,2130 ;iSGl. aSeMff)H.IJ9fir.l2S1lfiS6(15!fi:. IOOL StiilS, H„ jJn.i.t3».5!K6 W;. IQi. Schmihisg, 1L, 'to CnywCorp.) t\ S. Patent 1,989,625 (19353- 101 Schmidt, H-, to L G. Farlwaiadustrie, Ait.-Gs.;, U. 8. Patent!J91,438 (1931;. 3C3. M., U. S. Paten: 3,791,434 '1S3L IM, Sciuia, M., and Jarces, K.T Ber.r 34, 1504 ;I9)i;. 105. Sociere pour Îndustrie Chimique u Bale, French Patent 511,504 £1987). JOB. Soreason, B. E.f (to E. L du Pont de Xemours & Co., Inc.) U. S. Patent 2,201,927 (1940). 107. Soreran, S. P. L, Biockm. Z, 7,45-101 (1905); ft .4., 11388. 105. Sprung, M. tf., CteKfof tofacs, 26,29M3S (1940!. 309. M M p. 365. 110. Stodfcger, H., &r., 59,3019 • 192ft). 111. Supi, F. Tolfce Arobci Manufacturing Co.) l\ S, Patent 974,445 (1910). 332. Sutler, L, ,'ro Society of Chemical Industry in Basel), U. 3. Parent 2,038,143 (1937). 113. Talbot, W. F.;« Monsanto Chemical Co.-, t\ 3. Patent 2,260,239 (1941), 114. Theis31. R., and Otteas, E. F,, /, iw. las/tar CAem. Am., 35,33H7 (1940). 115. Theis, E. R., and Ottens, E. E, M, 36,32-37 (1941), 316, Thomas, A. W., Kelly, If. W., and Foster, S. B„ M>t 21,57-76 (1928). 117. ToEens, B., JSer^ I7fr S57 :iSK\ US. ioi(i.r p. 559- 119. Verelaigte Chemisehe Fabriken Kreidl, Heller t Co., French Patent 352,079 (1339). 120. Voisener, E,,Bull soc. dim., $\ 33, U9M214 (1905;; Oem. Zentr., MM, 1,90. 121. Wagner, L C, J, ira. Chem. Sot, 55,724 [1533). 122. Wagser, L C„ /6£tf.t 56, IS44 3934;. 123. Walker, J. FJbii., 55,2S21 "1933;. 324. Walter, G.f British Parent 2G2,14S '19271. 125. Walter, G., British Patent 2*4,273 192S - 126. Waker, G., British Patent 291,712 192S. 127. Wellington, C, and Tote, B.f for., 18,3295 (1SS5). 125. Werner, E. A„ J, Chem. Soc., HI. S44-S53 '1917). 129. Widmer, G.: and Fisch, W„ >o Cik Products Corp.) U. 3. Patent 2,197,357 • 194fli; 130.ffoa,AvBfP.l»f234M 1«6\ 131. Zdeny, L., and Gortner, S. A.t /, Biol Chemt) 90,42741 (19311.
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Formaldehyde Tank Cars. Courtesy B.
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Copyright, 1944, by REIXHOLD PUBLIS
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iv FORMALDEHYDE of the highest valu
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Introduction Formaldehyde chemistry
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Page o y GENERAL IxrRODrcTiON iii P
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Page CHAPTER IS. HEXAIIETHYLEXEIETR
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Early History of Formaldehyde FORMA
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FORMALDEHYDE Production of Formalde
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6 POEM ALDEHYDE 30-cm hard-glass tu
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_ 3, "Formaldehyde unit developed b
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10 FORMALDEHYDE hyde. A modern plan
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12 FORMALDEHYDE catalysts contain f
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14 FORMALDEHYDE decompose at temper
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18 FORMALDEHYDE comprising aluminum
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Chapter 2 Monomeric Formaldehyde Al
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20 FORMALDEHYDE u-av contain small
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22 FORMALDEHYDE turea from 25 to 12
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24 FORMALDEHYDE formaldehyde in ace
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2G FORMALDEHYDE polymerizes very sl
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Chapter 3 State of Dissolved Formal
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30 ' FORMALDEHYDE ethylene oxide wi
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32 FORMALDEHYDE cal equilibrium bet
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34 FORMALDEHYDE Skrabal and Leutner
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36 FORMALDEHYDE Equilibria of the f
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38 FORMALDEHYDE molecule is saturat
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40 FORMALDEHYDE develop measurable
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42 ' FORMALDEHYDE present in the mo
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44 FORMALDEHYDE formaldehyde (methy
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46 FORMALDEHYDE Toxicity: Physiolog
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Chapter 5 Physical Properties of Pu
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50 :H:O/J00 £. Solution 2.23 4.60
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50 FORMA UihlHYhi: by Natta. and Ba
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.32 FORMALDEHYDE Partial Pressure,
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54 FORMALDEHYDE Lacy 17 * has recen
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50 FORMALDEHYDE At temperatures bel
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Chapter 6 Distillation of Formaldeh
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60 FORMALDEHYDE and that the soluti
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62 FORMALDEHYDE was found to contai
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Chapter 7 Formaldehyde Polymers Pol
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60 FORMALDEHYDE true polyoxymethyle
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6S FORMALDEHYDE sodium sulfate, and
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70 FORMALDEHYDE formaldehyde soluti
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72 FORMALDEHYDE ance of a colorless
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74 FORMALDEHYDE centrationa the rea
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76 FORMALDEHYDE the vacuum concentr
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78 FORMALDEHYDE mately 0.1 to 0.3 p
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80 FORMALDEHYDE dehyde solution was
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S2 FORMALDEHYDE ingers studies of t
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Table .17, Proportion at "VidyaxymQ
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SB FORMALDEHYDE soluble solid diace
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ss FORMALDEHYDE gradually increases
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go FORMALDEHYDE sulfuric acid were
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92 FORMALDEHYDE molecules. This con
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94 FORMALDEHYDE temperature. Since
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96 FORMALDEHYDE are forming or evap
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9S FORMALDEHYDE of formaldehyde to
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100 FORMALDEHYDE sublimate in the f
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Chapter 8 ; Chemical Properties of
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104 FORMALDEHYDE modif}- the decomp
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106 FORMALDEHYDE Reactions of Forma
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IMS FORMALDEHYDE i-.n^ ;t!i a-i^-at
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Ha FORI! ALDEHYDE arid 'ii:„-":.;
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FORMALDEHYDE \V;:h a-motiii;, :orn^
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m FORMALDEHYDE Under anhydrous cond
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116 FORMALDEHYDE 34,1. G. Farbenind
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118 FORMALDEHYDE The effect of alka
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120 FORMALDEHYDE precipitates. Coll
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122 FORMALDEHYDE On heating solutio
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124 FORMALDEHYDE prepared it by gra
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126 FORMALDEHYDE By reaction of 960
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X2S FORMALDEHYDE On reaction of two
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130 FORMALDEHYDE methylene glycol d
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132 FORMALDEHYDE Although this acid
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134 FORMALDEHYDE evolved and carbon
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m FORMALDEHYDE References I. Anders
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Chapter 10 Reactions of Formaldehyd
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ttJSAUTiuivs WITH HYDROXY COMPOUNDS
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142 FORMALDEHYDE alcohol with forma
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144 FORMALDEHYDE that no stable con
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146 FORMALDEHYDE hydrogen halide, a
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148 FORMALDEHYDE Z, Backer, H. :..
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152 FORMALBEH YDE Pentaerythritol i
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] 54 FORMA LDEHYDB Pentaglyeerol ap
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lot; CH2OH),C-CHOH,Cf;CEtOH)8 FORMA
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15S FORM A L DEH YDE In the ease ox
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1,30 FORMALDEHYDE with cold concent
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104 FORMALDEHYDE indicated. rhi> re
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166 FORMALDEHYDE substituted phenol
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H3S FORMALDEHYDE The preparation an
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170 FORMALDEHYDE are slow to react
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172 FORMALDEHYDE produce methylene
Page 187 and 188: 174 FORMALDEHYDE The ether, dimethy
Page 189 and 190: i7G FORMALDEHYDE ratios, as would b
Page 191 and 192: ITS FORMALDEHYDE ami it- polviiueU-
Page 193 and 194: ISO FORMALDEHYDE HO^ /> - CH-OCaq)
Page 195 and 196: 1S2 FORMALDEHYDE On oxidation and h
Page 197 and 198: 154 FORMALDEHYDE ghieinol itseli ar
Page 199 and 200: l&e H 0 T FORMALDEHYDE O il a c / ^
Page 201 and 202: 1SS FORMALDEHYDE Phenols having thr
Page 203 and 204: 190 FORMALDEHYDE 27. Eanus, F., J.
Page 205 and 206: 192 FORMALDEHYDE Acids containing a
Page 207 and 208: 194 FORMALDEHYDE reaction which tak
Page 209 and 210: 190 FORMALDEHYDE era! hiji;rs. When
Page 211 and 212: 19S FORMALDEHYDE By oxidation with
Page 213 and 214: 200 FORMALDEHYDE cold reaction mixt
Page 215 and 216: 202 FORMALDEHYDE In the case of eth
Page 217 and 218: 204 FORMALDEHYDE *m \it.^:U:Z hi mt
Page 219 and 220: 200 FORMALDEHYDE In av^îu:, -econd
Page 221 and 222: 2QS FORMALDEHYDE Mixed methylene de
Page 223 and 224: •210 FORMALDEHYDE According to Ka
Page 225 and 226: 12 FORMALDEHYDE Tho t>*.:y:;.*:'k-
Page 227 and 228: 214 FORMALDEHYDE hy employing an ac
Page 229 and 230: 2IM FORMA LDEH YDE In the presence
Page 231 and 232: 21S FORMALDEHYDE On exposure TO dil
Page 233 and 234: 220 FORMALDEHYDE •with 4 or more
Page 235 and 236: 222 FORMALDEHYDE anism by which the
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Page 241 and 242: 22S FORMALDEHYDE Since strongly aci
Page 243 and 244: 230 FOEMALDBBYDE feolsble derivativ
Page 245 and 246: 232 HOCHjCi - j V / u H H CH2C! FOR
Page 247 and 248: 234 CHj CHa / \ FORMALDEHYDE CHs /
Page 249 and 250: 2m FORMALDEHYDE extremely stringent
Page 251 and 252: 23S FORMALDEHYDE silver aeervHde an
Page 253 and 254: 24.0 FORMALDEHYDE alcohol*. Moureu
Page 255 and 256: 242 FORMALDEHYDE Farbenindusnie pat
Page 257 and 258: Chapter 16 Detection and Estimation
Page 259 and 260: 24ti FORMALDEHYDE iiiriue :'-r vrr.
Page 261 and 262: *>JS FOIOIALBEHYD, t-,TîKêd «JJ
Page 263 and 264: 250 FORMALDEHYDE Beta-Naphthoi. Bet
Page 265 and 266: 252 FORMALDEHYDE bridle compounds o
Page 267 and 268: 254 FORMALDEHYDE 14. Dtoigts, G., C
Page 269 and 270: 250 FORMALDEHYDE Formaldehyde may a
Page 271 and 272: 23S FORMALDEHYDE analyzed, but shou
Page 273 and 274: 2u0 FORMALDEHYDE by Roniijn :: . Th
Page 275 and 276: 262 FORMALDEHYDE The following modi
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Page 279 and 280: 26G FORMALDEHYDE should be neutral
Page 281 and 282: 2i kS FORMALDEHYDE previously m^-ur
Page 283 and 284: 270 FORMALDEHYDE tioii of ike metha
Page 285 and 286: 272 FORMALDEHYDE insoluble material
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Chapter 18 Hexamethylenetetramine H
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27S FORMALDEHYDE show monobasic cha
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2S0 FORMALDEH YDE Reactions I and I
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2S2 FORMALDEHYDE 275"F 135 ; C/. By
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2S4 FORMALDEHYDE On ignition, it bu
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2S6 FORMALDEHYDE Physiological Prop
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2SS FORMA LDEH YDE base or ?JV :he
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290 FORMALDEHYDE Reaction* with Sul
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292 FORMA LDEH1 'BE erately concent
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294 FORMALDEHYDE acetone in boiling
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296 FORMALDEHYDE for 15 minute* wit
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298 FORMALDEHYDE approximately 0/2
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300 FORMALDEHYDE 35. D^v-jkv. -T. V
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Chapter 19 Uses of Formaldehyde, Fo
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304 ' FORMA LDEH YJj£ of both plan
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306 FORMALDEHYDE ent, resistant to
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305 FORMALDEHYDE Resins, joining wo
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310 FORMALDEHYDE has played an incr
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312 FORMA LB Ell 3 V D£ resin-like
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314 FORMALDEHYDE For example, it is
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316 FORMALDEHYDE ically involved in
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Chapter 20 Uses of Formaldehyde, Fo
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320 FORMALDEHYDE 12-24 hours-. Some
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322 FORMALDEHYDE has been utilized
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324 FORMALDEHYDE References 1. Baue
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326 FORMALDEHYDE soaking for four t
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32S FORMALDEHYDE colors is among th
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330 FORMALDEHYDE 7. Jones, H. I., !
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332 FORMALDEHYDE Tetranifcthylenedi
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334 FORMALDEHYDE 0. Rinser, F., :o
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33(3 FORMA LDEHYDE low dishes or on
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338 FORMALDEHYDE sistance and other
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340 FORMALDEHYDE complUhed by deriv
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M2 FORMALDEHYDE is reported thai t'
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344 FORMALDEHYDE References 1. Bore
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341) FORMALDEHYDE distilled water a
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34S FORMALDEHYDE high wet-strength
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350 FORMALDEHYDE a roll, after whic
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35*2 FORMA LDEH \ 'DK chloride "lit
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354 FORMALDEHYDE forming developers
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356 FORMALDEHYDE In addition, it is
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35S FORMALDEHYDE An entirely differ
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360 FORMALDEHYDE According to Seymo
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362 FORMALDEHYDE improved by an aci
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364 FORMALDEHYDE type because the p
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366* FORMALDEHYDE spiration can be
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36S FORMALDEHYDE itatrng bath which
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370 FORMALDEHYDE 39. Lantz, L. A.,
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Abel, JM 1S1 Acres, S. F., 125 Adam
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Lacy, B. S.t 54 Ladisck, C, 215 Lae
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IB, 1, Itotaf,!,! Ifflt,0,S i,! ife
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Ammonia, reaction, of formaldehyde
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Cyclic polymers, 65; 94-100 Tetraox
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Hydrocarbon gases, production from,
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Polyeondensation of simple, 112 Rea
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Lower polyoxymethylene glycols, 67-
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Aromatic hydrocarbons, 231-237 Dlar
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Latex, 355-356 Synthetic, 358 Salic
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,- T7 Dyes, 327-329 Embalming, 329-
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No. 35. Noxious Gases. By Yandell H
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