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formaldehyde - Sciencemadness Dot Org

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Lower polyoxymethylene glycols, 67-<br />

60<br />

Para<strong>formaldehyde</strong>, 69-77<br />

Appearance, 71-72<br />

Composition, 70-71<br />

Decomposition pressure, 72-75<br />

Early history, 69-70<br />

Heat of formation, 71<br />

Manufacture, 75-76<br />

Melting point, 72<br />

Odor, 71-72<br />

Production, mechanism of, 76-77<br />

Properties, 71-72<br />

Structure, 70-71<br />

Thermal decomposition, 72-75<br />

Thermochemistry, 71<br />

Polyoxymethylene diacetates, 82-86<br />

Preparation, 83-86<br />

Properties, 82-83, 84^85<br />

Structure, 82<br />

Polyoxymethylene dimethyl ethere,<br />

86-88<br />

Preparation, 88<br />

Properties, 86-88<br />

Structure, 86<br />

Polyoxymethylene glycol derivatives,<br />

81-82<br />

Tetraoxymethylene, 99-100<br />

Trioxane, 94-99<br />

Depolymerization, 98-99<br />

Heat of formation, 96<br />

Hydrolysis, 98-99<br />

Preparation, 99<br />

Properties;<br />

Physical, 95-96<br />

Physiological, 99<br />

Thermodynamic, 96-98<br />

Structure, 9-^-95<br />

Polymethylol phenols, methylol derivatives,<br />

168-169<br />

Polyoxymethylene diacetates, <strong>formaldehyde</strong><br />

polymers, 82-86<br />

Preparation, 83-86<br />

Properties, S2-S3, S4-S5<br />

Structure, S2<br />

Poiyoxymethylene dimethyl ethers,<br />

<strong>formaldehyde</strong> polymers, 86-SS, see<br />

also Gamma-polyoxymethylene<br />

Preparation, 88<br />

Properties, 86-88<br />

Structure, 86<br />

Poiyoxymethylene glycols:<br />

Derivatives, <strong>formaldehyde</strong> polymers,<br />

81-S2<br />

Lower, 67-69<br />

Conversion to para<strong>formaldehyde</strong>, 77<br />

SUBJECT IXDEX<br />

Potassium cyanide method, determining<br />

<strong>formaldehyde</strong>, 262-263<br />

Precautions, commercial solutions, -16-47<br />

Precipitation polymer, pure aqueous<br />

solutions, 56<br />

Preparation:<br />

Alpha-polyoxymethylene. 79-SO<br />

Delta-polyoxymethylene,' 91<br />

Eu-polyoxymetbylenc, 93-94<br />

Gamma-polyosymethylene, S9<br />

Liquid <strong>formaldehyde</strong>, 24-26<br />

Poiyoxymethylene diacetates, S3-S6<br />

Poiyoxymethylene dimethyl ethers, SS<br />

Trioxane, 99<br />

Preserving, use of <strong>formaldehyde</strong>, 329-330<br />

Pressure, see also Partial pressure<br />

Decomposition, para<strong>formaldehyde</strong>,<br />

72-75<br />

Distillation, 59-60<br />

Production, see also Manufacture<br />

Formaldehyde, 1-16<br />

From methane and other hydrocarbon<br />

gases, 13-16<br />

From methanol, £-12<br />

Present methods of manufacture, 3<br />

Para<strong>formaldehyde</strong>, 75-77<br />

Products treated with <strong>formaldehyde</strong>:<br />

Detection of <strong>formaldehyde</strong> in, 253<br />

Determination of combined <strong>formaldehyde</strong><br />

in, 273-274<br />

Determination of <strong>formaldehyde</strong> in,<br />

271-273<br />

Properties of <strong>formaldehyde</strong>:<br />

Alpha-polyoxymethylene, 78-79<br />

Chemical, 102-115<br />

Decomposition, 103-ftM<br />

Oxidation, 104-105<br />

Reactions:<br />

Formaldehyde with <strong>formaldehyde</strong>,<br />

106-10S<br />

Methylol derivatives, 113-115<br />

Polymerization, 112-113<br />

Type, 108-112<br />

Reduction, 104-105<br />

Stability, 103-104<br />

Commercial <strong>formaldehyde</strong> solution,<br />

40-42<br />

Epsilon-polyoxymethylene, 91<br />

Eu-polyosymethylene, 92-93<br />

Liquid <strong>formaldehyde</strong>, 23-24<br />

Magnetic, pure aqueous solutions, 51<br />

Physical;<br />

Aqueous solutions, pure, 4S-57<br />

Delta-polyoxymethylene, 90-91<br />

Gamma-polyosymethylene, 89<br />

Hexamethylenetetramine, 282-285

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