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formaldehyde - Sciencemadness Dot Org

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Polyeondensation of simple, 112<br />

Reactions of, 113-115<br />

Addition, 114<br />

Condensation -with other compounds,<br />

114<br />

Decomposition with liberation of<br />

<strong>formaldehyde</strong>, 113-114<br />

Dehydration to double-bonded<br />

methylene derivatives, 114<br />

Formaldehyde with phenols, 167-175<br />

Cresol, 169-170<br />

Phenol alcohols, 167-168<br />

Polyhydric phenols, 171-172<br />

Polymethylol phenols, 16S-169<br />

S&ligenin phenol^ 16S-169<br />

Xylenol derivatives, 169-170<br />

Polyeondensation, 114<br />

Reduction to methyl derivatives,<br />

114-115<br />

Methylolphenols, derivatives of, 172-175<br />

Monoamides, reactions of <strong>formaldehyde</strong><br />

with, 206-208<br />

Monomelic <strong>formaldehyde</strong>, 18-26<br />

Absorption spectra, 22-23<br />

Atomic structure, 22-23<br />

Gas, 18-20<br />

Heat capacity of, 20<br />

Heat of formation and free energy of;<br />

20-22<br />

Liquid <strong>formaldehyde</strong>:<br />

Preparation of, 24-26<br />

Properties of, 23-24<br />

N<br />

Naphthols, methylene derivatives, 180-<br />

1S1<br />

Nitration, reaction of hexametbylenetetraroine,<br />

288-289<br />

Nitric acid, reaction of <strong>formaldehyde</strong><br />

with, 134<br />

Nitro-hydroearhons, reactions of <strong>formaldehyde</strong><br />

with, 240-242<br />

Nitrophenols, methylene derivative^<br />

181-183<br />

Nitrous acid, reaction of <strong>formaldehyde</strong><br />

with, 134<br />

Non-polar solvents, solutions in, 23<br />

Novolaks, linear resins, 1S6-1S7<br />

O<br />

Odor:<br />

Alpha-polyoxymethylene, 78<br />

Para<strong>formaldehyde</strong>, 71-72<br />

Olefins, reactions of <strong>formaldehyde</strong> with,<br />

227-230<br />

Cyclo-, 227-230<br />

Halogenated, 230-231<br />

SUBJECT IXDEX 385<br />

<strong>Org</strong>anic compounds, reactions of he:-><br />

ameihylene-letramine with, 292-2&6<br />

<strong>Org</strong>anometallie hydrocarbon derivatives,<br />

reactions o: formal dehvde<br />

with, 23S-24Q<br />

Oxidation, 104-105<br />

Oxides, metal, reactions o; <strong>formaldehyde</strong><br />

with, 119<br />

p-Nixrophenylhydra^ine hydrochloride.<br />

identification of <strong>formaldehyde</strong>, 249<br />

Paper, use of <strong>formaldehyde</strong>, 347-351<br />

Coated papers, 349-350<br />

Direct treatment, 347-34$<br />

Indirect methods of treatment, 349<br />

Treatment with <strong>formaldehyde</strong> and<br />

proteins, 34S<br />

Para<strong>formaldehyde</strong>, <strong>formaldehyde</strong> polymer,<br />

69-77<br />

Appearance, 71-72<br />

Commercial, assay of, 270-271<br />

Composition, 70-71<br />

Decomposition pressure, 72-75<br />

Heat of formation, 71<br />

History, earl3% 69-70<br />

Lower polyoxymethyleiie glycols, conversion<br />

tOj 77<br />

Manufacture, 75-76<br />

Melting point, 72<br />

Odor, 71-72<br />

Production, 1<br />

Mechanism of, 76-77<br />

Properties, 71-72<br />

Structure, 70-71<br />

Thermal decomposition^ 72-75<br />

Thermochemistry j 71<br />

Partial pressure:<br />

Aqueous solutions, pure> 52-56<br />

Formaldehyde, 41—42<br />

Para<strong>formaldehyde</strong>, 72-75<br />

Pentaerythritol production, 151-153<br />

Pent&erythritol, reaction of <strong>formaldehyde</strong><br />

with, 141<br />

Peroxides, hydrogen, reaction of <strong>formaldehyde</strong><br />

with, 126-129<br />

Petroleum, hydrocarbon products from,<br />

purification and modification of, 334-<br />

335<br />

Phenol aleohols, 167-I6S<br />

Phenol-<strong>formaldehyde</strong> condensates> determination<br />

of <strong>formaldehyde</strong> inT 272<br />

Phenol-<strong>formaldehyde</strong> resins, 1S4-1S9<br />

Infusible, 1S7-1S8<br />

Linear, 1S6-1S7<br />

Novolaks, 186-1S7

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