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CHEM01200604012 Dibakar Goswami - Homi Bhabha National ...

CHEM01200604012 Dibakar Goswami - Homi Bhabha National ...

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III.2.1 cyclic TS for metal mediated crotylation of aldehyde 1 118<br />

IV.1.1 Structure of (R)-(-)-Arundic acid (V) 138<br />

IV.1.2<br />

IV.1.3.<br />

IV.1.4<br />

IV.1.5<br />

1 H NMR spectrum of compound 106 145<br />

13 C NMR spectrum of compound 106 145<br />

1 H NMR spectrum of compound 109 146<br />

13 C NMR spectrum of compound 109 146<br />

IV.2.1<br />

Precursor units for convergent synthetic approach to<br />

cryptophycins<br />

148<br />

IV.2.2<br />

IV.2.3<br />

IV.2.4<br />

IV.2.5<br />

IV.2.6<br />

IV.2.7<br />

IV.3.1<br />

IV.3.2<br />

IV.3.3<br />

1 H NMR spectrum of compound 131 158<br />

13 C NMR spectrum of compound 131 158<br />

1 H NMR Spectrum of compound 132b 159<br />

13 C NMR spectrum of compound 132b 159<br />

1 H NMR spectrum of compound 140 160<br />

13 C NMR spectrum of compound 140 160<br />

1 H NMR spectrum of compound 145 166<br />

1 H NMR spectrum of compound 146 166<br />

1 H NMR spectrum of compound 148 167<br />

IV.4.1 Structure of 2(S)-[1(S)-Azido-2phenylethyl]oxirane (VI) 169<br />

IV.4.2<br />

IV.4.3<br />

IV.4.4<br />

1 H NMR spectrum of compound 91a 174<br />

13 C NMR spectrum of compound 91a 174<br />

1 H NMR spectrum of compound VI 175<br />

IV.4.5.<br />

13 C NMR spectrum of compound VI 175<br />

IV.5.1 Structure of cis- and trans-Oak lactones 177<br />

xxv

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