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INAUGURAL–DISSERTATION zur Erlangung der Doktorwürde der ...

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List of Figures<br />

1.1 A schematic diagram of the spray drying process [3]. . . . . . . . . . . 2<br />

1.2 Chemical structure of polyvinylpyrrolidone (C 6 H 9 NO) n [8]. . . . . . . . 3<br />

1.3 SEM images of spray dried PVP [11]. . . . . . . . . . . . . . . . . . . . 4<br />

1.4 Chemical structure of mannitol (C 6 H 8 (OH) 6 ) [12]. . . . . . . . . . . . . 4<br />

2.1 Sketch of a pressure-atomized spray formation [69, 70]. . . . . . . . . . 11<br />

2.2 A typical log-normal distribution with different values of µ and σ. . . . 21<br />

2.3 Approximation of NDF in QMOM. . . . . . . . . . . . . . . . . . . . . 24<br />

2.4 NDF approximation in DQMOM. . . . . . . . . . . . . . . . . . . . . . 25<br />

2.5 Schematic diagram of stages in single droplet evaporation and drying. . 34<br />

2.6 Droplet breakup mechanisms based on Weber number [69, 178]. . . . . 41<br />

2.7 Droplet collision regimes: (a) bouncing, (b) coalescence [184]. . . . . . . 42<br />

2.8 Droplet collision regimes: (c) reflexive or crossing separation, (d) stretching<br />

separation [184]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42<br />

3.1 Flowchart of the DQMOM computational code. . . . . . . . . . . . . . 52<br />

4.1 Photograph of the water spray formation. . . . . . . . . . . . . . . . . . 56<br />

4.2 Schematic diagram of spray with measurement positions. . . . . . . . . 56<br />

4.3 Experimental surface frequency distribution at cross section 0.14 m (left)<br />

and 0.54 m (right) away from the nozzle exit. . . . . . . . . . . . . . . 57<br />

4.4 Comparison of simulated and measured [199] droplet mass and temperature<br />

profiles for the evaporation of a pure water droplet. . . . . . . . . 58<br />

4.5 Homogeneous and inhomogeneous calculations of DQMOM. . . . . . . 59<br />

4.6 Comparison of QMOM and DQMOM results with experiment. . . . . . 60<br />

4.7 Droplet size distribution of water spray and at t = 0 s, and at t = 1 s<br />

with d 2 law evaporation rate. . . . . . . . . . . . . . . . . . . . . . . . 60<br />

4.8 Velocity profiles of three droplets with different initial radii and velocities<br />

un<strong>der</strong> the influence of drag alone (left) and drag and gravity (right). . . 62<br />

4.9 Effect of liquid inflow rates on Sauter mean diameter computed with<br />

and without coalescence. . . . . . . . . . . . . . . . . . . . . . . . . . . 62

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