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APPENDIX A<br />

Classes of Hazardous Materials<br />

OXIDIZER<br />

FLAMMABLES<br />

CARCINOGEN<br />

POISON<br />

EXPLOSIVE<br />

CORROSIVE<br />

Proper segregation and storage of hazardous chemicals is challenging in a laboratory environment<br />

characterized by the presence of many different chemicals having multiple hazardous properties.<br />

Particular attention to proper segregation, storage and handling is warranted for materials labeled with<br />

extremely, highly or acutely, such as in “strong oxidizer”, “extremely flammable” or “highly toxic.”<br />

Table of Contents<br />

I. Acids………………………………………………………………….38<br />

II. Hydrofluoric Acid…………………………………………………….39<br />

III. Bases…………………………………………………………………..41<br />

IV. Solvents……………………………………………………………….42<br />

V. Oxidizers……………………………………………………………...44<br />

VI. Toxic Compounds…………………………………………………….46<br />

VII. Water Reactive Chemicals……………………………………………48<br />

VIII. Pyrophoric Substances………………………………………………..49<br />

IX. Cryogenic Fluids……………………………………………………...50<br />

X. Asphyxiant Gases……………………………………………………..52<br />

XI. Flammable Gases……………………………………………………..53<br />

XII. Toxic Gases…………………………………………………………...54<br />

XIII. Reactive or Explosive Chemicals…………………………………….57<br />

XIV. Carcinogens…………………………………………………………..59<br />

XV. Biohazardous Restricted "Select Agents"…………………………….62<br />

XVI. Appendices of useful information. ………………………………………….70<br />

XVII. Appendices example of a SOP……………………………………………….93<br />

(For additional information regarding chemical hazards, consult the on-line NIOSH Pocket Guide to<br />

Chemical Hazards at: www.cdc.gov/niosh/npg/pgintrod.html ).<br />

37

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