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Immediate Action Personal Protection Health • May be irritating to eyes, nose, throat, or case burns. • Poisonous if ingested. NOTIFY EH&S OF ANY RELEASE: • Beyond immediate work area • Causing personal injury • Use inside a fume hood. • Use appropriate chemical resistant gloves. • Use eye protection First Aid • In case of contact, flush skin or eyes with water for 15 minutes. • Remove and isolate contaminated clothing. • Move victim to fresh air. • If not breathing, give artificial respiration, if trained. Common Oxidizers: Chlorites Perchlorates Nitrates Chlorates Nitrites Oxidation Reactions These reactions tend to generate heat and are often explosive. The following examples of typical oxidizers may: Increase Rate of Combustion Aluminum Nitrate Ammonium Persulfate Barium Chlorate Barium Peroxide Calcium Chlorate Calcium Nitrate Calcium Peroxide Cupric Nitrate Hydrogen Peroxide Lead Nitrate Lithium Hypochlorite Lithium Peroxide Magnesium Nitrate Magnesium Perchlorate Magnesium Peroxide Nickel Nitrate Nitric Acid 70% or less Cause Spontaneous Ignition Calcium Hypochlorite Chromic Acid Hydrogen Peroxide (27.5-52%) Perchloric Acid 60% or less Potassium Chloriate Potassium Dichromate Potassium Nitrate Potassium Persulfate Silver Nitrate Silver Nitrite Sodium Perborate Sodium Perchlorate Sodium Persulfate Strontium chlorate Strontium nitrate Strontium nitrite Thorium nitrite Uranium nitrate Zinc chlorate Zinc peroxide Sodium Chlorite (40%) Sodium Peroxide Sodium Permanganate 44
Nitric Acid Potassium Bromate Potassium Permanganate Trichloroisocyanuric Acid Sodium Dichloroisocyanurate Decompose with Catalyst or Heat Ammonium Dichromate Hydrogen Peroxide (52-91%) Calcium Hypochlorite (>50%) Perchloric Acid (60-72.5%) Potassium Dichloroisocyanurate Sodium Dichloroisocyanurate Cause Explosive Reaction when exposed to Catalyst, Heat, Shock, or Friction Ammonium Perchlorate Perchloric Acid Ammonium Permanganate Potassium Superoxide VI. TOXIC COMPOUNDS Characteristics • Can be a solid, liquid or gas • Warning: These chemicals are dangerous or extremely dangerous to health and life when inhaled, swallowed, or absorbed by skin contact. Take proper precautionary measures to avoid exposure Storage Precautions Potential Hazards Immediate Action Personal Protection • Store according to hazardous nature of chemical, using appropriate security when necessary • Store in cool, dry, well-ventilated location Fire • May be ignited by sparks or flames Explosion • Container may explode due to heat or fire Health • Poisonous by inhalation, ingestion, or skin contact • May cause burns to skin or eyes NOTIFY EH&S OF ANY RELEASE: • Beyond immediate work area • Causing personal injury • Avoid breathing vapors • Avoid bodily contact • Wear appropriate chemical protective clothing • Handle only inside a fume hood First Aid • Move victim to fresh air • Remove and isolate contaminated clothing • In case of contact, flush skin or eyes with water for at least 15 minutes • Keep victim quiet and warm • If not breathing give artificial respiration • Keep victim under observation for delayed effects 45
Page 2 and 3: Table of Contents 1 Safety Philosop
Page 4 and 5: 9.8 Odors in the lab:…………
Page 6 and 7: The staff at INRF/BiON also recogni
Page 8 and 9: • Gas Hazards Compressed gases po
Page 10 and 11: physical and chemical properties, t
Page 12 and 13: 5.2 Liquid Chemical Storage To prev
Page 14 and 15: ‣ Protective Gear (PPE) Protectiv
Page 16 and 17: Antimony, Arsenic, Barium, Berylliu
Page 18 and 19: ‣ Other Oxidizing Acids Nitric, a
Page 20 and 21: 8 Specific Hazardous Gases 8.1 Pyro
Page 22 and 23: 9.2 Building and lab Evacuations Al
Page 24 and 25: Chemical spills that occur outside
Page 26 and 27: * Response Procedures 1. In the eve
Page 28 and 29: 10. Alarms 10.1 Fire Alarms Appeara
Page 30 and 31: 11.4 INRF Laboratory Safety Map Int
Page 32 and 33: Building Number 321 is the INRF lab
Page 34 and 35: • Outside of the bottle is clean
Page 36 and 37: How to dispose of corrosive and oth
Page 38 and 39: I. ACIDS Characteristics • Typica
Page 40 and 41: Personal Protection • Be sure tha
Page 42 and 43: IV. SOLVENTS Characteristics • Ma
Page 46 and 47: Common Toxics: Solids Antimony Comp
Page 48 and 49: VIII. PYROPHORIC SUBSTANCES Charact
Page 50 and 51: Liquid helium 700 to 1 Liquid nitro
Page 52 and 53: XII. TOXIC GASES Characteristics
Page 54 and 55: XIII. REACTIVE OR EXPLOSIVE CHEMICA
Page 56 and 57: XIV. CARCINOGENS Characteristics
Page 58 and 59: XV. CDC SELECT AGENTS, USDA HIGH CO
Page 60 and 61: Bacillus anthracis Brucella abortus
Page 62 and 63: Personal Chemical Storage Personal
Page 64 and 65: Solid Solvent Waste The steel waste
Page 66 and 67: Sharpie Container Sharpie container
Page 72 and 73: Chemical Utensil & Hot Plates Some
Page 74 and 75: “ Solvent” Wet Bench Solvent be
Page 76 and 77: Eye Wash on “ Standard “ Wet Be
Page 78 and 79: Transporting Chemical Bottle When t
Page 80 and 81: Gas Detection System For Combustibl
Page 82 and 83: Inches of water Exhaust Alarm These
Page 84 and 85: Pollution Control Device INRF This
Page 86 and 87: Procedures / Steps Needed To Comple
Page 88 and 89: E. Dispose the HF/Silicone oil wast
Page 90 and 91: #3 Engineering Controls: Describe a
Page 92 and 93: #9 Decontamination and spill clean-
Page 95:
SAFETY COMPLIANCE FORM THIS FORM MU
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