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XIV. CARCINOGENS Characteristics • A substance or agent that causes cancer Storage Precautions Potential Hazards • A hazard warning sign incorporating the carcinogen symbol must be posted at all areas where carcinogens are used or stored • Segregate carcinogens • Consult with EH&S prior to handling • Store in cool, dry, well-ventilated location Consult MSDS for each chemical. Immediate Action Personal Protection First Aid NOTIFY EH&S OF ANY RELEASE: • Beyond immediate work area • Causing personal injury • The Standard Operating Procedures (SOP) outlines safety procedures that should be followed when working with carcinogens • Users of any regulated carcinogens are required to fill out a SOP and Supplemental Information Form for Chemicals Requiring Cal/OSHA Registration and submit the form to EH&S for review and approval. • Use only inside fume hoods and regulated areas. Notify EH&S of any exposures. Cal-OSHA Reportable Hazardous Chemicals: Scope: Applies to occupational settings where these chemicals are manufactured, processed, used, repackaged, released, stored or otherwise handled. Table 1: Must complete Supplemental Information Form for Chemical Requiring Registration with Cal-OSHA: If above % weight or Name volume 2-Acetylaminofluorene 1.0 4-Aminodiphenyl 0.1 Benzidine (and its salts) 0.1 3,3'-Dichlorobenzidine (and its salts) 1.0 4-Dimethylaminoazobenzene 1.0 alpha-Naphthylamine 1.0 beta-naphthylamine 0.1 4-Nitrosodimethylamine 1.0 N-Nitrosodimethylamine 1.0 beta-Propiolactone 1.0 bis-Chloromethyl ether 0.1 Methyl chloromethyl ether 0.1 Ethyleneimine 1.0 56
Table 2: May have to complete Supplemental Information Form for Chemical Requiring Registration with Cal-OSHA. Contact the Chemical Hygiene Officer at 824-5730 for assistance. Name If exposure occurring above: Acrylonitrile PEL 1 (2ppm) Asbestos PEL (0.1ff/cc 2 ) or 30 minute-excursion (1ff/cc) Benzene STEL 3 (5ppm) or PEL (1ppm) Cadmium PEL (5ug/m3) Beryllium any potential exposure Ethylene Dibromide any exposure level where composition > 0.1% 4 Ethylene Oxide STEL (5ppm) or PEL (1ppm) Formaldehyde STEL (2ppm) or PEL (0.75ppm) Inorganice Arsenic PEL (0.01mg/m3) Methylene Chloride STEL (125ppm) or PEL (25ppm) Methylenedianaline any potential exposure Vinyl Chloride STEL (5ppm) or PEL (1ppm) 1,3 Butadiene any exposure level where composition > 0.1% The list above only represents “regulated” carcinogens. There are however many other suspect carcinogens. For a complete list of all categories of carcinogens, go to the following Internet sites: • International Agency for <strong>Research</strong> of Cancer (IARC): http://monographs.iarc.fr/ENG/Classification/index.php. • National Toxicology Program (NTP): http://ehp.niehs.nih.gov/roc/toc10.html • National Institute of Occupational Health (NIOSH): http://www.cdc.gov/niosh/npotocca.html • FAQs about developing Standard Operating Procedures for carcinogens. 1 PEL Cal-OSHA permissible exposure limit 8-hour time weighted average. 2 ff/cc Friable fibers per cubic centimeter of air 3 STEL Cal-OSHA short-term exposure limit 15 minute. 4 % by weight or volume. 57
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Table of Contents 1 Safety Philosop
Page 4 and 5:
9.8 Odors in the lab:…………
Page 6 and 7: The staff at INRF/BiON also recogni
Page 8 and 9: • Gas Hazards Compressed gases po
Page 10 and 11: physical and chemical properties, t
Page 12 and 13: 5.2 Liquid Chemical Storage To prev
Page 14 and 15: ‣ Protective Gear (PPE) Protectiv
Page 16 and 17: Antimony, Arsenic, Barium, Berylliu
Page 18 and 19: ‣ Other Oxidizing Acids Nitric, a
Page 20 and 21: 8 Specific Hazardous Gases 8.1 Pyro
Page 22 and 23: 9.2 Building and lab Evacuations Al
Page 24 and 25: Chemical spills that occur outside
Page 26 and 27: * Response Procedures 1. In the eve
Page 28 and 29: 10. Alarms 10.1 Fire Alarms Appeara
Page 30 and 31: 11.4 INRF Laboratory Safety Map Int
Page 32 and 33: Building Number 321 is the INRF lab
Page 34 and 35: • Outside of the bottle is clean
Page 36 and 37: How to dispose of corrosive and oth
Page 38 and 39: I. ACIDS Characteristics • Typica
Page 40 and 41: Personal Protection • Be sure tha
Page 42 and 43: IV. SOLVENTS Characteristics • Ma
Page 44 and 45: Immediate Action Personal Protectio
Page 46 and 47: Common Toxics: Solids Antimony Comp
Page 48 and 49: VIII. PYROPHORIC SUBSTANCES Charact
Page 50 and 51: Liquid helium 700 to 1 Liquid nitro
Page 52 and 53: XII. TOXIC GASES Characteristics
Page 54 and 55: XIII. REACTIVE OR EXPLOSIVE CHEMICA
Page 58 and 59: XV. CDC SELECT AGENTS, USDA HIGH CO
Page 60 and 61: Bacillus anthracis Brucella abortus
Page 62 and 63: Personal Chemical Storage Personal
Page 64 and 65: Solid Solvent Waste The steel waste
Page 66 and 67: Sharpie Container Sharpie container
Page 72 and 73: Chemical Utensil & Hot Plates Some
Page 74 and 75: “ Solvent” Wet Bench Solvent be
Page 76 and 77: Eye Wash on “ Standard “ Wet Be
Page 78 and 79: Transporting Chemical Bottle When t
Page 80 and 81: Gas Detection System For Combustibl
Page 82 and 83: Inches of water Exhaust Alarm These
Page 84 and 85: Pollution Control Device INRF This
Page 86 and 87: Procedures / Steps Needed To Comple
Page 88 and 89: E. Dispose the HF/Silicone oil wast
Page 90 and 91: #3 Engineering Controls: Describe a
Page 92 and 93: #9 Decontamination and spill clean-
Page 95: SAFETY COMPLIANCE FORM THIS FORM MU
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