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E. Dispose the HF/Silicone oil waste a. Put the HF/Silicone oil into a plastic waster bottle. b. Clean the HF container with ~50 ml 5-10% of Simple green. c. Swirl and rinse the funnel with the same Simple green in the HF container. d. Rinse the HF container and the funnel with the de-ionized water. F. Fiber removal a. Remove the fiber from the de-ionized water container. b. Rinse the water container with the de-ionized water. 88
APPENDIX B READ AND REVIEW ANY APPLICABLE MANUFACTURER/VENDOR MATERIAL SAFETY DATA SHEET (MSDS) INFORMATION BEFORE DEVELOPING STANDARD OPERATING PROCEDURE AND PERFORMING WORK. PI Name: _____________________ Dept/Section Name of Work Unit:_____________________ Standard Operating Procedures for Hydrofluoric Acid #1 Scope of Work/Activity: State the process/operation/equipment that the SOP concerns. #2 Specific <strong>Safety</strong> and Environmental Hazards: State the specific hazard and consequences if procedure not followed to person, environment, or property. Review MSDS prior to working with any hazardous material. Acute effects of HF exposure include extreme respiratory irritation, immediate and severe eye damage and pulmonary edema. Skin, eye, or lung exposure to concentrated (~50%) HF solutions will cause immediate, severe, penetrating burns. Exposure to less concentrated solutions may have equally serious effects, but the appearance of symptoms can be delayed for up to 24 hours. If you are exposed to hydrofluoric acid seek medical attention immediately, even if you do not feel pain Pure HF etches glass. Secondary containment trays constructed of polypropylene must be used Check container compatibility at: http://www.coleparmer.com/techinfo/ChemComp.asp .Never use Hydrofluoric Acid when working alone or after hours. <strong>Lab</strong>el containers with contents and indicate: Corrosive. Wash contaminated areas and apply antidote on skin. Seek medical attention. 89
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Table of Contents 1 Safety Philosop
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9.8 Odors in the lab:…………
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The staff at INRF/BiON also recogni
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• Gas Hazards Compressed gases po
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physical and chemical properties, t
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5.2 Liquid Chemical Storage To prev
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‣ Protective Gear (PPE) Protectiv
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Antimony, Arsenic, Barium, Berylliu
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‣ Other Oxidizing Acids Nitric, a
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8 Specific Hazardous Gases 8.1 Pyro
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9.2 Building and lab Evacuations Al
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Chemical spills that occur outside
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* Response Procedures 1. In the eve
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10. Alarms 10.1 Fire Alarms Appeara
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11.4 INRF Laboratory Safety Map Int
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Building Number 321 is the INRF lab
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• Outside of the bottle is clean
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How to dispose of corrosive and oth
Page 38 and 39: I. ACIDS Characteristics • Typica
Page 40 and 41: Personal Protection • Be sure tha
Page 42 and 43: IV. SOLVENTS Characteristics • Ma
Page 44 and 45: Immediate Action Personal Protectio
Page 46 and 47: Common Toxics: Solids Antimony Comp
Page 48 and 49: VIII. PYROPHORIC SUBSTANCES Charact
Page 50 and 51: Liquid helium 700 to 1 Liquid nitro
Page 52 and 53: XII. TOXIC GASES Characteristics
Page 54 and 55: XIII. REACTIVE OR EXPLOSIVE CHEMICA
Page 56 and 57: XIV. CARCINOGENS Characteristics
Page 58 and 59: XV. CDC SELECT AGENTS, USDA HIGH CO
Page 60 and 61: Bacillus anthracis Brucella abortus
Page 62 and 63: Personal Chemical Storage Personal
Page 64 and 65: Solid Solvent Waste The steel waste
Page 66 and 67: Sharpie Container Sharpie container
Page 72 and 73: Chemical Utensil & Hot Plates Some
Page 74 and 75: “ Solvent” Wet Bench Solvent be
Page 76 and 77: Eye Wash on “ Standard “ Wet Be
Page 78 and 79: Transporting Chemical Bottle When t
Page 80 and 81: Gas Detection System For Combustibl
Page 82 and 83: Inches of water Exhaust Alarm These
Page 84 and 85: Pollution Control Device INRF This
Page 86 and 87: Procedures / Steps Needed To Comple
Page 90 and 91: #3 Engineering Controls: Describe a
Page 92 and 93: #9 Decontamination and spill clean-
Page 95: SAFETY COMPLIANCE FORM THIS FORM MU
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