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Exchangeable cations of the meadow-chestnut soils at the Dzhanybek<br />

Research Station in the Northern Caspian Region<br />

A. V. KOLESNIKOV<br />

Institute of Forest Research, Russian Academy of Sciences, 143030, Sovetskaya str., 21,<br />

Uspenskoe, Odintsovsky district, Moscow region, Russia.<br />

Contact e-mail: wheelwrights@rambler.ru, root@ilan.msk.ru<br />

The predominance of exchangeable Ca 2+ , Mg 2+ , and Na + in soils of arid regions is a<br />

well-known fact. The relationship between these cations in the soil adsorption complex<br />

(SAC) is determined by the content and chemical composition of soluble salts in the soil<br />

solution and by the values of the selectivity factors. This general regularity is well seen<br />

in the studied soils of solonetzic complexes in the semidesert zone of the northern<br />

Caspian region. The soil cover differentiation is related to the microtopography:<br />

microhighs are occupied by solonchakous solonetzes, and microlows are occupied by<br />

nonsaline meadow chestnut soils. In the solonchakous solonetzes, the portion of<br />

exchangeable Na + reaches 30 – 40% of the cation exchange capacity (CEC); in the<br />

meadow-chestnut soils, it does not exceed 1 – 2% of the CEC.<br />

The studies of the composition of the SAC in the soils of solonetzic complexes at the<br />

Dzhanybek Research Station were mainly focused on the solonchakous solonetzes, as<br />

the high percentage of exchangeable sodium in them was one of the factors exerting a<br />

negative effect on forest shelterbelts and crops grown in the course of the agroforest<br />

amelioration of this area. The SAC of meadow-chestnut soils was studied to a lesser<br />

extent.<br />

Our work is aimed at studying the composition of the SAC and the nature of the CEC in<br />

the meadow chestnut soils located in the microlows under virgin herbaceous vegetation<br />

and in the analogous soils located under artificially planted forest shelterbelts<br />

Taking into account that the main carriers of exchangeable cations are the organic<br />

matter and clay minerals, the humus content, particle-size distribution, and the<br />

mineralogical composition of the clay and fine silt fractions were determined. We made<br />

approximate calculations to estimate the contribution of these factors to the value of the<br />

effective CEC in the soils. The activity of Na + and the salt reserves were determined to<br />

characterize the level of the soil salinity<br />

The meadow-chestnut soils of the Dzhanybek Research Station are characterized by the<br />

eluvial-illuvial textural differentiation of the solonetzic type. It is supposed that<br />

solonetzic process took place in these soils at the earlier stages of their development.<br />

Later, the excessive salts and the adsorbed sodium were removed from these soils by the<br />

fresh water supplied with the snowmelt.<br />

In the virgin and ameliorated meadow-chestnut soils, the portions of exchangeable<br />

calcium and magnesium in the CEC reach 70–80 and 13–30%, respectively. The<br />

composition of exchangeable cations remains relatively stable in the entire profile. The<br />

exchangeable sodium percentage is less than 1%, and there are no indications of the<br />

current activity of solonetzic process in the profiles of meadow-chestnut soils.<br />

The research was supported by the Russian Foundation for Basic Studies (project 09-<br />

04-00030).<br />

Key words: salt-affected soils, soil salinization, soil adsorption complex, cation<br />

exchange in soils.<br />

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