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Changes of salt minerals of soil surface efflorescences in space and<br />

time: a case study in Hungary<br />

Géza SZENDREI* 1 , Tibor TÓTH 2 , Péter KOVÁCS-PÁLLFY 3 , Sándor SZAKÁLL 4<br />

1 Department of Mineralogy and Petrology, Hungarian Natural History Museum,<br />

Budapest, Hungary<br />

2 Research Institute for Soils Science and Agrochemistry, Hungarian Academy of<br />

Sciences, Budapest, Hungary<br />

3 Hungarian Geological Survey, Budapest, Hungary<br />

4 Department of Mineralogy and Petrology, University of Miskolc, Hungary<br />

*Corresponding author’s e-mail: szendrei@miner.nhmus.hu<br />

In the European prairie ecological division (term after Bailey 1996) mineralogical<br />

investigations of soil surface efflorescences have not been published. As there are more<br />

minerals with sodium sulphate or sodium carbonate chemical compositions, more<br />

details were expected from the mineralogical study than from the chemical<br />

compositions alone.<br />

176 spots were visited for surveying and characterizing salt minerals in soil surface<br />

efflorescences, and on 39 localities (at 29 villages) were found salt efflorescences<br />

between 1995-2005.<br />

The soil profiles were described and sampled by the Hungarian soil survey manual and<br />

were analysed by international standard methods. The salt minerals were mainly<br />

determined by X-ray diffractometry.<br />

There were differences in the geographical distributions of salt mineral associations in<br />

surface efflorescences: sulphate mineral associations were only found in salt affected<br />

areas West of the Danube and North of Tisza river. Other salt mineral associations:<br />

carbonate, carbonate-chloride, carbonate-sulphate and carbonate-sulphate-chloride<br />

minerals were found in Danube-Tisza interfluve and in Trans-Tisza river region. Except<br />

for gypsum, salt minerals were dominantly sodium salts, sodium-magnesium salt<br />

minerals were found only at one site.<br />

Concerning long-term changes in salt efflorescences more occurrences were recorded in<br />

the past (1817-1995) than at present (1995-2005): 107 sites compared to 39 spots. The<br />

extent of salt efflorescences became much less than they were in the past.<br />

The geographical distribution also changed, in the past more occurrences were observed<br />

in the Danube-Tisza interfluve and Nyírség region, and less in Hajdúság region than<br />

today, and sodium-carbonate minerals were more frequent.<br />

Attempts were made to observe short-term changes by repeated sampling (six sampling<br />

in 2001) at Nyírőlapos (Hortobágy). Only thenardite was determined in springtime. In<br />

addition to this, mineral gypsum, sodium carbonate minerals (mainly trona) were<br />

identified in summer, termonatrite, thenardite and halite in autumns were found. This is<br />

likely due to increasing salt concentrations in the solutions.<br />

The relationship between the chemical composition of groundwater and occurrence and<br />

nature of salt efflorescences has already been well-known. In our study we tried to find<br />

relationship of groundwater levels and the distribution of salt minerals in soil surface<br />

efflorescences.<br />

Reference Bailey, R. C. (1996): Ecosystem geography. New York. Springer.<br />

39

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