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Hydrogeology and Groundwater Quality of Highlands ... - USGS

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50 <strong>Hydrogeology</strong> <strong>and</strong> <strong>Groundwater</strong> <strong>Quality</strong> <strong>of</strong> Highl<strong>and</strong>s County, Florida<br />

27°30’<br />

27°15’<br />

27°00’<br />

HARDEE<br />

COUNTY<br />

21<br />

DESOTO<br />

COUNTY<br />

CHARLOTTE<br />

COUNTY<br />

POLK<br />

COUNTY<br />

Avon<br />

Park<br />

68<br />

54<br />

30<br />

30<br />

0.20<br />

54<br />

27<br />

63<br />

Sebring<br />

98<br />

5.3<br />

7.4<br />

76<br />

HIGHLANDS<br />

COUNTY<br />

17 45<br />

Lake<br />

Placid<br />

30<br />

69 0.20<br />

Figure 38. Generalized distribution <strong>of</strong> sulfate concentrations in water from the surficial aquifer.<br />

Concentrations <strong>of</strong> nitrate in groundwater underlying<br />

undeveloped areas generally are low, indicating that natural<br />

sources <strong>of</strong> nitrate do not contribute substantially to concentrations<br />

in groundwater. Nitrate concentrations <strong>of</strong> water samples<br />

underlying the Ocala National Forest in Lake <strong>and</strong> Marion<br />

Counties were less than 1.0 mg/L (Adamski <strong>and</strong> Knowles,<br />

2001). Water samples collected from the surficial aquifer<br />

beneath undeveloped l<strong>and</strong> at two sites in Polk <strong>and</strong> Highl<strong>and</strong>s<br />

Counties had concentrations <strong>of</strong> less than 0.002 mg/L (Tihansky<br />

<strong>and</strong> Sacks, 1997). Likely sources <strong>of</strong> nitrate in these undeveloped<br />

areas are usually organic matter in soils <strong>and</strong> atmospheric deposition.<br />

In central Florida, the concentration <strong>of</strong> nitrate in rainwater<br />

generally is less than 1.0 mg/L (Adamski <strong>and</strong> German, 2004).<br />

81°30’ 81°15’<br />

81°00’<br />

Kuhlman<br />

1.8<br />

7.0 2.1<br />

0.20<br />

87<br />

39<br />

40<br />

1.9<br />

7.1<br />

17<br />

16 2.0<br />

Archbold<br />

Biological<br />

Station<br />

29<br />

51<br />

2.0 51<br />

3.9<br />

Venus<br />

Base modified from U.S. Geological Survey digital data, 1:100,000, 1985<br />

Albers NAD projection 1983<br />

0<br />

0<br />

27<br />

44<br />

9.8<br />

Lorida<br />

0.23<br />

5 10MILES<br />

5 10KILOMETERS<br />

70<br />

98<br />

2.8<br />

GLADES<br />

COUNTY<br />

1.0<br />

36<br />

Brighton<br />

EXPLANATION<br />

SULFATE CONCENTRATION,<br />

IN MILLIGRAMS PER LITER<br />

< 10 10 - 29<br />

30 or greater<br />

30<br />

Cornwell<br />

OSCEOLA<br />

COUNTY<br />

OKEECHOBEE<br />

COUNTY<br />

30<br />

WELL – Number indicates<br />

sulfate concentration<br />

Other nutrients <strong>of</strong> interest in the study area are<br />

orthophosphate <strong>and</strong> phosphorus. Concentrations <strong>of</strong> dissolved<br />

orthophosphate in water from the surficial aquifer in Highl<strong>and</strong>s<br />

County ranged from 0.004 to 4.5 mg/L, with a median<br />

value <strong>of</strong> 0.027 mg/L. Phosphorous concentrations ranged from<br />

0.004 to 5.2 mg/L, with a median value <strong>of</strong> 0.016 mg/L (app. 3<br />

<strong>and</strong> table 3).<br />

Orthophosphate concentrations are typically low in the<br />

surficial aquifer because phosphate-bearing minerals are generally<br />

uncommon in the surficial aquifer (at least in the upper<br />

part). In addition, because <strong>of</strong> the ability <strong>of</strong> phosphate ions to<br />

sorb onto metal oxides, especially ferric <strong>and</strong> manganese oxyhydroxides,<br />

background concentrations in water greater than a<br />

0.87<br />

0.20

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