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Hydrogeology and Groundwater Quality of Highlands ... - USGS

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52 <strong>Hydrogeology</strong> <strong>and</strong> <strong>Groundwater</strong> <strong>Quality</strong> <strong>of</strong> Highl<strong>and</strong>s County, Florida<br />

0<br />

100<br />

20<br />

Magnesium<br />

40<br />

<strong>and</strong> chloride concentrations in water from the intermediate<br />

aquifer system are shown in figures 41 <strong>and</strong> 42. Specific<br />

conductance values for Highl<strong>and</strong>s County ranged from 66 to<br />

11,500 µS/cm, with a median value <strong>of</strong> 424 µS/cm. Chloride<br />

concentrations in water ranged from 3.8 to 3,770 mg/L, with a<br />

median value <strong>of</strong> 13 mg/L. Specific conductance <strong>and</strong> chloride<br />

concentrations were lowest primarily in the northwestern <strong>and</strong><br />

south-central parts <strong>of</strong> the county <strong>and</strong> highest in the southwestern<br />

<strong>and</strong> southeastern parts. Sulfate concentrations ranged<br />

from 0.12 to 111 mg/L, <strong>and</strong> hardness as CaCO3 (calcium<br />

carbonate) concentrations ranged from 17 to 1,200 mg/L.<br />

The median values for sulfate <strong>and</strong> hardness were 2.5 <strong>and</strong><br />

175 mg/L, respectively. Nitrate, orthophosphate, <strong>and</strong> phosphorus<br />

concentrations ranged, respectively, from 0.004 to less<br />

than 0.04 mg/L, 0.004 to 1.5 mg/L, <strong>and</strong> 0.003 to 1.6 mg/L.<br />

The highest values for specific conductance, chloride<br />

concentration, <strong>and</strong> water hardness (as CaCO3) in the intermediate<br />

aquifer system were obtained from a 500-ft deep<br />

well (well 22) in southern Highl<strong>and</strong>s County. These values<br />

also were the highest values reported from any aquifer in the<br />

county. The specific conductance <strong>of</strong> water from this well was<br />

80<br />

60<br />

PERCENT<br />

80<br />

100 0<br />

60<br />

40<br />

Calcium<br />

0<br />

20<br />

0<br />

Sulfate plus Chloride<br />

20<br />

20<br />

40<br />

60<br />

20<br />

40<br />

Sodium plus Potassium<br />

40<br />

60<br />

60<br />

80<br />

100<br />

0<br />

80<br />

80<br />

100<br />

100<br />

100<br />

100<br />

80<br />

80<br />

PERCENT<br />

100<br />

0<br />

Calcium plus Magnesium<br />

60<br />

60<br />

80<br />

40<br />

40<br />

60<br />

20<br />

20<br />

20<br />

40<br />

Carbonate plus Bicarbonate<br />

0<br />

40<br />

60<br />

11,500 µS/cm. Hardness <strong>and</strong> chloride concentrations were<br />

1,200 <strong>and</strong> 3,770 mg/L, respectively. Sulfate concentration,<br />

although not anomalously high, was 111 mg/L. The source <strong>of</strong><br />

this highly mineralized water is probably relict seawater that<br />

entered the intermediate aquifer system during Pleistocene<br />

age. This zone <strong>of</strong> mineralized water, probably trapped in strata<br />

<strong>of</strong> low permeability, has not been removed by the modern-day<br />

freshwater flow system.<br />

Upper Floridan Aquifer<br />

0<br />

20<br />

0<br />

100<br />

PERCENT<br />

80<br />

80<br />

The Upper Floridan aquifer is the most productive <strong>and</strong><br />

widely used aquifer in Highl<strong>and</strong>s County. In much <strong>of</strong> the<br />

county, water in the Upper Floridan aquifer generally meets<br />

FDEP primary <strong>and</strong> secondary drinking-water st<strong>and</strong>ards.<br />

However, more mineralized water is present at depth beneath<br />

the entire county. Chemical analyses <strong>of</strong> groundwater samples<br />

from wells completed in the Upper Floridan aquifer indicate<br />

differences in the ionic composition <strong>of</strong> water, <strong>and</strong> several<br />

chemical types <strong>of</strong> groundwater occur in the study area.<br />

60<br />

Sulfate<br />

40<br />

20<br />

100<br />

Chloride, Fluoride, Nitrate plus Nitrite<br />

Figure 40. Chemical composition <strong>of</strong> water from the intermediate aquifer system.<br />

0

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