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Hydrogeology and Groundwater Quality of Highlands ... - USGS

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0<br />

100<br />

20<br />

Magnesium<br />

40<br />

Measured total dissolved-solids values (app. 2, table 4)<br />

indicate that total dissolved solids in water in the Upper<br />

Floridan aquifer in Highl<strong>and</strong>s County ranged from 96 to<br />

1,050 mg/L, with a median value <strong>of</strong> 199 mg/L. Most calculated<br />

total dissolved-solids values determined from specific<br />

conductance (fig. 33) also fell within this range. With the<br />

exception <strong>of</strong> the areas in the extreme southwestern <strong>and</strong><br />

extreme eastern Highl<strong>and</strong>s County, total dissolved-solids<br />

concentrations were below the 500-mg/L recommended<br />

FDEP limits.<br />

Chloride concentrations in the Upper Floridan aquifer<br />

in Highl<strong>and</strong>s County ranged from 4.4 to 403 mg/L (fig. 45,<br />

app. 2), with a median value <strong>of</strong> 12 mg/L (table 4). The lowest<br />

concentrations, less than 10 mg/L, generally occurred along<br />

the recharge area <strong>of</strong> the Lake Wales Ridge. Concentrations<br />

ranging from 26 to 250 mg/L occurred in the southwestern<br />

<strong>and</strong> eastern parts <strong>of</strong> the county. Chloride concentrations were<br />

below the 250-mg/L recommended limit for drinking water<br />

throughout most <strong>of</strong> the county, with the exception <strong>of</strong> the<br />

extreme southwestern <strong>and</strong> extreme eastern parts <strong>of</strong> the county.<br />

Bradner (1994) reported chloride concentrations greater than<br />

400 mg/L in Okeechobee County just east <strong>of</strong> Brighton, <strong>and</strong><br />

80<br />

60<br />

PERCENT<br />

80<br />

100 0<br />

60<br />

40<br />

Calcium<br />

0<br />

20<br />

0<br />

Sulfate plus Chloride<br />

20<br />

20<br />

40<br />

60<br />

20<br />

40<br />

Sodium plus Potassium<br />

40<br />

60<br />

60<br />

80<br />

100<br />

0<br />

80<br />

80<br />

100<br />

100<br />

100<br />

100<br />

80<br />

80<br />

PERCENT<br />

100<br />

0<br />

Calcium plus Magnesium<br />

60<br />

60<br />

80<br />

40<br />

40<br />

60<br />

20<br />

20<br />

20<br />

40<br />

Carbonate plus Bicarbonate<br />

0<br />

0<br />

20<br />

40<br />

Assessment <strong>of</strong> <strong>Groundwater</strong> <strong>Quality</strong> 55<br />

0<br />

100<br />

60<br />

PERCENT<br />

80<br />

60<br />

80<br />

Sulfate<br />

Klein <strong>and</strong> others (1964) reported chloride concentrations<br />

exceeding 1,000 mg/L in the extreme northeastern part <strong>of</strong><br />

Glades County.<br />

Chloride concentration <strong>of</strong>ten is used as an indicator to<br />

delineate the extent <strong>of</strong> saltwater intrusion within an area.<br />

Most <strong>of</strong> the mineralized water in the Upper Floridan aquifer<br />

in southeastern Highl<strong>and</strong>s County (<strong>and</strong> into Glades County)<br />

probably is a mixture <strong>of</strong> freshwater <strong>and</strong> relict seawater that<br />

entered the aquifer during a higher st<strong>and</strong> <strong>of</strong> sea level in the<br />

geologic past <strong>and</strong> has not been completely flushed from the<br />

aquifer. Natural salts <strong>of</strong> chloride (halite) are not present in the<br />

Upper Floridan aquifer (Sprinkle, 1989).<br />

Sulfate concentrations in the Upper Floridan aquifer in<br />

Highl<strong>and</strong>s County ranged from less than 0.18 to 255 mg/L<br />

(fig. 46, app. 2), with a median value <strong>of</strong> 23 mg/L (table 4).<br />

Concentrations <strong>of</strong> less than 10 mg/L generally occurred in the<br />

northwestern <strong>and</strong> west-central parts <strong>of</strong> the county <strong>and</strong> from<br />

30 to 250 mg/L in much <strong>of</strong> the western <strong>and</strong> eastern parts <strong>of</strong><br />

the county. Sulfate concentrations exceeded 250 mg/L in the<br />

extreme southeastern part <strong>of</strong> the county near the Kissimmee<br />

River, <strong>and</strong> possibly in the extreme western part <strong>of</strong> the county<br />

near the DeSoto/Hardee County line.<br />

40<br />

20<br />

100<br />

Chloride, Fluoride, Nitrate plus Nitrite<br />

Figure 43. Chemical composition <strong>of</strong> water from the Upper Floridan aquifer.<br />

0

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