from first principles PP-I-1

PP-III-48Nanosize Catalysis New Nanoscale Gas Molecular StructuresKibalnikova O.V.The Saratov State Technical University, 410054 Saratov Politechnic street 77,Saratov, Russiaokib@inbox.ruCatalytic system used in a computer chromatography has been examined. The sorbentrepresents the nanostructure composite with hard polymer electrolyte. Nanostructurepolymeric dendrimers were absorbed on the surface to form monolayer. Dendrimers promoteselective bind of substratum, resulting in increase efficiency and selectivity of the anchoredmetal complex catalysts [1,2]. At the research concentration of toluene and pyridine as sorbedgases (с= 4,45 • 10 -2 M/l, V=2 ml), the dimensional effect in properties of the catalyst activecomponent in formation of ionic tees is observed in the chromatography column. The reactionis thermodynamically forbidden. Experiment demonstrates that the size of a particle is thethermodynamic variable specifying system conditions. The size of a particle operates a role oftemperature [3]. Calculations show that the particle radius of sorbent initiating reactions attemperatures studied changes for toluene within r s =0,025÷2,24Å, and for pyridiner s =1,48÷3,03 Å. At some temperatures the spin catalysis can be observed, which stimulates atriplet-singlet conversion of radical pair. The hypothesis on the triplet nature ofparamagnetism in conducting polymers [4, 5, 6] is supported. At volume change of tolueneadsorbed (с=4,45 • 10 -2 M/l, = 0,5 ml; ΔG