from first principles PP-I-1

PP-IV-2Transition Metal Peroxo Complexes as Catalysts for Chemo- andStereoselective Sulfides OxidationBaleeva N.S., Anisimov A.V., Rakhmanov E.V.Lomonosov Moscow State University, Department of Chemistry, Moscow, RussiaDyuha-89@yandex.ruThe synthesis V- and Mn- complexes with pyridincontaining ligands has been carried outfrom corresponding ligands and metal salts in water solutions according with followingscheme:R 1ONOR 1R 2OHHOR 2VMnR 1OHNNOVHNOR 1R 1OHNNClMnHNOR 1R 2 OO R 2R 2 OO R 2A BThose complexes were applied at catalysts for chemo- and stereoselective oxidation of modelsulfide to corresponding sulfoxides:A,B complexesPh CH Ph CH 3 3S SH 2O 2OThe structures of complexes and oxidation products were supported by NMR andmass-spectrometry methods.This work was supported by RFBR grant №12-03-00260.286