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Dissolved organic matter in water of Daugava river

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Structural Investigation <strong>of</strong> Novel Organic Materials with PhotophysicalPropertiesS.Belyakov* 1 , A.Yanychev 2 , M.Fleisher 11 Latvian Institute <strong>of</strong> Organic Synthesis, Riga, Latvia;2 Riga Technical University, Riga, Latvia.e-mail: serg@osi.lvIn recent years a series <strong>of</strong> <strong>organic</strong> compounds with photophysical properties has beenstudied by means <strong>of</strong> X-ray diffraction and theoretical calculations. The molecular andcrystal structure <strong>of</strong> these compounds are <strong>in</strong>tensively <strong>in</strong>vestigated, because there are muchunexpected results. In this presentation the results <strong>of</strong> the follow<strong>in</strong>g <strong>in</strong>vestigations will bereported: molecular and crystal structures <strong>of</strong> 2-(4’-Dimethylam<strong>in</strong>o)-benzylydene-1,3-<strong>in</strong>dandione (DMABI) analogues, structure <strong>of</strong> 8-mercaptoqu<strong>in</strong>ol<strong>in</strong>e and 8-selenoqu<strong>in</strong>ol<strong>in</strong>ecomplexes conta<strong>in</strong><strong>in</strong>g metal atoms, structure <strong>of</strong> benzanthrone derivatives. Part <strong>of</strong> these<strong>in</strong>vestigations has been published earlier as orig<strong>in</strong>al articles [1-6]; the other part will bepresented for the first time.1. B Sil<strong>in</strong>a, E., Belyakov, S., Ashaks, J., Pecha, L., Zaruma, D. Tris(2-methylqu<strong>in</strong>ol<strong>in</strong>e-8-selenolatok1 N,Se)antimony (III). Acta Crystallogr. 2007, vol.63.,Sec.C. p. m62-m64.2. Belyakov, S., Kampars, V., Pastors, P.J., Tokmakov, A. 2-(4,5,6,7,8,9-Hexahydro-6aazaphenylen-2-ylmethylene)<strong>in</strong>dian-1,3-dione.Acta Crystallogr. 2008, vol.64.,Sec.E. p. o1200.3. Kirilova, E.M., Belyakov, S.V., Kirilov, G.K., Kaln<strong>in</strong>a, I., Gerbreder, V. Lum<strong>in</strong>escent propertiesand crystal structure <strong>of</strong> novel benzanthrone dyes. J. Lum<strong>in</strong>escence 2009, vol.129, p. 1827-1830.4. Sil<strong>in</strong>a, E., Belyakov, S., Ashaks, J., Pecha, L., Zaruma, D. Crystal structure <strong>of</strong> catena-poly[bis (8-mercaptoqu<strong>in</strong>ol<strong>in</strong>ato-N,S)disilver(I)], Ag 2 (C 9 H 6 NS) 2 . Zeitschrift für Kristallographie 2010,no.225. p. 211-212.- 12 -

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