16Foliar and Soil-Active HerbicidesArsenal ® AC (imazapyr)Arsenal ® PowerL<strong>in</strong>e (imazapyr)Chopper ® Gen2 (imazapyr)Clearcast ® (imazamox aquatic)Escort ® XP (metsulfuron)Habitat ® (imazapyr aquatic)Hyvar ® X-L (bromacil)Journey ® (imazapic + glyphosate)Milestone ® VM (am<strong>in</strong>opyralid)Outrider ® (sulfosulfuron)Overdrive ® (diflufenzopyr + dicamba)Pathway ® (2,4-D + picloram)Plateau ® (imazapic)Tordon ® 101 (2,4-D + picloram, Restricted use)Tordon ® K (picloram, Restricted use)Transl<strong>in</strong>e ® (clopyralid)Stalker ® (imazapyr)Vanquish ® (dicamba)Velpar L ® (hexaz<strong>in</strong>one)Because nonnative <strong>in</strong>vasive plants are usually difficult to control, select<strong>in</strong>g the most effective herbicide(s) is important.Often herbicides that have both soil and foliar activity are most effective with the least number of applications. However,apply<strong>in</strong>g herbicides with soil activity can damage desirable plants when their roots are present <strong>in</strong> the treatment zoneor when herbicides move downslope to untreated areas follow<strong>in</strong>g heavy ra<strong>in</strong>fall. Garlon herbicides are ma<strong>in</strong>ly foliaractive, but they have some soil activity at high rates or when mixed with oils. Garlon 4 and Vanquish can volatilizeor vaporize at high temperatures, and their residues can move by air currents to affect surround<strong>in</strong>g plants; there<strong>for</strong>e,avoid application of these herbicides on days when temperatures exceed 80 °F. Avoid applications when ra<strong>in</strong>fall isanticipated, unless soil activation is needed. Consult the label <strong>for</strong> the ra<strong>in</strong>fast period. Delay applications dur<strong>in</strong>g severedrought because herbicides are not as effective when plants go <strong>in</strong>to stress dormancy dur<strong>in</strong>g dry periods.When possible, use selective herbicides that target specific nonnative species, e.g., Transl<strong>in</strong>e, which controls ma<strong>in</strong>lylegumes and composites and m<strong>in</strong>imizes damage to surround<strong>in</strong>g desirable plants even though they receive herbicidecontact. M<strong>in</strong>imiz<strong>in</strong>g damage to desirable plants also can be achieved by mak<strong>in</strong>g applications when they are dormant.For example, apply basal sprays to the bark of <strong>in</strong>vasives <strong>in</strong> late w<strong>in</strong>ter be<strong>for</strong>e most other plants emerge, or foliar sprayevergreen or semievergreen <strong>in</strong>vasives after surround<strong>in</strong>g plants have entered dormancy. Remember that desirablewoody plants can be damaged through transfer of herbicides by root exudates follow<strong>in</strong>g stem <strong>in</strong>jection and cut-treattreatments or when soil-active herbicides wash off treated stems. Damage to surround<strong>in</strong>g native plants can be m<strong>in</strong>imizedwith care and <strong>for</strong>ethought dur<strong>in</strong>g plann<strong>in</strong>g and application.Adjuvants and Additives to Herbicide Spray SolutionsAdjuvants are any product other than water added to a spray solution to improve herbicide per<strong>for</strong>mance and effectiveness,<strong>in</strong>clud<strong>in</strong>g delivery, retention on foliage, and foliar or bark penetration. Adjuvants may be <strong>in</strong>cluded as part of thecommercial herbicide product or sold separately as an additive you must mix with the herbicide be<strong>for</strong>e application.Another common additive used by professionals is a mark<strong>in</strong>g dye, which is not an adjuvant. Choose an adjuvantaccord<strong>in</strong>g to label recommendations and appropriate <strong>for</strong> your particular application method and field conditions. Beaware that many adjuvants are sold under <strong>in</strong>valid claims and unproven results. Be<strong>for</strong>e purchas<strong>in</strong>g an adjuvant, ask<strong>for</strong> recommendations from reliable, certified distributors, applicators, or extension specialists. Useful adjuvants andadditives <strong>in</strong>clude the follow<strong>in</strong>g and are classified here accord<strong>in</strong>g to their type of action.
17Mark<strong>in</strong>g dyes and colorants, used <strong>in</strong> selective or broadcast herbicide applications,verify that the treatment was applied to the <strong>in</strong>tended target. Application dyes showhow well target vegetation has been covered and whether harmful contact has beenmade with nontarget vegetation or with the applicator. Although dyes are messy andshort-lived as visible markers, they are helpful <strong>in</strong> tra<strong>in</strong><strong>in</strong>g applicators and check<strong>in</strong>g thequality of applications. Common dyes <strong>in</strong>clude Bullseye ® Blue Spray Pattern Indicator,Hi-Light ® Blue Indicator, and Blazon ® Blue Spray Pattern Indicator. Bullseye is awater-soluble polymeric colorant, not a dye, and nonsta<strong>in</strong><strong>in</strong>g on sk<strong>in</strong>, cloth<strong>in</strong>g, andequipment. Bas-Oil ® Red is oil-soluble and used with basal oil mixes.Surface active agents (better known by the acronym surfactants) are a broadgroup of materials that facilitate the emulsify<strong>in</strong>g, dispers<strong>in</strong>g, spread<strong>in</strong>g, wett<strong>in</strong>g, andother surface modify<strong>in</strong>g properties of liquids. Surfactants <strong>in</strong>crease herbicide activity bymak<strong>in</strong>g droplets larger on the leaf, thus improv<strong>in</strong>g penetration of the plant. Herbicide,weed species, and environmental conditions affect surfactant per<strong>for</strong>mance. Surfactantsshould be used with most foliar applications, except when prohibited by the herbicidelabel <strong>for</strong> specific uses, such as safety to desirable seeds and seedl<strong>in</strong>gs. Nonionicsurfactants are usually recommended because they enhance wett<strong>in</strong>g and retentionof spray drops and do not b<strong>in</strong>d with the herbicide molecule to cause deactivation.Never use household detergents as surfactants because they can deactivate manyherbicides. Common surfactants <strong>in</strong>clude Entry II ® , Big Sur 90, and Timbersurf 90. Anewer type of surfactant with leaf penetrat<strong>in</strong>g action and ra<strong>in</strong>fastness is based onSpray colorant <strong>in</strong>dicatescoverage.organosilicones, with commonly used products be<strong>in</strong>g Sil Energy ® and Silwet ® L-77. These must be mixed exactly orthey will be <strong>in</strong>effective. They also <strong>in</strong>crease the risk of <strong>in</strong>jury to sk<strong>in</strong> and eyes dur<strong>in</strong>g application. Organosilicones arenow commonly blended with other surfactants <strong>for</strong> additive properties.Water conditioners are spray solution additives that enhance herbicide per<strong>for</strong>mance by prevent<strong>in</strong>g deactivationof the herbicide’s active <strong>in</strong>gredient. Ammoniated salts are added to prevent loss of herbicidal activity of glyphosateand picloram when us<strong>in</strong>g “hard water” with greater than 200 parts per million of calcium, magnesium, and potassium.Acidifiers and buffers are additives sometimes listed on herbicide labels <strong>for</strong> use with specific water sources. Ammoniatedsalts, buffers, and surfactants are now blended to comb<strong>in</strong>e their activities <strong>in</strong> special spray additives. Commonwater conditioners are Choice ® Weather Master, and AMSWC (just ammonium sulfate). Because dirt and organicdebris can cause herbicide deactivation, always mix herbicides only with clean water from a filtered and treated source.Vegetable oils, such as methylated seed oil (MSO), can <strong>in</strong>crease spray drop adherence to leaves, <strong>in</strong>crease herbicidepenetration of leaves, and slow evaporation dur<strong>in</strong>g and after application. Herbicides must rema<strong>in</strong> <strong>in</strong> solution on a leaf<strong>for</strong> plant uptake. Vegetable oils also are mixed <strong>in</strong> basal sprays, and some vegetable oils conta<strong>in</strong> emulsify<strong>in</strong>g agents<strong>for</strong> this purpose. Several new <strong>for</strong>mulations of herbicides come with vegetable oils. Common MSOs are Improved JLBOil Plus and DYNE-AMIC ® . A commonly used bark oil is Aqumix ® .Drift retardants thicken spray solutions to create larger drops that are less likely to drift <strong>in</strong> w<strong>in</strong>d, permitt<strong>in</strong>g more accurateapplications <strong>in</strong> light w<strong>in</strong>d and cont<strong>in</strong>ued applications <strong>in</strong> slightly w<strong>in</strong>dier conditions. Common drift retardants arePoly Control 2, Nalcotrol ® , and Sta-Put ® Deposition Aid.Penetrants partially dissolve waxy plant surfaces to help the herbicide penetrate leaves or move through bark. Commonpenetrants are Cide-Kick ® and Cide-Kick ® II.Defoamers dissolve foam <strong>in</strong> spray tanks to improve mix<strong>in</strong>g and transfers of herbicides like Arsenal AC and Velpar ®L. Common defoamers are Fighter-F ® 10, Foam Fighter ® , and Brewer’s Defoamer.