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Statistical models of elasticity in main chain and smectic liquid ...

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96 CHAPTER 4. THE ELASTICITY OF SMECTIC-A ELASTOMERSFrom this expression it is clear that the layer normal should deform accord<strong>in</strong>gto the transpose <strong>of</strong> the <strong>in</strong>verse matrix, i.e. the matrix <strong>of</strong> c<strong>of</strong>actors.The layer spac<strong>in</strong>g for this aff<strong>in</strong>e model can also be calculated. Considertwo adjacent planes <strong>in</strong> the deformed system, the first <strong>of</strong> which conta<strong>in</strong>s thepo<strong>in</strong>t p <strong>and</strong> the second conta<strong>in</strong>s the po<strong>in</strong>t q as illustrated <strong>in</strong> Fig. 4.8. Fromdx+ n 0qd 0d 0pxOOFigure 4.8: The figure shows the required vectors to calculatethe spac<strong>in</strong>g between the layers as the elastomer is deformed.Fig. 4.8 it is clear thatp = λ·x (4.58)q = λ·x+d 0 λ·n 0 (4.59)The displacement between these po<strong>in</strong>ts resolved along the layer normal givesthe spac<strong>in</strong>g between the <strong>smectic</strong> layersd = (q−p)·n (4.60)= d 0 (λ·n 0 )·n. (4.61)Assum<strong>in</strong>g that the normal is <strong>in</strong>itially parallel to the z axis then the layerspac<strong>in</strong>g can be written asdd 0= (λ·n 0 )·=1|ǫ ijk λ jx λ ky |λ −T ·n 0|ǫ ijk λ jx λ ky |(4.62)(4.63)whereEq.(4.54) hasbeenusedtosubstituteforn<strong>and</strong>thedenom<strong>in</strong>ator rewrittenby identify<strong>in</strong>g k = ˆx <strong>and</strong> m = ŷ. The cross product expression that producesthe new layer normal can be thought <strong>of</strong> geometrically as calculat<strong>in</strong>g thedistance along the normal between two planes, or equivalently as calculat<strong>in</strong>gthe area <strong>of</strong> the plane. These two statements are equivalent because the systemis volume conserv<strong>in</strong>g.

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