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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Organometallic -

Organometallic - Regioselectivity

Reaction of Organocuprates Conjugate Addition (cont’d) • organocopper reagents used for conjugate additions to enones are homocuprates,heterocuprates, higher-order cuprates, and Grignard reagents in the presence of catalytic amounts of copper salts (CuX). • Addition of organocopper reagents to α,β-unsaturated carbonyl compounds (enones and conjugated esters) generates enolates with concomitant introduction of an organic group at the β-position.

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