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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Reaction of Organozinc

Reaction of Organozinc compounds The Reformatsky Reaction • Reformatsky enolates: different from base-generated enolates since zinc enolates add to highly hindered+to easily enolizable ketones, thus no formation of condensation products. • No danger of a Claisen-type self-condensation since zincenolates do not react with esters but react readily with aldehydes and ketones to furnish aldol-type products. • Enantioselective addition of organozinc to C=O gives chiral alcohols.

Reaction of Organozinc compounds Reactions of functionally substituted RZnI • application of functionally substituted organozincs allows for construction of C-C bonds while circumventing tedious protection-deprotection strategies.

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