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AlitInform 50

“ALITinform” is a periodical that covers different aspects in production and applications of cement, concrete, and dry building mixtures. Pages of this journal offer contributions from leading Russian and International scientists, technologists and leading professionals, news from the stock markets, research laboratories, latest elaborations by producers and suppliers of modern building materials and equipment. The magazine goal is to unite on its pages the articles of the leading Russian and International specialists in the field of cement, concrete, dry building mixtures; latest news of the Russian and world building materials market, the traditions of peer-reviewed Russian scientific magazines and innovative informational approach of the contemporary printed media. The prime focus is on developments serving the purpose of rationalization of production, reduction of energy consumption, enhancement of quality and improvement of environmental safety. _______________________________________

“ALITinform” is a periodical that covers different aspects in production and applications of cement, concrete, and dry building mixtures. Pages of this journal offer contributions from leading Russian and International scientists, technologists and leading professionals, news from the stock markets, research laboratories, latest elaborations by producers and suppliers of modern building materials and equipment.

The magazine goal is to unite on its pages the articles of the leading Russian and International specialists in the field of cement, concrete, dry building mixtures; latest news of the Russian and world building materials market, the traditions of peer-reviewed Russian scientific magazines and innovative informational approach of the contemporary printed media. The prime focus is on developments serving the purpose of rationalization of production, reduction of energy consumption, enhancement of quality and improvement of environmental safety.
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dry mixtures | сухие смеси<br />

is much easier today with the use of rheometers, taking<br />

into account that cement is a time depending system and<br />

that results will be always depending on the shear history<br />

of the mortar [3].<br />

When a mineral thickener is introduced and<br />

dispersed in a mortar matrix it will form a gel structure.<br />

When clay particles (fibers in the case of sepiolite and<br />

attapulgite or flakes for bentonites) are well dispersed in<br />

the mortar they interact among themselves and at the<br />

same time with other components of the mortar. This<br />

interaction, forming a gel structure, is responsible for an<br />

increase in the viscosity and therefore it is providing slip<br />

and sag resistance control. This interaction is caused by a<br />

weak dipole attraction that could be easily broken under<br />

shear (Fig. 1). Due to this the mortar density decreases<br />

when the product is stirred making it easier to work with,<br />

this is the so called workability, pseudoplasticity or shear<br />

thinning. This effect is reversible; if the shear stops the<br />

gel structure will recover and so the initial viscosity will<br />

do. This effect is called thixotropy (Fig. 2).<br />

бингамовской вязкопластичной жидкости [2]. Поэтому<br />

предметом практически всех проведенных<br />

исследований были два реологических параметра —<br />

предел текучести и пластическая вязкость, и их изменение<br />

при сдвиге. Данные параметры, представленные<br />

в виде кривых, отображают характеристики<br />

растворных смесей в зависимости от реологических<br />

свойств. Сегодня провести реологический анализ намного<br />

проще, благодаря специальным приборам —<br />

реометрам. Это особенно важно, учитывая, что для<br />

цемента имеет значение фактор времени, а показатели<br />

растворной смеси всегда зависят от усилия сдвига [3].<br />

При введении в растворную смесь минеральных<br />

тиксотропных добавок образуется гелеподобная<br />

структура. За счет высокой степени диспергирования<br />

частицы глины (в виде волокон в случае сепиолита и<br />

аттапульгита или в виде пластин в случае бентонита)<br />

взаимодействуют друг с другом, а также с другими<br />

компонентами растворной смеси. В результате образования<br />

гелеподобной структуры увеличивается<br />

Fig. 1a. Hydrogen bonds between fibers (Sepiolite and<br />

Attapulgite)<br />

Рис. 1a. Водородные связи между волокнами (сепиолиты и<br />

аттапульгиты)<br />

Fig. 1b. Electric attraction between flakes (Bentonite)<br />

Рис. 1b. Электростатическое притяжение между<br />

пластинами (бентониты)<br />

Viscosity // Вязкость<br />

Pseudoplasticity<br />

// Псевдопластичность<br />

Shear rate // Усилие сдвига<br />

Thixotropy // Тиксотропность<br />

Time // Время<br />

Fig. 2. Effects in gel structure under shear strain<br />

Рис. 2. Явления, возникающие в гелеподобных структурах при деформации сдвига<br />

“ALITinform” International Analytical Review No. 1 (<strong>50</strong>) 2018<br />

49

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