„Letztendlich sind alle Dinge miteinander verbunden, Jim.“

Inhaltsverzeichnis
1.EINLEITUNG ....................................................................................................................... 1
1.1 Allgemeiner Kenntnisstand ............................................................................................... 1
2. ALLGEMEINER TEIL ....................................................................................................... 6
2.1 Abkürzungen / Maßeinheiten ............................................................................................ 6
2.2 Arbeitstechniken ................................................................................................................. 8
2.3 Verwendete Analysemethoden ........................................................................................ 10
2.3.1 Elementaranalyse ...................................................................................................... 10
2.3.2 Infrarot-Spektroskopie ............................................................................................. 10
2.3.3 Raman-Spektroskopie ............................................................................................... 10
2.3.4 Kernresonanzspektroskopie ..................................................................................... 10
2.3.5 Massenspektrometrie ................................................................................................ 11
2.3.6 Einkristallröntgenstrukturanalyse .......................................................................... 11
2.3.7 Schmelzpunktbestimmung ....................................................................................... 11
3. EXPERIMENTELLER TEIL ........................................................................................... 12
3.1 Modifizierte / neue Synthesestrategien ........................................................................... 12
3.1.1 Synthese von p-Tosylazid (1) .................................................................................... 12
3.1.2. Synthese von 1-Azido-2,6-bis-(2,4,6-trimethylphenyl)benzol (2) ......................... 13
3.1.3 Synthese von 2,6-Bis-(2,4,6-trimethylphenyl)anilin (3) .......................................... 15
3.2 Darstellung und Reaktionen ............................................................................................ 16
3.2.1 Synthese von N,N-Bis-dichlorphosphanyl-2,6-bis-(2,4,6-trimethylphenyl)anilin (4) 16
3.2.2 Synthese von N,N’,N’-[Tris-(trimethylsilyl)]hydrazino-N’’-[2,6-bis-(2,4,6-trimethylphenyl)phenyl]iminophosphan
(5) ................................................................ 17
3.2.3 Synthese von N-[2,6-Bis-(2,4,6-trimethylphenyl)phenyl]aminodichlorphosphan
(6) ................................................................................................................................. 18
3.2.4 Synthese von 1,3-Dichlor-2,4-di-[2,6-bis-(2,4,6-trimethylphenyl)phenyl]-cyclo-
1,3-diphospha-2,4-diazan (7) ..................................................................................... 19
3.2.5 Synthese von 1-Chlor-2,4-di-[2,6-bis-(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3diphospha-2,4-diazenium
tetrachlorogallat (8) ....................................................... 22
3.2.6 Synthese von 1-Azido-2,4-di-[2,6-bis-(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3diphospha-2,4-diazenium
azido-hexachlorodigallat (9) ..................................... 23
3.2.7 Synthese von N-(2,4,6-Tri-tertbutylphenyl)imino-chlorphosphan (10) ................ 24
3.2.8 Synthese von N-Trimethylsilyl-2,6-bis-(2,4,6-trimethylphenyl)anilin (11) .......... 25
3.2.9 Synthese von N-Trimethylsilyl-N-dichlorphosphanyl-2,6-bis-(2,4,6-trimethyl
phenyl)anilin (12) ........................................................................................................ 26
3.2.10 Synthese von 1–(2,6-Bis-(2,4,6-trimethylphenyl)phenyl)tetrazaphosphol
galliumtrichlorid addukt (13) .................................................................................... 27
3.2.11 Synthese von N-2,6-Bis-(2,6-diisopropylphenyl)phenyl]amino-dichlor-
phosphan (14) .............................................................................................................. 28
3.2.12 Umsetzung von N-Trimethylsilyl-N-dichlorphosphanyl-2,6-bis-(2,4,6-tri-
methylphenyl)anilin (12) mit GaCl3 .......................................................................... 30