Heterogeneously Catalyzed Oxidation Reactions Using ... - CHEC

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References [1] J.H. Clark, Green Chem. 1 (1999) 1. CHAPTER 1 [2] P.T. Anastas, M.M. Kirchhoff, Acc. Chem. Res. 35 (2002) 686. [3] C.H. Christensen, J. Rass‐Hansen, C.C. Marsden, E. Taarning, K. Egeblad, ChemSusChem 1 (2008) 283. [4] G. Ertl, Angew. Chem. 120 (2008) 3578. [5] T. Mallat, A. Baiker, Chem. Rev. 104 (2004) 3037. [6] W. Partenheimer, Adv. Synth. Catal. 351 (2009) 456. [7] M. Haruta, T. Kobayashi, H. Sano, N. Yamada, Chem. Lett. (1987) 405. [8] S.R. Collinson, W. Thielemans, Coord. Chem. Rev. 254 (2010) 1854. [9] J. Herwig, W. Kaminsky, Polym. Bull. 9 (1983) 464. [10] W. Partenheimer, Catal. Today 23 (1995) 69. [11] M.J. Beier, W. Knolle, A. Prager‐Duschke, M.R. Buchmeiser, Macromol. Rapid Comm. 29 (2008) 904. [12] M.M. Schubert, V. Plzak, J. Garche, R.J. Behm, Catal. Lett. 76 (2001) 143. [13] I. Hermans, E.S. Spier, U. Neuenschwander, N. Turra, A. Baiker, Top. Catal. 52 (2009) 1162. [14] D.I. Enache, J.K. Edwards, P. Landon, B. Solsona‐Espriu, A.F. Carley, A.A. Herzing, M. Watanabe, C.J. Kiely, D.W. Knight, G.J. Hutchings, Science 311 (2006) 362. [15] F. Ullmann, "Ullmann's encyclopedia of industrial chemistry", 6 th edition, Wiley‐VCH, Weinheim, 2003. [16] H. Fiege, K. Wedemeyer, Angew. Chem. Int. Ed. 20 (1981) 783. [17] T. Mallat, A. Baiker, Catal. Today 19 (1994) 247. [18] R. Anderson, K. Griffin, P. Johnston, P.L. Alsters, Adv. Synth. Catal. 345 (2003) 517. [19] K. Yamaguchi, N. Mizuno, Angew. Chem. Int. Edit. 41 (2002) 4538. [20] J. Kim, K. Yamaguchi, N. Mizuno, Angew. Chem. Int. Edit. 47 (2008) 9249. [21] H. Miyamura, M. Shiramizu, R. Matsubara, S. Kobayashi, Angew. Chem. Int. Edit. 47 (2008) 8093. [22] S. Mori, M. Takubo, T. Yanase, T. Maegawa, Y. Monguchi, H. Sajiki, Adv. Synth. Catal. 352 (2010) 1630. [23] M. Haruta, N. Yamada, T. Kobayashi, S. Iijima, J. Catal. 115 (1989) 301. [24] M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M.J. Genet, B. Delmon, J. Catal. 144 (1993) 175. [25] A. Corma, H. Garcia, Chem. Soc. Rev. 37 (2008) 2096. [26] C. Della Pina, E. Falletta, L. Prati, M. Rossi, Chem. Soc. Rev. 37 (2008) 2077. [27] M.D. Hughes, Y.J. Xu, P. Jenkins, P. McMorn, P. Landon, D.I. Enache, A.F. Carley, G.A. Attard, G.J. Hutchings, F. King, E.H. Stitt, P. Johnston, K. Griffin, C.J. Kiely, Nature 437 (2005) 1132. 6
1. Introduction [28] S. Bawaked, N.F. Dummer, N. Dimitratos, D. Bethell, Q. He, C.J. Kiely, G.J. Hutchings, Green Chem. 11 (2009) 1037. [29] M. Turner, V.B. Golovko, O.P.H. Vaughan, P. Abdulkin, A. Berenguer‐Murcia, M.S. Tikhov, B.F.G. Johnson, R.M. Lambert, Nature 454 (2008) 981. [30] T. Seki, M. Baiker, Chem. Rev. 109 (2009) 2409. [31] A. Baiker, Chem. Rev. 99 (1999) 453. [32] C. Keresszegi, T. Burgi, T. Mallat, A. Baiker, J. Catal. 211 (2002) 244. [33] C. Keresszegi, D. Ferri, T. Mallat, A. Baiker, J. Phys. Chem. B 109 (2005) 958. [34] M. Caravati, J.‐D. Grunwaldt, A. Baiker, Catal. Today 126 (2007) 27. [35] J.‐D. Grunwaldt, C. Keresszegi, T. Mallat, A. Baiker, J. Catal. 213 (2003) 291. [36] C. Keresszegi, J.‐D. Grunwaldt, T. Mallat, A. Baiker, J. Catal. 222 (2004) 268. [37] Obtained from "http://en.wikipedia.org/wiki/Carbon_dioxide", last accessed on January, 24 th , 2011. [38] M. Caravati, J.‐D. Grunwaldt, A. Baiker, Catal. Today 91‐2 (2004) 1. [39] M. Caravati, J.‐D. Grunwaldt, A. Baiker, Phys. Chem. Chem. Phys. 7 (2005) 278. [40] R.M. Lambert, F.J. Williams, R.L. Cropley, A. Palermo, J. Mol. Catal A 228 (2005) 27. 7
Page 1 and 2: TECHNICAL UNIVERSITY OF DENMARK (DT
Page 3 and 4: Preface The present dissertation su
Page 5 and 6: the carboxylic acid, ceria inhibite
Page 7 and 8: Resume Denne afhandling giver indle
Page 9 and 10: hvorimod mængden af katalysator ku
Page 11 and 12: 2.3.8 Oxidation of sulfides .......
Page 13 and 14: 5.3.5 Macroscopic mass transport in
Page 15 and 16: Chapter 1 Introduction With its gre
Page 17 and 18: 1. Introduction Scheme 1‐1: High
Page 19: 1. Introduction Figure 1‐2: Phase
Page 23 and 24: 2.1 Introduction 2.1 Introduction E
Page 25 and 26: 2.2.1 Synthesis of gold catalysts 2
Page 27 and 28: 2.2 Catalyst synthesis for oxidatio
Page 29 and 30: 2.2 Catalyst synthesis for oxidatio
Page 31 and 32: 2.3 Selective liquid‐phase oxidat
Page 33 and 34: Table 2-1: Overview over alcohol ox
Page 45 and 46: Ph O O Ph (4) (5) 2.3 Selective liq
Page 51 and 52: Table 2-4: Side-chain oxidation of
Page 53 and 54: 2.3.4 Oxidation of cyclohexane 2.3
Page 55 and 56: Table 2-5: Oxidatin of cyclohexane.
Page 59 and 60: Table 2-6: Ring hydroxylation of ar
Page 63 and 64: Table 2-7: Aerobic oxidation of ami
Page 65 and 66: Table 2-8: Oxidation of hydroquinon
Page 69 and 70: Table 2-9: Oxidation of silanes wit
Page 71 and 72:
Table 2-10: Oxidation reactions cat
Page 73 and 74:
2.4 Strengths and opportunities of
Page 75 and 76:
Page 77 and 78:
Page 79 and 80:
Page 81 and 82:
2.6 References 2.6 References [1] M
Page 83 and 84:
2.6 References [56] H. Tumma, N. Na
Page 85 and 86:
2.6 References [113] C. Keresszegi,
Page 87 and 88:
2.6 References [169] Q. Zhu, Y. Lia
Page 89 and 90:
2.6 References [223] M. Fetizon, M.
Page 91 and 92:
Chapter 3 Selective Liquid-Phase Ox
Page 93 and 94:
3.2 Experimental 3.2.1 Catalyst pre
Page 95 and 96:
3.3 Results Scattering amplitudes a
Page 97 and 98:
Absorption (a.u.) 1.2 1.0 0.8 0.6 0
Page 99 and 100:
Conversion (%) 100 90 80 70 60 50 4
Page 101 and 102:
3.3 Results Figure 3‐5: In situ X
Page 103 and 104:
3.3 Results Table 3‐2: Conversion
Page 105 and 106:
3.3 Results In order to gain insigh
Page 107 and 108:
3.3 Results the cost of selectivity
Page 109 and 110:
3.4 Discussion synergetic interacti
Page 111 and 112:
3.5 Conclusions to corroborate the
Page 113 and 114:
3.6 References [29] T. Mitsudome, Y
Page 115 and 116:
Chapter 4 Selective Side-Chain Oxid
Page 117 and 118:
4.2 Experimental single‐step flam
Page 119 and 120:
4.2 Experimental alcohol (Aldrich,
Page 121 and 122:
4.3 Results Scheme 4‐1: Oxidation
Page 123 and 124:
4.3 Results Figure 4‐2: Formation
Page 125 and 126:
4.3 Results oxidation by either 2,6
Page 127 and 128:
Absorption (a.u.) Absorption (a.u.)
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4.3 Results atomic mixing of Ag and
Page 131 and 132:
4.3 Results Figure 4‐7: Influence
Page 133 and 134:
4.4 Discussion and mechanistic cons
Page 135 and 136:
4.5 Conclusions heterogeneous radic
Page 137 and 138:
4.6 References [29] S.I. Zabinsky,
Page 139 and 140:
Chapter 5 Experimental Determinatio
Page 141 and 142:
5.2 Experimental The most important
Page 143 and 144:
5.2 Experimental Eurotherm 2216e te
Page 145 and 146:
Figure 5-1: Schematic view of the e
Page 147 and 148:
(Eq. 5‐5) AB i j ε AB i j β 5.2
Page 149 and 150:
(a) (b) (c) (d) (e) (f) (g) (h) (i)
Page 151 and 152:
5.3 Results two association sites o
Page 153 and 154:
Pressure (bar) 150 145 140 135 5.3
Page 155 and 156:
5.3 Results Figure 5‐7: Oxidation
Page 157 and 158:
Weight (g) 5.3 Results Figure 5‐8
Page 159 and 160:
5.4 Discussion catalytic reactions
Page 161 and 162:
5.4 Discussion corresponding CO2‐
Page 163 and 164:
5.5 Conclusions 5.5 Conclusions The
Page 165 and 166:
5.6 References [29] I. Tsivintzelis
Page 167 and 168:
6.1 Introduction 6.1 Introduction A
Page 169 and 170:
6.2 Experimental [38]. In a typical
Page 171 and 172:
6.3 Results out in 1 mm quartz tube
Page 173 and 174:
6.3 Results Figure 6‐2: Structure
Page 175 and 176:
6.3 Results Figure 6‐4: Epoxidati
Page 177 and 178:
6.3 Results Figure 6‐6: Compariso
Page 179 and 180:
6.3 Results Figure 6‐8: Influence
Page 181 and 182:
6.3 Results investigated the epoxid
Page 183 and 184:
6.3 Results Figure 6‐10: Co‐epo
Page 185 and 186:
6.3 Results Figure 6‐11: EXAFS an
Page 187 and 188:
6.4 Discussion would need to be for
Page 189 and 190:
6.5 Conclusions Formation of the ep
Page 191 and 192:
6.6 References [28] J. Perles, N. S
Page 193 and 194:
Chapter 7 Concluding Remarks 7.1 Co
Page 195 and 196:
7.2 Final remarks and outlook speci
Page 197 and 198:
Acknowledgements Acknowledgements T
Page 199:
Curriculum Vitae Matthias Josef Bei
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