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Abstract SCHIRACK, ANDRIANA VAIS. The Effect of Microwave ...

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1969). <strong>The</strong> flavor characteristics <strong>of</strong> major headspace volatiles in raw peanuts were<br />

identified as musty aftertaste, fruity, and musty (Young and Hovis, 1990). A<br />

combination <strong>of</strong> γ-butyrolactone, benzaldehyde, indene, 2-methoxy-3-<br />

isopropylpyrazine, nonanal, benzyl alcohol, and alkyl-substituted benzenes have<br />

also been associated with the legume-like flavor (Fischer and Grosch, 1981). In<br />

addition, high amounts <strong>of</strong> raw/beany flavor in the raw peanuts have been correlated<br />

with methanol and ethanol concentrations (Crippen et al., 1992).<br />

Flavor Production During Roasting<br />

<strong>The</strong> unique flavor <strong>of</strong> roasted peanuts drives product marketing in the peanut<br />

industry. This flavor is the result <strong>of</strong> genetics, production and handling, storage, and<br />

processing factors (Sanders et al., 1995). <strong>The</strong> basic characteristics <strong>of</strong> roasted<br />

peanut flavor have been described as nutty, stemming from the presence <strong>of</strong><br />

methylpyrazine, 2,6-dimethylpyrazine, and 2-methyl-5-ethylpyrazine; cheesy, from<br />

isobutyric and valeric acids; and garlic, from sulphides present in the peanuts (Lee,<br />

1980). <strong>The</strong> thermal products <strong>of</strong> the roasting process contribute to the unique peanut<br />

flavor, and are affected by environment during storage and the initial mix <strong>of</strong> flavor<br />

precursors (Vercellotti et al., 1994). Non-enzymatic carbonyl-amine browning and<br />

lipid oxidation reactions are the sources <strong>of</strong> volatile flavor compounds in peanuts, and<br />

include interactions between peanut components as well as thermal decomposition<br />

products and loss <strong>of</strong> volatiles (H<strong>of</strong>fpauir, 1953; Warner et al., 1996).<br />

Maillard reactions are primarily responsible for browning reactions in roasted<br />

peanuts, although caramelization <strong>of</strong> sugars plays a minor role. <strong>The</strong> products <strong>of</strong><br />

37

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