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GROUND WATER IN NORTH-CENTRAL TENNESSEE

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104 <strong>GROUND</strong> <strong>WATER</strong> <strong>IN</strong> <strong>NORTH</strong>-<strong>CENTRAL</strong> <strong>TENNESSEE</strong><br />

(CaCO3) equivalent to all the calcium and magnesium. This quan­<br />

tity is the so-called "total hardness" of the water. It is calculated<br />

by the formula<br />

Total hardness = 2.5 Ca +4.1 Mg<br />

in which all quantities are expressed in parts per million. Hardness<br />

is caused both by the bicarbonates and by the sulphates of calcium<br />

and magnesium. The hardness due to sulphates the so-called "non-<br />

carbonate hardness" or "permanent hardness" may be calculated<br />

from the formula<br />

Noncarbonate hardness = 2.5 Ca+4.1 Mg 0.82 HCO3 .<br />

Water with a total hardness less than 50 parts per million is gen­<br />

erally considered soft, and under most circumstances its treatment to<br />

remove hardness is not justified on the score of economy. Hardness<br />

between 50 and 150 parts per million does not render the water un­<br />

satisfactory for most purposes, but it does increase the consumption<br />

of soap slightly. Hence, it is profitable for laundries and other indus­<br />

tries that use large quantities of soap to soften such a water to remove<br />

calcium and magnesium. Hardness exceeding 150 parts per million<br />

is objectionable in common household uses of water, and if the hard­<br />

ness is 200 or 300 parts per million it is common practice to soften the<br />

water or to install cisterns and rain catches. When an entire munici­<br />

pal supply is softened, the hardness is generally reduced to about 100<br />

parts per million, as the additional improvement from further soften­<br />

ing is not deemed an economy. If the hardness is much more than<br />

100 parts per million, the water must generally be treated for. the<br />

prevention of scale formation before it can be used successfully in<br />

steam boilers. The cost and difficulty of adequate softening for this<br />

purpose are likely to be increased materially if the noncarbonate hard­<br />

ness is large.<br />

Very few of the ground waters of north-central Tennessee contain<br />

less than 50 parts per million total hardness, and many are so hard<br />

that they should be softened to make them suitable for general use.<br />

In some of the waters the noncarbonate hardness also is relatively<br />

large.<br />

There are two processes for softening water in general use the<br />

lime and soda process and the exchange silicate or so-called "zeolite"<br />

or "permutite" process, which has been developed in recent years.<br />

lii the lime and soda process the noncarbonate hardness, if present<br />

in the raw water, is converted to carbonate hardness by the addition<br />

of enough soda (sodium carbonate) to react with the sulphates of<br />

calcium and magnesium to form the bicarbonates of calcium and mag-

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