Hazardous Materials Shipping Guide - Industrial Safety and Hazmat ...

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Sym- bols FedEx Ground Hazardous Materials Table D.O.T. Basic Description for Hazardous Material Shipments Packaging (§173.***) Hazardous materials descriptions and proper shipping names Hazard class or Division Identifi- cation Numbers PG Label codes Special provisions Exceptions NonBulk FedEx Ground Restrictions (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (9) Bombs, with bursting charge 1.2F UN0291 II EXPLOSIVE 1.2F 62 Not Accepted by FedEx Ground Bombs with flammable liquid, with bursting charge 1.1J UN0399 II EXPLOSIVE 1.1J 62 Not Accepted by FedEx Ground Bombs with flammable liquid, with bursting charge 1.2J UN0400 II EXPLOSIVE 1.2J 62 Not Accepted by FedEx Ground Boosters with detonator 1.1B UN0225 II EXPLOSIVE 1.1B None 62 Not Accepted by FedEx Ground Boosters with detonator 1.2B UN0268 II EXPLOSIVE 1.2B None 62 Not Accepted by FedEx Ground Boosters, without detonator 1.1D UN0042 II EXPLOSIVE 1.1D None 62 Not Accepted by FedEx Ground Boosters, without detonator Borate and chlorate mixtures, see Chlorate and borate mixtures 1.2D UN0283 II EXPLOSIVE 1.2D None 62 Not Accepted by FedEx Ground Borneol 4.1 UN1312 III FLAMMABLE SOLID None 213 + Boron tribromide 8 (6.1) UN2692 I CORROSIVE, POISON 2,N34 None 227 Not Accepted by FedEx Ground Boron trichloride 2.3 (8) UN1741 POISON GAS, CORROSIVE 3 None 304 Not Accepted by FedEx Ground Boron trifluoride 2.3 UN1008 POISON GAS 2 None 302 Not Accepted by FedEx Ground Boron trifluoride acetic acid complex, liquid 8 UN1742 II CORROSIVE 154 202 Boron trifluoride acetic acid complex, solid 8 UN3419 II CORROSIVE 154 212 Boron trifluoride diethyl etherate 8 (3) UN2604 I CORROSIVE, FLAMMABLE LIQUID None 201 Boron trifluoride dihydrate 8 UN2851 II CORROSIVE 154 212 Boron trifluoride dimethyl etherate 4.3 (8,3) UN2965 I DANGEROUS WHEN WET, CORROSIVE, FLAMMABLE LIQUID** None 201 Boron trifluoride propionic acid complex, liquid 8 UN1743 II CORROSIVE 154 202 Boron trifluoride propionic acid complex, solid Box toe gum, see Nitrocellulose etc. 8 UN3420 II CORROSIVE 154 212 Bromates, inorganic, aqueous solution, n.o.s. 5.1 UN3213 II OXIDIZER 152 202 Bromates, inorganic, aqueous solution, n.o.s. 5.1 UN3213 III OXIDIZER 152 203 Bromates, inorganic, n.o.s. 5.1 UN1450 II OXIDIZER 152 212 Accepted only when packaged under applicable special permit or 49CFR 173.13 + Bromine or Bromine solution 8 (6.1) UN1744 I CORROSIVE, POISON 1,N34, N43 None 226 Not Accepted by FedEx Ground Bromine azide Forbid- den Bromine chloride 2.3 (8,5.1) UN2901 POISON GAS, CORROSIVE, OXIDIZER 2 None 304 Not Accepted by FedEx Ground + Bromine pentafluoride 5.1 (6.1,8) UN1745 I OXIDIZER, POISON, CORROSIVE 1 None 228 Not Accepted by FedEx Ground + Bromine trifluoride 5.1 (6.1,8) UN1746 I OXIDIZER, POISON, CORROSIVE 2 None 228 Not Accepted by FedEx Ground 4-Bromo-1,2-dinitrobenzene Forbid- den 4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C.) Forbid- den 2-Bromo-2-nitropropane-1,3-diol 4.1 UN3241 III FLAMMABLE SOLID 46 151 213 Not Accepted by FedEx Ground 1-Bromo-3-chloropropane 6.1 UN2688 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 1-Bromo-3-methylbutane 3 UN2341 III FLAMMABLE LIQUID 150 203 1-Bromo-3-nitrobenzene (unstable at 56 degrees C) Forbid- den Bromoacetic acid, solid 8 UN3425 II CORROSIVE N34 154 212 Bromoacetic acid, solution 8 UN1938 II CORROSIVE 154 202 + Bromoacetone 6.1 (3) UN1569 II POISON, FLAMMABLE LIQUID 2 None 193 Not Accepted by FedEx Ground Bromoacetyl bromide 8 UN2513 II CORROSIVE 154 202 Bromobenzene 3 UN2514 III FLAMMABLE LIQUID 150 203 Bromobenzyl cyanides, liquid 6.1 UN1694 I POISON** None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 Bromobenzyl cyanides, solid 6.1 UN3449 I POISON** None 211 Accepted only when packaged under applicable special permit or 49CFR 173.13 1-Bromobutane 3 UN1126 II FLAMMABLE LIQUID 150 202 Note: Proper shipping names that must include a technical name in parentheses are indicated by the letter G in column 1 ** Column 6: See column 9 for FedEx Ground restrictions 165
Sym- bols FedEx Ground Hazardous Materials Table D.O.T. Basic Description for Hazardous Material Shipments Packaging (§173.***) Hazardous materials descriptions and proper shipping names Hazard class or Division Identifi- cation Numbers PG Label codes Special provisions Exceptions NonBulk FedEx Ground Restrictions (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (9) 2-Bromobutane 3 UN2339 II FLAMMABLE LIQUID 150 202 Bromochloromethane 6.1 UN1887 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 2-Bromoethyl ethyl ether 3 UN2340 II FLAMMABLE LIQUID 150 202 Bromoform 6.1 UN2515 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 Bromomethylpropanes 3 UN2342 II FLAMMABLE LIQUID 150 202 2-Bromopentane 3 UN2343 II FLAMMABLE LIQUID 150 202 Bromopropanes 3 UN2344 II FLAMMABLE LIQUID 150 202 Bromopropanes 3 UN2344 III FLAMMABLE LIQUID 150 203 3-Bromopropyne 3 UN2345 II FLAMMABLE LIQUID 150 202 Bromosilane Bromotoluene-alpha, see Benzyl bromide Forbid- den Bromotrifluoroethylene 2.1 UN2419 FLAMMABLE GAS None 304 Bromotrifluoromethane or Refrigerant gas, R 13B1 2.2 UN1009 NONFLAMMABLE GAS 306 304 Brucine 6.1 UN1570 I POISON** None 211 Accepted only when packaged under applicable special permit or 49CFR 173.13 Bursters, explosive 1.1D UN0043 II EXPLOSIVE 1.1D None 62 Not Accepted by FedEx Ground Butadienes, stabilized or Butadienes and Hydrocarbon mixture, stabilized containing more than 40% butadienes Butane, butane mixtures and mixtures having similar properties in cartridges each not exceeding 500 grams, see Receptacles, etc. 2.1 UN1010 FLAMMABLE GAS 306 304 Butanedione 3 UN2346 II FLAMMABLE LIQUID 150 202 Butane see also Petroleum gases, liquefied 2.1 UN1011 FLAMMABLE GAS 19 306 304 1,2,4-Butanetriol trinitrate Forbid- den Butanols 3 UN1120 II FLAMMABLE LIQUID 150 202 Butanols 3 UN1120 III FLAMMABLE LIQUID 150 203 tert-Butoxycarbonyl azide Forbid- den 5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene 4.1 UN2956 III FLAMMABLE SOLID 159 None 223 Butyl acetates 3 UN1123 II FLAMMABLE LIQUID 150 202 Butyl acetates 3 UN1123 III FLAMMABLE LIQUID 150 203 Butyl acid phosphate 8 UN1718 III CORROSIVE 154 203 Butyl acrylates, stabilized Butyl alcohols, see Butanols 3 UN2348 III FLAMMABLE LIQUID 150 203 n-Butylamine 3 (8) UN1125 II FLAMMABLE LIQUID, CORROSIVE 150 202 N-Butylaniline 6.1 UN2738 II POISON** 153 202 Accepted only when packaged under applicable special permit or 49CFR 173.13 Butyl benzenes n-Butyl bromide, see 1-Bromobutane n-Butyl chloride, see Chlorobutanes 3 UN2709 III FLAMMABLE LIQUID 150 203 D sec-Butyl chloroformate 6.1 (3,8) NA2742 I POISON, FLAMMABLE LIQUID, CORROSIVE 2 None 227 Not Accepted by FedEx Ground n-Butyl chloroformate 6.1 (3,8) UN2743 I POISON, CORROSIVE, FLAMMABLE LIQUID 2 None 227 Not Accepted by FedEx Ground tert-Butylcyclohexylchloroformate 6.1 UN2747 III POISON** 153 203 1,2-Butylene oxide, stabilized 3 UN3022 II FLAMMABLE LIQUID 150 202 Butylene see also Petroleum gases, liquefied Butyl ethers, see Dibutyl ethers 2.1 UN1012 FLAMMABLE GAS 19 306 304 Note: Proper shipping names that must include a technical name in parentheses are indicated by the letter G in column 1 ** Column 6: See column 9 for FedEx Ground restrictions 166 Accepted only when packaged under applicable special permit or 49CFR 173.13
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Hazardous Materials Shipping Guide
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-TABLE OF CONTENTS- TOPIC Page # Fe
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FedEx Ground Conditions and Require
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may be marked with a statement indi
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o For packages weighing up to 20 lb
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Small Quantity Exceptions Hazardous
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Qualification Process In order to s
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• Hazardous Materials Label, OP-9
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DOT Basic Description for Hazardous
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the telephone number applies to all
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A B C D E F HAZARDOUS MATERIAL SHIP
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SAMPLE HAZARDOUS MATERIAL SHIPPING
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OP-900 Example #5: Radioactive Radi
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Each package containing a material
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Example #3: Flammable Gas (Class 2.
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Definitions and other terms For the
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individually, palletized, or unitiz
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Class 8. See § 173.136 of this sub
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(2) Is currently registered as a pr
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Flammable gas. See § 173.115 of th
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transportation safety. This term in
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(2) Is designated for mechanical ha
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Metered delivery service means a ca
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components necessary to contain and
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Placarded car means a rail car whic
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ail, and includes a box car, flat c
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compounds or elements that will not
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Train means one or more engines cou
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Vessel includes every description o
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equirements of this subchapter and
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(3) A description, copy, or the loc
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demonstrated need to know. The secu
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(3) Each salvage cylinder must be p
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(ii) Thirty (30) g (1 ounce) for au
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(1) Cargo-only aircraft. Only hazar
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and pressure, and shocks, loadings
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(5) Packagings used for solids, whi
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gravity marked on the packaging, pr
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(b) Examination, classing and appro
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new explosive that has not been exa
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(2) Off-shore down-hole tool pallet
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(3) For flammable liquids in Packin
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(1) For flammable solids in Packing
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(b) of this section, shipments of O
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(d) Materials corrosive to aluminum
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fitted that shock of impact damage,
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as required for use in the United S
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package must be of the same type wh
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(e) Cells and batteries may be tran
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(4) Wax “Vesta” matches are mat
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the metal container must be capable
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efillable inside container must be
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of this section. A copy of the qual
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The warning must be on a contrastin
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(2) Packaged to conform with the re
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FedEx Ground Guide for Shipping Haz
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Identification Number-Cross Referen
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Identification Number-Cross Referen
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carbon), which does not meet the de
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29 Lithium cells and batteries and
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49 Mixtures of solids which are not
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general packaging requirements of s
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transport. Mixtures containing at l
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141. A toxin obtained from a plant,
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162 This material may be transporte
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N33 Aluminum drums are not authoriz
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Appendix A to 172.101 List of Hazar
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Code Hazardous Substance 277 Report
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Code Hazardous Substance Reportable
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Code Hazardous Substance 2,4-(1H,3H
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1000 FedEx Drive Moon Township, PA
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