Hazardous Materials Shipping Guide - Industrial Safety and Hazmat ...

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Sym- bols FedEx Ground Hazardous Materials Table D.O.T. Basic Description for Hazardous Material Shipments Packaging (§173.***) Hazardous materials descriptions and proper shipping names Hazard class or Division Identifi- cation Numbers PG Label codes Special provisions Exceptions NonBulk FedEx Ground Restrictions (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (9) 4-Methoxy-4-methylpentan-2-one 3 UN2293 III FLAMMABLE LIQUID 150 203 + Methoxymethyl isocyanate 3 (6.1) UN2605 I FLAMMABLE LIQUID, POISON 1 None 226 Not Accepted by FedEx Ground 2-Methyl-1-butene 3 UN2459 I FLAMMABLE LIQUID None 201 3-Methyl-1-butene 3 UN2561 I FLAMMABLE LIQUID None 201 2-Methyl-2-butene 3 UN2460 II FLAMMABLE LIQUID None 202 Methyl 2-chloropropionate 3 UN2933 III FLAMMABLE LIQUID 150 203 2-Methyl-2-heptanethiol 6.1 (3) UN3023 I POISON, FLAMMABLE LIQUID 2 None 227 Not Accepted by FedEx Ground 2-Methyl-5-ethylpyridine 6.1 UN2300 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 Methyl acetate 3 UN1231 II FLAMMABLE LIQUID 150 202 Methyl acetylene and propadiene mixtures, stabilized 2.1 UN1060 FLAMMABLE GAS 306 304 Methyl acrylate, stabilized 3 UN1919 II FLAMMABLE LIQUID 150 202 Methylal Methyl alcohol, see Methanol 3 UN1234 II FLAMMABLE LIQUID None 202 Methyl allyl chloride 3 UN2554 II FLAMMABLE LIQUID 150 202 Methylamine, anhydrous 2.1 UN1061 FLAMMABLE GAS 306 304 Methylamine, aqueous solution 3 (8) UN1235 II FLAMMABLE LIQUID, CORROSIVE 150 202 Methylamine dinitramine and dry salts thereof Forbid- den Methylamine nitroform Forbid- den Methylamine perchlorate (dry) Forbid- den Methylamyl acetate Methyl amyl ketone, see Amyl methyl ketone 3 UN1233 III FLAMMABLE LIQUID 150 203 N-Methylaniline 6.1 UN2294 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 alpha-Methylbenzyl alcohol, liquid 6.1 UN2937 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 alpha-Methylbenzyl alcohol, solid 6.1 UN3438 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 Methyl bromide Methyl bromide and chloropicrin mixtures with more than 2 percent chloropicrin, see Chloropicrin and methyl bromide mixtures Methyl bromide and chloropicrin mixtures with not more than 2 percent chloropicrin, see Methyl bromide 2.3 UN1062 POISON GAS 3 None 193 Not Accepted by FedEx Ground Methyl bromide and ethylene dibromide mixtures, liquid 6.1 UN1647 I POISON 2,N65 None 227 Not Accepted by FedEx Ground Methyl bromoacetate 6.1 UN2643 II POISON** 153 202 Accepted only when packaged under applicable special permit or 49CFR 173.13 3-Methylbutan-2-one 3 UN2397 II FLAMMABLE LIQUID 150 202 N-Methylbutylamine 3 (8) UN2945 II FLAMMABLE LIQUID, CORROSIVE 150 202 Methyl butyrate Methyl chloride and chloropicrin mixtures, see Chloropicrin and methyl chloride mixtures 3 UN1237 II FLAMMABLE LIQUID 150 202 Methyl chloride and methylene chloride mixtures 2.1 UN1912 FLAMMABLE GAS 306 304 Methyl chloride or Refrigerant gas R 40 2.1 UN1063 FLAMMABLE GAS 306 304 Methyl chloroacetate Methyl chlorocarbonate, see Methyl chloroformate 6.1 (3) UN2295 I POISON, FLAMMABLE LIQUID** None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 Methyl chloroformate Methyl chloroform, see 1,1,1-Trichloroethane 6.1 (3, 8) UN1238 I POISON, FLAMMABLE LIQUID, CORROSIVE 1,N34 None 226 Not Accepted by FedEx Ground Note: Proper shipping names that must include a technical name in parentheses are indicated by the letter G in column 1 ** Column 6: See column 9 for FedEx Ground restrictions 213
Sym- bols FedEx Ground Hazardous Materials Table D.O.T. Basic Description for Hazardous Material Shipments Packaging (§173.***) Hazardous materials descriptions and proper shipping names Hazard class or Division Identifi- cation Numbers PG Label codes Special provisions Exceptions NonBulk FedEx Ground Restrictions (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (9) Methyl chloromethyl ether 6.1 (3) UN1239 I POISON, FLAMMABLE LIQUID 1 None 226 Not Accepted by FedEx Ground Methylchlorosilane 2.3 (3, 8) UN2534 POISON GAS, FLAMMABLE GAS, CORROSIVE 2,N34 None 226 Not Accepted by FedEx Ground Methylcyclohexane 3 UN2296 II FLAMMABLE LIQUID 150 202 Methylcyclohexanols, flammable 3 UN2617 III FLAMMABLE LIQUID 150 203 Methylcyclohexanone 3 UN2297 III FLAMMABLE LIQUID 150 203 Methylcyclopentane 3 UN2298 II FLAMMABLE LIQUID 150 202 Methyl dichloroacetate 6.1 UN2299 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 D Methyldichloroarsine 6.1 NA1556 I POISON 2 None 192 Not Accepted by FedEx Ground Methyldichlorosilane Methylene chloride, see Dichloromethane 4.3 (8, 3) UN1242 I DANGEROUS WHEN WET, CORROSIVE, FLAMMABLE LIQUID** N34 None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 Methylene glycol dinitrate Methyl ethyl ether, see Ethyl methyl ether Forbid- den Methyl ethyl ketone peroxide, in solution with more than 9 percent by mass active oxygen Methyl ethyl ketone, see Ethyl methyl ketone Forbid- den Methyl fluoride or Refrigerant gas R 41 2.1 UN2454 FLAMMABLE GAS 306 304 Methyl formate 3 UN1243 I FLAMMABLE LIQUID 150 201 2-Methylfuran 3 UN2301 II FLAMMABLE LIQUID 150 202 a-Methylglucoside tetranitrate Forbid- den a-Methylglycerol trinitrate Forbid- den 5-Methylhexan-2-one 3 UN2302 III FLAMMABLE LIQUID 150 203 Methylhydrazine 6.1 (3, 8) UN1244 I POISON, FLAMMABLE LIQUID, CORROSIVE 1,N34 None 226 Not Accepted by FedEx Ground Methyl iodide 6.1 UN2644 I POISON 2 None 227 Not Accepted by FedEx Ground Methyl isobutyl carbinol 3 UN2053 III FLAMMABLE LIQUID 150 203 Methyl isobutyl ketone 3 UN1245 II FLAMMABLE LIQUID 150 202 Methyl isobutyl ketone peroxide, in solution with more than 9 percent by mass active oxygen Forbid- den Methyl isocyanate 6.1 (3) UN2480 I POISON, FLAMMABLE LIQUID 1 None 226 Not Accepted by FedEx Ground Methyl isopropenyl ketone, stabilized 3 UN1246 II FLAMMABLE LIQUID 150 202 Methyl isothiocyanate 6.1 (3) UN2477 I POISON, FLAMMABLE LIQUID 2 None 227 Not Accepted by FedEx Ground Methyl isovalerate 3 UN2400 II FLAMMABLE LIQUID 150 202 Methyl magnesium bromide, in ethyl ether 4.3 (3) UN1928 I DANGEROUS WHEN WET, FLAMMABLE LIQUID** None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 Methyl mercaptan Methyl mercaptopropionaldehyde, see 4-Thiapentanal 2.3 (2.1) UN1064 POISON GAS, FLAMMABLE GAS 3 None 304 Not Accepted by FedEx Ground Methyl methacrylate monomer, stabilized 3 UN1247 II FLAMMABLE LIQUID 150 202 4-Methylmorpholine or n-methylmorpholine 3 (8) UN2535 II FLAMMABLE LIQUID, CORROSIVE 150 202 Methyl nitramine (dry) Forbid- den Methyl nitrate Forbid- den Methyl nitrite Forbid- den Methyl norbornene dicarboxylic anhydride, see Corrosive liquids, n.o.s. Methyl orthosilicate 6.1 (3) UN2606 I POISON, FLAMMABLE LIQUID 2 None 227 Not Accepted by FedEx Ground Methylpentadienes 3 UN2461 II FLAMMABLE LIQUID 150 202 Note: Proper shipping names that must include a technical name in parentheses are indicated by the letter G in column 1 ** Column 6: See column 9 for FedEx Ground restrictions 214
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Hazardous Materials Shipping Guide
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-TABLE OF CONTENTS- TOPIC Page # Fe
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FedEx Ground Conditions and Require
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may be marked with a statement indi
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o For packages weighing up to 20 lb
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Small Quantity Exceptions Hazardous
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Qualification Process In order to s
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• Hazardous Materials Label, OP-9
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DOT Basic Description for Hazardous
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the telephone number applies to all
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A B C D E F HAZARDOUS MATERIAL SHIP
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SAMPLE HAZARDOUS MATERIAL SHIPPING
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OP-900 Example #5: Radioactive Radi
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Each package containing a material
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Example #3: Flammable Gas (Class 2.
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Definitions and other terms For the
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individually, palletized, or unitiz
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Class 8. See § 173.136 of this sub
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(2) Is currently registered as a pr
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Flammable gas. See § 173.115 of th
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transportation safety. This term in
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(2) Is designated for mechanical ha
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Metered delivery service means a ca
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components necessary to contain and
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Placarded car means a rail car whic
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ail, and includes a box car, flat c
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compounds or elements that will not
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Train means one or more engines cou
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Vessel includes every description o
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equirements of this subchapter and
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(3) A description, copy, or the loc
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demonstrated need to know. The secu
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(3) Each salvage cylinder must be p
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(ii) Thirty (30) g (1 ounce) for au
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(1) Cargo-only aircraft. Only hazar
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and pressure, and shocks, loadings
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(5) Packagings used for solids, whi
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gravity marked on the packaging, pr
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(b) Examination, classing and appro
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new explosive that has not been exa
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(2) Off-shore down-hole tool pallet
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(3) For flammable liquids in Packin
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(1) For flammable solids in Packing
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(b) of this section, shipments of O
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(d) Materials corrosive to aluminum
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fitted that shock of impact damage,
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as required for use in the United S
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package must be of the same type wh
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(e) Cells and batteries may be tran
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(4) Wax “Vesta” matches are mat
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the metal container must be capable
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efillable inside container must be
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of this section. A copy of the qual
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The warning must be on a contrastin
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(2) Packaged to conform with the re
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FedEx Ground Guide for Shipping Haz
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Identification Number-Cross Referen
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alternate proper shipping name and
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may, due to differing physical stat
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group or hazard zone shown in assoc
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standards, or not appropriately add
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Column 8A Exceptions Column 8B NonB
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Sym- bols FedEx Ground Hazardous Ma
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Page 165 and 166: Sym- bols FedEx Ground Hazardous Ma
Page 215: Sym- bols FedEx Ground Hazardous Ma
Page 263 and 264: carbon), which does not meet the de
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49 Mixtures of solids which are not
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general packaging requirements of s
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transport. Mixtures containing at l
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141. A toxin obtained from a plant,
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162 This material may be transporte
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N33 Aluminum drums are not authoriz
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Appendix A to 172.101 List of Hazar
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Code Hazardous Substance 277 Report
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Code Hazardous Substance Reportable
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Code Hazardous Substance 2,4-(1H,3H
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1000 FedEx Drive Moon Township, PA
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