Hazardous Materials Shipping Guide - Industrial Safety and Hazmat ...

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Sym- bols FedEx Ground Hazardous Materials Table D.O.T. Basic Description for Hazardous Material Shipments Packaging (§173.***) Hazardous materials descriptions and proper shipping names Hazard class or Division Identifi- cation Numbers PG Label codes Special provisions Exceptions NonBulk FedEx Ground Restrictions (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (9) Substituted nitrophenol pesticides, liquid, flammable, toxic, flahspoint less than 23 degrees C 3 UN2780 II FLAMMABLE LIQUID, POISON** None 202 Substituted nitrophenol pesticides, liquid, toxic 6.1 UN3014 I POISON** None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, liquid, toxic 6.1 UN3014 II POISON** 153 202 Accepted only when packaged under applicable special permit or 49CFR 173.13 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, liquid, toxic 6.1 UN3014 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 (3) UN3013 I POISON, FLAMMABLE LIQUID** None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 (3) UN3013 II POISON, FLAMMABLE LIQUID** None 202 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 (3) UN3013 III POISON, FLAMMABLE LIQUID** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, solid, toxic 6.1 UN2779 I POISON** None 211 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, solid, toxic 6.1 UN2779 II POISON** 153 212 Accepted only when packaged under applicable special permit or 49CFR 173.13 Substituted nitrophenol pesticides, solid, toxic 6.1 UN2779 III POISON** 153 213 Accepted only when packaged under applicable special permit or 49CFR 173.13 Sucrose octanitrate (dry) Forbid- den Sulfamic acid 8 UN2967 III CORROSIVE 154 213 I Sulfur 4.1 UN1350 III FLAMMABLE SOLID 30 None None Not Accepted by FedEx Ground D Sulfur 9 NA1350 III CLASS 9 30 None None May not be regulated via highway Sulfur and chlorate, loose mixtures of Forbid- den Sulfur chlorides Sulfur dichloride, see Sulfur chlorides 8 UN1828 I CORROSIVE 5, N34 None 201 Sulfur dioxide Sulfur dioxide solution, see Sulfurous acid Sulfuretted hydrogen, see Hydrogen sulfide 2.3 (8) UN1079 POISON GAS, CORROSIVE 3 None 304 Not Accepted by FedEx Ground Sulfur hexafluoride 2.2 UN1080 NONFLAMMABLE GAS 306 304 + Sulfuric acid, fuming with 30 percent or more free sulfur trioxide 8 UN1831 I CORROSIVE, POISON 2,N34 None 227 Not Accepted by FedEx Ground Sulfuric acid, fuming with less than 30 percent free sulfur trioxide 8 UN1831 I CORROSIVE N34 None 201 Sulfuric acid, spent 8 UN1832 II CORROSIVE N34 None 202 Sulfuric acid with more than 51 percent acid 8 UN1830 II CORROSIVE N34 154 202 Sulfuric acid with not more than 51 percent acid Sulfuric and hydrofluoric acid mixtures see Hydrofluoric and sulfuric acid mixtures Sulfuric anhydride, see Sulfur trioxide, inhibited 8 UN2796 II CORROSIVE N6, N34 154 202 I Sulfur, molten 4.1 UN2448 III FLAMMABLE SOLID 30 None 213 Not Accepted by FedEx Ground D Sulfur, molten 9 NA2448 III CLASS 9 30 None 213 Not Accepted by FedEx Ground Sulfurous acid 8 UN1833 II CORROSIVE 154 202 Sulfur tetrafluoride 2.3 (8) UN2418 POISON GAS, CORROSIVE 1 None 302 Not Accepted by FedEx Ground + Sulfur trioxide, stabilized 8 (6.1) UN1829 I CORROSIVE, POISON 2, N34 None 227 Not Accepted by FedEx Ground + Sulfuryl chloride 8 (6.1) UN1834 I CORROSIVE, POISON 1, N34 None 226 Not Accepted by FedEx Ground Sulfuryl fluoride 2.3 UN2191 POISON GAS 4 None 304 Not Accepted by FedEx Ground Tars, liquid including road asphalt and oils, bitumen and cut backs 3 UN1999 II FLAMMABLE LIQUID 150 202 Tars, liquid including road asphalt and oils, bitumen and cut backs 3 UN1999 III FLAMMABLE LIQUID 150 203 Note: Proper shipping names that must include a technical name in parentheses are indicated by the letter G in column 1 ** Column 6: See column 9 for FedEx Ground restrictions 245
Sym- bols FedEx Ground Hazardous Materials Table D.O.T. Basic Description for Hazardous Material Shipments Packaging (§173.***) Hazardous materials descriptions and proper shipping names Hazard class or Division Identifi- cation Numbers PG Label codes Special provisions Exceptions NonBulk FedEx Ground Restrictions (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (9) Tear gas candles Tear gas cartridges, see Ammunition, tear-producing, etc. 6.1 (4.1) UN1700 II POISON, FLAMMABLE SOLID** None 340 D Tear gas devices with more than 2 percent tear gas substances, by mass 6.1 NA1693 I POISON** None 340 Accepted only when packaged under applicable special permit or 49CFR 173.13 Accepted only when packaged under applicable special permit or 49CFR 173.13 D Tear gas devices with more than 2 percent tear gas substances, by mass Tear gas devices, with not more than 2 percent tear gas substances, by mass, see Aerosols, etc. Tear gas grenades, see Tear gas candles 6.1 NA1693 II POISON** None 340 Accepted only when packaged under applicable special permit or 49CFR 173.13 G Tear gas substances, liquid, n.o.s. 6.1 UN1693 I POISON** None 201 Accepted only when packaged under applicable special permit or 49CFR 173.13 G Tear gas substances, liquid, n.o.s. 6.1 UN1693 II POISON** None 202 Accepted only when packaged under applicable special permit or 49CFR 173.13 G Tear gas substances, solid, n.o.s. 6.1 UN3448 I POISON** None 211 Accepted only when packaged under applicable special permit or 49CFR 173.13 G Tear gas substances, solid, n.o.s. 6.1 UN3448 II POISON** None 212 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tellurium compound, n.o.s. 6.1 UN3284 I POISON** None 211 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tellurium compound, n.o.s. 6.1 UN3284 II POISON** 153 212 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tellurium compound, n.o.s. 6.1 UN3284 III POISON** 153 213 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tellurium hexafluoride 2.3 (8) UN2195 POISON GAS, CORROSIVE 1 None 302 Not Accepted by FedEx Ground Terpene hydrocarbons, n.o.s. 3 UN2319 III FLAMMABLE LIQUID 150 203 Terpinolene 3 UN2541 III FLAMMABLE LIQUID 150 203 Tetraazido benzene quinone Forbid- den Tetrabromoethane 6.1 UN2504 III POISON** 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 1,1,2,2-Tetrachlorethane 6.1 UN1702 II POISON** N36 153 202 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tetrachloroethylene 6.1 UN1897 III POISON** N36 153 203 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tetraethylammonium perchlorate (dry) Forbid- den Tetraethyl dithiopyrophosphate 6.1 UN1704 II POISON** 153 212 Accepted only when packaged under applicable special permit or 49CFR 173.13 Tetraethylenepentamine 8 UN2320 III CORROSIVE 154 203 Tetraethyl silicate 3 UN1292 III FLAMMABLE LIQUID 150 203 1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a 2.2 UN3159 NONFLAMMABLE GAS 306 304 Tetrafluoroethylene, stabilized 2.1 UN1081 FLAMMABLE GAS 306 304 Tetrafluoromethane, compressed or Refrigerant gas R 14 2.2 UN1982 NONFLAMMABLE GAS None 302 1,2,3,6-Tetrahydrobenzaldehyde 3 UN2498 III FLAMMABLE LIQUID 150 203 Tetrahydrofuran 3 UN2056 II FLAMMABLE LIQUID None 202 Tetrahydrofurfurylamine 3 UN2943 III FLAMMABLE LIQUID 150 203 Tetrahydrophthalic anhydrides with more than 0.05 percent of maleic anhydride 8 UN2698 III CORROSIVE 154 213 1,2,3,6-Tetrahydropyridine 3 UN2410 II FLAMMABLE LIQUID 150 202 Tetrahydrothiophene 3 UN2412 II FLAMMABLE LIQUID 150 202 Tetramethylammonium hydroxide, solid 8 UN3423 II CORROSIVE 154 213 Tetramethylammonium hydroxide solution 8 UN1835 II CORROSIVE 154 202 Note: Proper shipping names that must include a technical name in parentheses are indicated by the letter G in column 1 ** Column 6: See column 9 for FedEx Ground restrictions 246
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Hazardous Materials Shipping Guide
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-TABLE OF CONTENTS- TOPIC Page # Fe
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FedEx Ground Conditions and Require
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may be marked with a statement indi
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o For packages weighing up to 20 lb
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Small Quantity Exceptions Hazardous
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Qualification Process In order to s
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• Hazardous Materials Label, OP-9
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DOT Basic Description for Hazardous
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the telephone number applies to all
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A B C D E F HAZARDOUS MATERIAL SHIP
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SAMPLE HAZARDOUS MATERIAL SHIPPING
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OP-900 Example #5: Radioactive Radi
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Each package containing a material
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Example #3: Flammable Gas (Class 2.
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Definitions and other terms For the
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individually, palletized, or unitiz
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Class 8. See § 173.136 of this sub
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(2) Is currently registered as a pr
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Flammable gas. See § 173.115 of th
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transportation safety. This term in
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(2) Is designated for mechanical ha
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Metered delivery service means a ca
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components necessary to contain and
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Placarded car means a rail car whic
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ail, and includes a box car, flat c
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compounds or elements that will not
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Train means one or more engines cou
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Vessel includes every description o
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equirements of this subchapter and
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(3) A description, copy, or the loc
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demonstrated need to know. The secu
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(3) Each salvage cylinder must be p
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(ii) Thirty (30) g (1 ounce) for au
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(1) Cargo-only aircraft. Only hazar
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and pressure, and shocks, loadings
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(5) Packagings used for solids, whi
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gravity marked on the packaging, pr
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(b) Examination, classing and appro
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new explosive that has not been exa
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(2) Off-shore down-hole tool pallet
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(3) For flammable liquids in Packin
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(1) For flammable solids in Packing
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(b) of this section, shipments of O
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(d) Materials corrosive to aluminum
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fitted that shock of impact damage,
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as required for use in the United S
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package must be of the same type wh
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(e) Cells and batteries may be tran
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(4) Wax “Vesta” matches are mat
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the metal container must be capable
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efillable inside container must be
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of this section. A copy of the qual
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The warning must be on a contrastin
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(2) Packaged to conform with the re
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FedEx Ground Guide for Shipping Haz
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Identification Number-Cross Referen
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alternate proper shipping name and
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may, due to differing physical stat
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group or hazard zone shown in assoc
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standards, or not appropriately add
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Column 8A Exceptions Column 8B NonB
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Sym- bols FedEx Ground Hazardous Ma
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Page 197 and 198: Sym- bols FedEx Ground Hazardous Ma
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Page 263 and 264: carbon), which does not meet the de
Page 265 and 266: 29 Lithium cells and batteries and
Page 267 and 268: 49 Mixtures of solids which are not
Page 269 and 270: general packaging requirements of s
Page 271 and 272: transport. Mixtures containing at l
Page 273 and 274: 141. A toxin obtained from a plant,
Page 275 and 276: 162 This material may be transporte
Page 277 and 278: N33 Aluminum drums are not authoriz
Page 279 and 280: Appendix A to 172.101 List of Hazar
Page 281 and 282: Code Hazardous Substance 277 Report
Page 285 and 286: Code Hazardous Substance Reportable
Page 289 and 290: Code Hazardous Substance 2,4-(1H,3H
Page 291: 1000 FedEx Drive Moon Township, PA
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