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9 Vaporisation / condensation<br />

9.1 Terminology and definitions<br />

• Vaporisation<br />

Vaporisation is understood to be the transition of a liquid into the gaseous<br />

stage upon reaching the substance’s boiling point. The onset of the<br />

boiling process depends on the following parameters:<br />

• Steam pressure of the liquid<br />

• Ambient pressure<br />

• Temperature<br />

• Substance<br />

• Saturated vapour pressure<br />

The saturated vapour pressure is that value, which is characterised by<br />

the balance between the ambient pressure and the vapour pressure<br />

of a liquid.<br />

Once the equilibrium is reached, vaporisation of the liquid takes place;<br />

this is called saturated steam.<br />

The steam pressure of a liquid is temperature-dependent so that the<br />

pressure equilibrium, at which evaporation begins, is characterised for<br />

each substance by a temperature pressure curve. This curve is called<br />

saturated steam curve.<br />

• Saturated steam<br />

Steam that reaches the saturated steam pressure but is not separated<br />

from the liquid phase, interacts with the liquid, i.e. the amount of water<br />

that vaporises equals the amount of steam that condenses. Steam, in<br />

such an interactive state, is called saturated steam.<br />

Most important characteristic:<br />

Saturated steam is not compressible (a part of it would condense in<br />

the process).<br />

• Wet steam<br />

When saturated steam cools down (e.g. by heat loss) part of it condenses,<br />

and the share of water droplets in the steam increases. This<br />

is called wet steam.<br />

• Superheated steam<br />

Steam, which is separated from the liquid and heated up, is called<br />

superheated steam.<br />

Most important characteristic:<br />

Superheated steam is compressible.

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