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EIS-0113_Section_11 - Hanford Site

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3.5.2.15<br />

non-conservative in both the drier and wetter climate scenarios, as<br />

discussed below.<br />

Because of soil variability and the difficulty of measuring moisture<br />

flux in undisturbed conditions, great uncertainty exists in pro ject/ng<br />

recharge rates from the areal ly restricted and generally artificial<br />

(lysimeters with reconstituted soils) studies conducted to date. The D<strong>EIS</strong><br />

(Vol. 2, page xxvifi) indicates that existing quantitative predictions of<br />

water recharge rates are goad only to within 2 or 3 cm/year. As noted in<br />

volume 1 of the D<strong>EIS</strong> (tap of page 4,20), the value of recharge under<br />

existing, relatively dry climatic conditions is expected to be resolved<br />

through more sophisticated investigation between 0.5 and 5 cm/yr. The same<br />

range is tentatively proposed by Gee and Heller (1985, page <strong>11</strong> . reference<br />

cited in D<strong>EIS</strong> appendix M) based an methodology being developed in current<br />

research. Kukla (1979), cited in Appendix M, indicates that present<br />

conditions represent the dry extreme of potential climatic variation.<br />

Therefore, It Is non-conservativefor USDOE to select the low end of this<br />

0.5. to 5.0 cm/yr range in the D<strong>EIS</strong> as representative of dry climate<br />

conditions.<br />

No actual data exist on recharge under a wetter climate; however,<br />

simulation of wet-climate recharge through a coarse soil was described In<br />

appendix M. Test cases 2 and 7 (Table M.7, page M.20) indicated about 15 to<br />

20 cm infiltration, depending on plant cover, after two years with 30 cm<br />

annual precipitation. The D<strong>EIS</strong> also states (page M.9, first paragraph),<br />

"The majority of soils and sediments in the vadose zone at <strong>Hanford</strong> consist<br />

of coarse-textured materials which tend to dram readily.- I view of this<br />

simulation, and the fact that recharge under present dry conditions could be<br />

as much as 5 cm/yr, the assumption of 5 cm/yr average recharge appears<br />

non-conservative for the wetter-climate scenario.<br />

Groundwater Transport of Contaminants. The D<strong>EIS</strong> (pa?e 0.1) expresses<br />

an intent to incorporate conservatism throughout its model ing analysis.<br />

Allowing for the general uncertainty in soil and transport characteristics,<br />

assumptions appear to be non-conservative in two main areas of the<br />

conceptual model of the basic transport framework. First, the assumption<br />

that hydraulic conductivities can be vertically averaged is non-conservative<br />

with respect to contaminant travel times in the unconfined aquifer. Second,<br />

and potentiallymore significant, assumptions regarding contaminant<br />

retardation, which the authors of the D<strong>EIS</strong> state (page 0.15) '...cannot be<br />

stated as necessarily conservative,' are in fact made no-conservatively<br />

(see review of Appendix P).<br />

<strong>Section</strong> 0.4.2 discusses assumptions made for numerical analysis of flow<br />

in the unconfined aquifer. While the assumptions listed on page 0.26<br />

represent great simplification of actual physical conditions, one In<br />

particular appears significantly non-conservative: Vertical averaging of<br />

hydraulic conductivities could result in horizontal travel times that are<br />

too long by an order of magnitude or mere, if large variations in hydraulic<br />

conductivity are present. This averaging in effect ignores aquifer-scale<br />

I Ong I tudinal dispersion, as is indicated at the bottom of page 0.26. A<br />

conservative approach for travel time calculation would use the largest<br />

values of hydraulic conductivity observed. The effect of this assumption is<br />

not large in the final analysis, however.<br />

NumericalModel-Unconfined ppuite, There is uncertainty as to what<br />

type of TRANSS model wasused to the transport modeling. <strong>Section</strong> 0.4.3.2<br />

states that a stochastic formulation was used which according to<br />

<strong>Section</strong> 0.4.3.3and its references (Simmons, 1981, 1982) eliminates the<br />

dispersion term by setting . the dispersion coefficient to zero and in its<br />

place, uses a random function for velocity to simulate dispersion. However,<br />

<strong>Section</strong> 0.4.3.5 states that the transport was determined using the<br />

convective-dispersive equation with a local-scale dispersion coefficient.<br />

These statements are contradictory.<br />

Because hydraulic flow velocities in the saturated zone are so high,<br />

they are relatively unimportant in the overall analysts of contaminant<br />

travel time. We are therefore not overly concerned with the process used in<br />

calibrating the numerical model of the unconfined aquifer.<br />

Unsaturated Flow Model. Transport in the vadose zone can be very slow<br />

so that assumptions made for calculations of unsaturated travel time<br />

(presented elsewhere In the D<strong>EIS</strong>) are important. <strong>Section</strong> 0.4.<strong>11</strong> describes<br />

the unit hydraulic gradient model used for hand calculating vertical<br />

groundwater travel times in the vadose zone. Use of this model requires<br />

estimating or determining three soil parameters; the saturated moisture<br />

content, saturated hydraulic conductivity, and 'b' value, the tatter<br />

depending in turn on the precise relationship between soil moisture content<br />

and capillary water potential_. These soil parameters would appear from<br />

references cited in the D<strong>EIS</strong> not to have been characterized with much<br />

precision, especially considering hysteresis and spatial variation among<br />

natural soil sat <strong>Hanford</strong>.<br />

Under the assumptions used in this model, travel velocity could have<br />

been obtained by simply dividing the assumed infiltration rate by the<br />

estimate average moisture content. It is not clear whether this Is, in<br />

effect, what has been done later in the D<strong>EIS</strong> to obtain travel times in the<br />

vices. zone. as is suggested by the moisture content assumption at the<br />

bottom of page P.6.<br />

The diffusion controlled transport in the unsaturated zonebeneath the<br />

protective barrier is discussed in <strong>Section</strong> 0.4.1.3. An assumption is made<br />

that there will be a linear concentration profile throughout the diffusion<br />

zone. Diffusion controlled profiles will be concave and not linear in this<br />

region. It is uncertain whether this assumption is ultimately conservative.<br />

The approach to modeling diffusion in this section is questioned since there<br />

are analytical solutions to.the one-dimensional diffusion equation which<br />

include source decay and contaminant decay which would be more appropriate.<br />

Finally, the diffusion coefficients used (Appendix P) are in some cases not<br />

conservative (see Appendix P review).<br />

3.5.2.9<br />

3.5.2.16<br />

3.5.2.16<br />

3.5.2.17<br />

3-22<br />

3-23

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