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Spectroscopy in a Suitcase - Royal Society of Chemistry

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UV<br />

Introduction to Ultraviolet -<br />

Visible <strong>Spectroscopy</strong> 1<br />

(UV)<br />

Background Theory<br />

Absorption <strong>of</strong> ultraviolet and visible radiation<br />

Absorption <strong>of</strong> visible and ultraviolet (UV) radiation is<br />

associated with excitation <strong>of</strong> electrons, <strong>in</strong> both atoms<br />

and molecules, from lower to higher energy levels.<br />

S<strong>in</strong>ce the energy levels <strong>of</strong> matter are quantized, only light<br />

with the precise amount <strong>of</strong> energy can cause transitions<br />

from one level to another will be absorbed.<br />

The possible electronic transitions that light might cause are 2 :<br />

All molecules will undergo electronic excitation follow<strong>in</strong>g<br />

absorption <strong>of</strong> light, but for most molecules very high<br />

energy radiation (<strong>in</strong> the vacuum ultraviolet,

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