(90) Cordes, A. W.; Bryan, C. D.; Davis, W. M.; de, L. R. H.; Glarum, S. H.; Goddard, J. D.; Haddon, R. C.; Hicks, R. G.; Kennepohl, D. K.; et, a. J. Am. Chem. Soc. 1993, 115, 7232. (91) Del Bel Belluz, P.; Cordes, A. W.; Kristof, E. M.; Kristof, P. V.; Liblong, S. W.; Oakley, R. T. J. Am. Chem. Soc. 1989, 111, 9276. (92) Cordes, A. W.; Glarum, S. H.; Haddon, R. C.; Hallford, R.; Hicks, R. G.; Kennepohl, D. K.; Oakley, R. T.; Palstra, T. T. M.; Scott, S. R. Chem. Commun. 1992, 1265. (93) Cordes, A. W.; Haddon, R. C.; Hicks, R. G.; Oakley, R. T.; Palstra, T. T. M.; Schneemeyer, L. F.; W<strong>as</strong>zczak, J. V. J. Am. Chem. Soc. 1992, 114, 1729. (94) Cordes, A. W.; Haddon, R. C.; Hicks, R. G.; Oakley, R. T.; Palstra, T. T. M. Inorg. Chem. 1992, 31, 1802. (95) Davis, W. M.; Hicks, R. G.; Oakley, R. T.; Zhao, B. Y.; Taylor, N. J. Can. J. Chem. 1993, 71, 180. (96) Boeré, R. T.; Moock, K. H.; Parvez, M. Z. Anorg. Allg. Chem. 1994, 620, 1589. (97) Bryan, C. D.; Cordes, A. W.; George, N. A.; Haddon, R. C.; MacKinnon, C. D.; Oakley, R. T.; Palstra, T. T. M.; Perel, A. S. Chem. Mater. 1996, 8, 762. (98) Cordes, A. W.; Haddon, R. C.; Hicks, R. G.; Oakley, R. T.; Vajda, K. E. Can J Chem 1998, 76, 307. (99) Feeder, N.; Less, R. J.; Rawson, J. M.; Oliete, P.; Palacio, F. Chem. Commun. 2000, 2449. (100) Yost, D. M.; Kircher, C. E. J. Am. Chem. Soc. 1930, 52, 4680. (101) Evans, F. P.; Ramsay, W. Dalton Trans. 1884, 45, 62. 60
(102) Herz, R.; Leopold C<strong>as</strong>sella & Co.: German, DE 1923-C3<strong>35</strong>48, 1923. (103) Rawson, J. M.; McManus, G. D. Coord. Chem. Rev. 1999, 189, 1<strong>35</strong>. (104) Warburton, W. K. Chem. Rev. 1957, 57, 1011. (105) Leitch, A. A.; McKenzie, C. E.; Oakley, R. T.; Reed, R. W.; Richardson, J. F.; Sawyer, L. D. Chem. Commun. 2006, 1088. (106) Risto, M.; Assoud, A.; Winter, S. M.; Oilunkaniemi, R.; Laitinen, R. S.; Oakley, R. T. Inorg. Chem. 2008, 47, 10100. (107) Mayer, R.; Bleisch, S.; Domschke, G.; Bartl, A.; St<strong>as</strong>ko, A. Z. Chem. 1981, 21, 146. (108) Bleisch, S.; Domschke, G.; Mayer, R.; Bartl, A.; Ger. Dem. Rep. . 1982, p 7 pp. (109) Beer, L.; Brusso, J. L.; Cordes, A. W.; Haddon, R. C.; Itkis, M. E.; Kirschbaum, K.; MacGregor, D. S.; Oakley, R. T.; Pinkerton, A. A.; Reed, R. W. J. Am. Chem. Soc. 2002, 124, 9498. (110) Brusso, J. L.; Derakhshan, S.; Itkis, M. E.; Kleinke, H.; Haddon, R. C.; Oakley, R. T.; Reed, R. W.; Richardson, J. F.; Robertson, C. M.; Thompson, L. K. Inorg. Chem. 2006, 45, 10958. (111) Barclay, T. M.; Wallace, C. A.; Oakley, R. T.; Preuss, K. E.; Reed, R. W. Chem. Commun. 1998, 1039. (112) Appel, R.; Janssen, H.; Siray, M.; Knoch, F. Chem. Ber. 1985, 118, 1632. (113) Mayer, R.; Domschke, G.; Bleisch, S.; Fabian, J.; Bartl, A.; St<strong>as</strong>ko, A. Collect. Czech. Chem. Commun. 1984, 49, 684. (114) Oakley, R. T.; Reed, R. W.; Robertson, C. M.; Richardson, J. F. Inorg. Chem. 2005, 44, 1837. 61
- Page 1 and 2:
1,2,3-Dithiazolyl and 1,2,35-Dithia
- Page 3 and 4:
an individual binuclear coordinatio
- Page 5 and 6:
weren’t sure about something our
- Page 7 and 8:
2.1 General........................
- Page 9 and 10:
5.3 Reverse oDTANQ.................
- Page 11 and 12:
LIST OF FIGURES AND SCHEMES Figure
- Page 13 and 14:
Figure 2-12. Magnetic susceptibilit
- Page 15 and 16:
GLOSSARY OF ABBREVIATIONS ° Degree
- Page 17 and 18:
K k k B LMCT ls LUMO Kelvin Exchang
- Page 19 and 20:
LIST OF STRUCTURES I-1 I-2 I-3 I-4
- Page 21 and 22:
I-16a I-16b I-16c I-16d I-16e I-16f
- Page 23 and 24:
I-22 I-23 I-24 I-25 exo I-26 endo x
- Page 25 and 26:
I-34 I-35 II-3 II-4 II-1 xxv
- Page 27 and 28:
III-2 III-1 III-3 III-4 III-5 III-6
- Page 29 and 30:
V-7 V-8 V-9 V-10 V-11 V-12 V-13 V-1
- Page 31 and 32:
Chapter 1 - General Introduction 1.
- Page 33 and 34:
linear relationship shown in Figure
- Page 35 and 36:
A plot of χT vs. T is an important
- Page 37 and 38:
examination of phenyl methylene. In
- Page 39 and 40: different atomic nuclei. Qualitativ
- Page 41 and 42: 3) 14 and a variety of thiazyl base
- Page 43 and 44: with one another with an energy bar
- Page 45 and 46: magnetic properties and undergoes a
- Page 47 and 48: heteroatoms which could facilitate
- Page 49 and 50: Figure 1-5. Qualitative molecular o
- Page 51 and 52: temperature. 64 This was a very imp
- Page 53 and 54: dimerization and therefore a quench
- Page 55 and 56: e enough to overcome the energetica
- Page 57 and 58: eaches the lower end of the investi
- Page 59 and 60: DTDAs has been to exploit the rearr
- Page 61 and 62: 1.3.4 1,2,3-Dithiazolyl Radicals (I
- Page 63 and 64: aromatic ring not only protects the
- Page 65 and 66: is quite similar to the spin-polari
- Page 67 and 68: compound there are many competing m
- Page 69 and 70: a b c d e Figure 1-16. a) Nonorthog
- Page 71 and 72: would result in non-orthogonal over
- Page 73 and 74: platinum center as well as the phos
- Page 75 and 76: substantial amount of unpaired elec
- Page 77 and 78: I-28 I-29 I-30 The metals manganese
- Page 79 and 80: gave a combination of 2 mononuclear
- Page 81 and 82: changes related to geometric, chemi
- Page 83 and 84: Finally, the last chapter reviews t
- Page 85 and 86: (23) Rajca, A. Chem. Rev. 1994, 94,
- Page 87 and 88: (53) Azuma, N.; Tsutsui, K.; Miura,
- Page 89: (79) Decken, A.; Cameron, T. S.; Pa
- Page 93 and 94: (128) Aliaga-Alcalde, N., 2003. (12
- Page 95 and 96: Chapter 2 - Structural and Magnetic
- Page 97 and 98: 2.2.2 pymDSDA Coordination Complexe
- Page 99 and 100: 2.2.3 DTDA Coordination Complexes o
- Page 101 and 102: indicators tend to be very weak str
- Page 103 and 104: In Figure 2-1a, the nickel complex
- Page 105 and 106: 2.2.3 Cyclic Voltametry The cyclic
- Page 107 and 108: propensity for intermolecular Se-N
- Page 109 and 110: dimerization motif. One possible ex
- Page 111 and 112: the bridging ligand such that the D
- Page 113 and 114: contacts into four different intera
- Page 115 and 116: e acting as a closed-shell, S = 0,
- Page 117 and 118: 2.3.4 [Zn(hfac) 2 ] 2·pymDTDA (II-
- Page 119 and 120: ancillary ligands and the nearly oc
- Page 121 and 122: single molecular unit. Upon closer
- Page 123 and 124: across the entire temperature regim
- Page 125 and 126: 2.5 Conclusions and Future Work It
- Page 127 and 128: therefore chain formation. However
- Page 129 and 130: The work presented in this chapter
- Page 131 and 132: 736(s), 723(s), 646(s), 632(s), 469
- Page 133 and 134: (0.2023 g, 1.104 mmol) in 30 mL of
- Page 135 and 136: (6) Chattoraj, S. C.; Cupka Jr, A.
- Page 137 and 138: Chapter 3 - 5-oxo-5H-naphtho[1,2-d]
- Page 139 and 140: triethylammonium chloride which was
- Page 141 and 142:
3.3.2 Mass Spectrometry A sample of
- Page 143 and 144:
3.3.4 X-ray Crystallography Crystal
- Page 145 and 146:
a 2-fold screw axis across half of
- Page 147 and 148:
number of electrons that this compo
- Page 149 and 150:
often generated in situ although wa
- Page 151 and 152:
similar to compounds II-1 and II-2,
- Page 153 and 154:
3.6 Experimental General All reacti
- Page 155 and 156:
Chapter 4 - The Polymorphism of Tri
- Page 157 and 158:
4.3 Discussion Prior to the discove
- Page 159 and 160:
(derived from angles ranging from 4
- Page 161 and 162:
a b c Figure 4-2. Packing diagrams
- Page 163 and 164:
polymorphs observed and are therefo
- Page 165 and 166:
Chapter 5 5.1 Overview There are se
- Page 167 and 168:
success and so a Herz ring closure
- Page 169 and 170:
did not immediately precipitate, bu
- Page 171 and 172:
Figure 5-2 shows the IR spectra for
- Page 173 and 174:
comparison of the infrared data obt
- Page 175 and 176:
discussed in section 5.2.2. As the
- Page 177 and 178:
ing was formed. One of the nitrogen
- Page 179 and 180:
equired to obtain a decent agreemen
- Page 181 and 182:
Considerations have been put toward
- Page 183 and 184:
chelation pocket is similar to that
- Page 185 and 186:
the mixture was filtered to remove
- Page 187 and 188:
good spectroscopic handle for this
- Page 189 and 190:
spectrum from about 1900 to 400 cm
- Page 191 and 192:
doublets of triplets associated wit
- Page 193 and 194:
adical, followed by the closed-shel
- Page 195 and 196:
completely dry after being under va
- Page 197 and 198:
changed substantially after the tra
- Page 199 and 200:
The reaction to produce V-15 was qu
- Page 201 and 202:
the proton two carbons away next to
- Page 203 and 204:
which is parallel to the mean plane
- Page 205 and 206:
of the 1,2,3-DTA rings could act as
- Page 207 and 208:
mixture was refluxed for 20 h yield
- Page 209 and 210:
the heat source was removed and the
- Page 211 and 212:
1085(w), 1059(w), 1008(w), 917(w),
- Page 213 and 214:
___________________________________
- Page 215 and 216:
Crystallography P 2 1 /c a = 9.1678
- Page 217 and 218:
Compound Name: 4-(2′-pyrimidyl)-1
- Page 219 and 220:
Compound Name: [μ-4-(2′-pyrimidy
- Page 221 and 222:
Magnetometry 192
- Page 223 and 224:
Crystallography P-1 a = 8.9576, b =
- Page 225 and 226:
Compound Name: [μ-4-(2′-pyrimidy
- Page 227 and 228:
Magnetometry: 198
- Page 229 and 230:
Crystallography: P2 1 /n a = 19.884
- Page 231 and 232:
Compound Name: 5-oxo-5H-naphtho[1,2
- Page 233 and 234:
204
- Page 235 and 236:
206
- Page 237 and 238:
MS (EI + ): 208
- Page 239 and 240:
Compound Name: 5-chloro-1H-[1,2,5]t
- Page 241 and 242:
Compound Name: 3-nitro-1,2-naphthaq
- Page 243 and 244:
Compound Name: 3,4-dioxo-3,4-dihydr
- Page 245 and 246:
Compound Name: 4,5-dioxo-4,5-dihydr
- Page 247 and 248:
Compound Name: 6,6′-dinitro-1,1
- Page 249 and 250:
220
- Page 251:
222