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Self-Consistent Field Theory and Its Applications by M. W. Matsen

Self-Consistent Field Theory and Its Applications by M. W. Matsen

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Index<br />

action 17<br />

binodal point 46<br />

block copolymer microstructure 5, 64<br />

boundary conditions 34<br />

Bragg condition 50<br />

Brazovskii fluctuations 72<br />

chemical potential 55<br />

classical path 15, 18<br />

classical phases 64<br />

complex phases 64<br />

composition fluctuations 72<br />

conformational asymmetry 67<br />

copolymer 3<br />

course-grained segment 8<br />

course-grained trajectory 11<br />

critical point 46<br />

degree of polymerization 4, 11<br />

diffusion equation 13<br />

dimensionless segment concentration 11<br />

Dirac δ function 75<br />

double-tangent construction 46<br />

elastic free energy 15<br />

end-segment distribution 27<br />

end-to-end vector 7<br />

Euler-Lagrange equation 76<br />

exclusion zone 69<br />

Flory-Huggins free energy 45<br />

Fourier transform 21<br />

freely-jointed chain 7<br />

functional 74<br />

functional derivative 75<br />

functional integration 76<br />

Gaussian chain model 9<br />

ground-state dominance 20<br />

homopolymer 3<br />

Hubbard-Stratonovich transformation 73<br />

incompressibility constraint 34, 42<br />

indistinguishability 43<br />

interaction χ parameter 42<br />

interfacial tension 51, 54<br />

interfacial width 51, 54, 63, 68<br />

internal energy 42<br />

invariant polymerization index 11<br />

L<strong>and</strong>au-Ginzburg free energy 21, 24, 72<br />

Lennard-Jones potential 42<br />

lever rule 46<br />

macrophase separation 45<br />

method of steepest descent 33<br />

microphase separation 57<br />

monomer 3<br />

nucleation <strong>and</strong> growth 46<br />

orthonormal basis functions 19<br />

polymer brush 5, 25<br />

polymer interface 5<br />

r<strong>and</strong>om-phase approximation 23<br />

saddle point 33<br />

scattering function 49, 60<br />

self-consistent field condition 44, 55<br />

sifting property 76<br />

spectral method 18, 36, 50, 61<br />

spinodal decomposition 46<br />

spinodal point 46

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