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22 nd Salt Water Intrusion Meeting: Salt Water Intrusion in Aquifers: Challenges and PerspectivesUSING GEOCHEMICAL AND MODELING TOOLS TO DETERMINESALINITY EVOLUTION IN THE AVEIRO CRETACEOUS AQUIFER(PORTUGAL)De MELO, M. Teresa Condesso 1 ; VANDENBOHEDE, Alexander 2teresa.melo@ist.utl.pt1- CVRM – Geosystems Center. Instituto Superior Técnico. Lisbon, Portugal.2- Dept. Geology and Soil Science, Ghent UniversityAv. Rovisco Pais. 1049-011 Lisboa. PortugalAbstract. The Aveiro Cretaceous aquifer represents a main water resource of an importantindustrialized area of northwestern Portugal with a high population density and intenseagricultural and industrial activity. The growing demand for water resources in the regionled progressively to an increased reliance on groundwater from the Cretaceous aquiferformations for most of the urban and industrial water supply. Intensive pumpage since theearly sixties has gradually caused natural piezometric surface declines and is nowthreatening the natural balance of this coastal aquifer system. The aquifer has been thesubject of detailed hydrogeological and geochemical studies during the present investigation,which were complemented by the use of a variable density groundwater flow modelling usingSEAWAT. These studies contributed to derive a coherent and broad understanding of thesalinity evolution in the aquifer system since Last Glacial Maximum (LGM) and to clarifyseveral aspects related to its man. Isotopic and chloride data show that the aquifer has beenfresh for more than 18 ka. But the freshening chemical pattern of the aquifer and theevolution of pH and alkalinity suggest that the aquifer has had previously seawater and thatthere is probably still an outlet offshore which is confirmed by the flow modelling results. Thedilute nature of the Aveiro groundwaters thus indicates previous freshening of the coastalaquifer since at least the Late Pleistocene or even earlier. Higher hydraulic gradients(~0.004) during the Last Glacial Maximum (LGM) or even before LGM imposed by a sealevel lowered by approximately 130-140 m compared to present day would have acceleratedthe complete refreshing of the aquifer, with fresh water flushing the original formation water.These hydrochemical results have been validated by variable density groundwater flowmodelling using SEAWAT which indicates that the aquifer has had freshwater since LGM andthat there will be long time before salt water will be entering the aquifer from the seaboundary.Keywords: Aveiro Cretaceous aquifer, palaewaters, salinity, geochemistry, modelling26

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