Annual Report - IHBT

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CSIR-IHBT Annual Report 2010-11Fig. 21a UV-Vis absorption spectrophotometric study of in situ conversion of Pd(II) salts to Pd(0)Fig. 21b Scanning electron micrograph of SS-Pd nano- and microparticles27
CSIR-IHBT Annual Report 2010-11Chemo- and regioselective reduction of aromatic nitro compoundsCopper/cobalt phthalocyanines and iron phthalocyanine with iron sulphate were established ascatalysts for very efficient chemo- and regio-selective reduction of aromatic nitro compoundsto generate corresponding amines. The selective reduction of nitro compounds was observed inpresence of large range of functional groups such as aldehyde, keto, acid, amide, ester, halogen,lactone, nitrile and heterocyclic functional groups. Furthermore, the present method was foundto be highly regioselective towards the reduction of dinitro aromatic compounds in shorter timewith higher yields. In most of the cases, the conversion and selectivity was >99% as monitoredby GC-MS. The reduction mechanism was elucidated by UV-Vis and electrospray ionizationquadrupole time-of-flight tandem mass spectrometry.Green and efficient method for Mannich reactionsA rapid and efficient silica-supported boric acid/ionic liquid ([bmim][PF 6]), catalyzed, one-potthree-component Mannich reaction was carried out to synthesize β-amino carbonyl compoundsat room temperature. The reaction afforded desired products in excellent yields with moderate togood diastereoselectivity. The preparation of H 3BO 3-SiO 2catalyst and its use with [bmim][PF 6] tosynthesize Mannich products is the first report. The catalyst can be reused at least 7 times.28
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Page 21 and 22: GENOMICS AND PROTEOMICSPathway engi
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Page 25 and 26: BIOINFORMATICSComputational biology
Page 27 and 28: NANOBIOLOGYSyzygium cumini and Bauh
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CSIR-IHBT Annual Report 2010-11Plan
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SUPPORT SERVICESEngineering Service
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CSIR-IHBT Annual Report 2010-11IHBT
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CSIR-IHBT Annual Report 2010-11CONF
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CSIR-IHBT Annual Report 2010-11Kuma
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CSIR-IHBT Annual Report 2010-11Uniy
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CSIR-IHBT Annual Report 2010-11AWAR
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CSIR-IHBT Annual Report 2010-11Arvi
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CSIR-IHBT Annual Report 2010-11MK S
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CSIR-IHBT Annual Report 2010-11GUES
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CSIR-IHBT Annual Report 2010-11Work
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CSIR-IHBT Annual Report 2010-11•
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CSIR-IHBT Annual Report 2010-11IMPO
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CSIR-IHBT Annual Report 2010-11IHBT
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CSIR-IHBT Annual Report 2010-11Moti
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CHAIRMANProf. Sudhir K Sopory, FNAV
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DirectorDr. PS AhujaScientist Gr. I
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CSIR-IHBT Annual Report 2010-11NEWL
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Annual Report - IHBT

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