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ISSN 1862-5258<br />

Jul / Aug<br />

<strong>04</strong> | <strong>2018</strong><br />

Cover Story:<br />

Vienna schoolgirls<br />

develop homecompostable<br />

coffee<br />

capsules| 34<br />

bioplastics MAGAZINE Vol. 13<br />

Basics<br />

PEF | 48<br />

Highlights<br />

Blow Moulding / Bottles | 16<br />

Coffee Capsules & Pods | 34<br />

... is read in 92 countries


Eastlon<br />

BIO-PET<br />

RE-THINKING THE BOTTLE:<br />

Different Bioplastics for one Application.<br />

A fi ne and high-value bottle can be made from different types of bioplastics.<br />

Rebhan was spoilt for choice and fi nally took all for their biobased packaging<br />

portfolio GREENline:<br />

• Bio-Flex ® , a PLA blend,<br />

• Eastlon, the Bio-PET by Fenc,<br />

• Braskem's Green PE.<br />

All resins are supplied by FKuR, naturally.


Editorial<br />

dear<br />

readers<br />

This year is the hottest summer in Germany that I can remember in 15 years. Unbelievably,<br />

we’ve had bright sunshine and high temperatures since the end of May. And one of the<br />

fundamental rules in weather like this is to drink a lot. Preferably water. But I prefer coffee.<br />

As I’m trying to minimize coffee-related waste at my home, I usually drink my<br />

coffee freshly brewed from freshly ground coffee beans in a modern, fully automatic<br />

coffee machine. But I must admit that there are benefits to today’s conveniently<br />

pre-dosed coffee pods and capsules: the wide variety of tastes and flavours, the<br />

different strengths available - with or without caffeine - while at home… the same<br />

coffee in each and every cup… . On the other hand, (traditional) coffee pods and<br />

capsule are causing at least some – to put it mildly – environmental concern.<br />

Could coffee pods and capsules made of biobased and/or biodegradable plastics<br />

offer a sustainable alternative? This is one of the highlight topics discussed in this<br />

issue. We’ve even included an article about a coffee capsule made of (sugar cane)<br />

paper, which are not exactly bioplastics, but in my opinion, still an alternative to<br />

aluminium worth reporting on.<br />

The other highlight topic is Blow Moulding / Bottle Applications which this time<br />

also includes the Basics section, where we have a closer look at PEF.<br />

Two more things I’d like to direct your attention to are:<br />

The 1 st PHA platform World Congress on 4 and 5 September in Cologne. We<br />

are happy to have no fewer that 28 speakers lined up to present the latest PHA<br />

developments and who are looking forward to networking with you.<br />

Second, we’re currently calling for submissions for the <strong>2018</strong> edition of the Global<br />

Bioplastics Award. If you think your product or service from the world of biobased plastics<br />

deserves the award, or you’d like to nominate somebody else’s, please let us know.<br />

Until then, please enjoy the summer - and have a great time reading this latest issue of<br />

bioplastics MAGAZINE.<br />

Sincerely yours<br />

Michael Thielen<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Like us on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 3


Content<br />

Imprint<br />

Jul / Aug <strong>04</strong>|<strong>2018</strong><br />

Blow Moulding<br />

14 No Message in the bottle –<br />

The bottle is the message!<br />

18 100% biobased PET bottle<br />

closer to reality<br />

Applications<br />

24 Natural fibres for motorsports<br />

Report/Opinon<br />

26 20 years Tecnaro<br />

Materials<br />

31 New biocomposite for<br />

thermally formable products<br />

33 New compound certified as<br />

biodegradable in soil<br />

42 Multilayer transparent barrierfilms<br />

Coffee capsules & pods<br />

36 Enjoying coffee with compostable<br />

coffee capsules<br />

37 Replacing aluminium with paper<br />

38 Coffee Klatch<br />

40 Bio-PBS to increase benefits<br />

of PLA coffee capsules<br />

41 PürPod 100<br />

From Science & Research<br />

43 Bioplastic from cactus<br />

44 From coffee grounds to plastic<br />

3 Editorial<br />

5 News<br />

10 Events<br />

26 Application News<br />

34 Cover Story<br />

48 Basics<br />

52 10 years ago<br />

54 Suppliers Guide<br />

57 Event Calendar<br />

58 Companies in this issue<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

sb@bioplasticsmagazine.com<br />

Michael Thielen (English Language)<br />

(see head office)<br />

Layout/Production<br />

Kerstin Neumeister<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

10<strong>04</strong> Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 3.600 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified subscribers<br />

(169 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all Information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

bioplastics MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not<br />

necessarily reflect those of Polymedia<br />

Publisher.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher GmbH<br />

unless otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity or legality.<br />

Please contact the editorial office via<br />

mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped in bioplastic envelopes<br />

sponsored by Minima Technology Co.,<br />

Ltd. , Taiwan<br />

Cover<br />

Photo: TGM Hetzmannseder<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

Global L-lactide market set for explosive growth<br />

The global L-lactide market was valued at US$ 781.81<br />

Mn in 2017 and is anticipated to expand at a CAGR of 14.1%<br />

from <strong>2018</strong> to 2026, according to a new report titled "L-lactide<br />

Market: Global Industry Analysis, Size, Share, Growth Trends,<br />

and Forecast, <strong>2018</strong>–2026," published by Transparency Market<br />

Research (TMR).<br />

The main driver behind this growth is the rising demand<br />

for bioplastics. Polylactic acid – PLA – is a commonly used<br />

bioplastics that is derived from L-lactide. Around the globe,<br />

consumers are increasingly indicating a preference for<br />

biodegradable materials as their awareness grows about the<br />

environmental impact of the use of fossil-based materials.<br />

North America accounts for a major share of the global<br />

L-lactide market.<br />

The properties of L-lactide, such as sustainability, its barrier<br />

properties and appearance, make it ideal for use in packaging<br />

applications. Stringent regulations on plastic consumption<br />

in developed regions such as North America and Europe are<br />

expected to have a positive influence on the expansion of the<br />

L-lactide market.<br />

Next to packaging, another area that is likely to stimulate<br />

the growth of the global L-lactide market is that of biomedical<br />

applications.<br />

Demand for L-lactide from various medical fields, such<br />

as controlled drug delivery systems, tissue regeneration,<br />

and medical implants, is on the rise owing to the favourable<br />

biocompatibility and the mechanical properties of the material.<br />

L-lactide is finding increasing use in biomedical applications<br />

such as orthopaedics, drug carriers, facial fracture repair,<br />

tissue engineering, and uteral stents, which is expected<br />

to add to the growth potential of the L-lactide market. The<br />

emergence of nanotechnology and material science using<br />

biomaterials has prompted researchers and manufacturers<br />

of medical devices to come up with advanced technologies<br />

using L-lactide.<br />

L-Lactides are also increasingly being applied in soil<br />

retention sheeting, agricultural films, and waste bags.<br />

Agricultural mulches, seeding strips, and tapes can today<br />

be made from PLA. Mulches help reduce evaporation and<br />

conserve moisture, increase soil temperature, and keep weeds<br />

under control. The successful replacement of petroleumbased<br />

materials will offer new value added markets for<br />

agricultural commodities and reduce the dependence on<br />

foreign crude oil and gas.<br />

The global L-lactide market is dominated by the food &<br />

beverage packaging segment. L-lactides have been used as<br />

packaging materials in the last few years, mainly as containers<br />

for dairy, bakery, and fresh food products. Food containers,<br />

bags and cups, disposable serviceware and utensils,<br />

lamination or coatings for paper and paperboard, foam<br />

products for trays, and other packaging materials and films<br />

manufactured using L-lactide are gaining popularity due to<br />

the favourable material properties and superior performance<br />

of the material. However, the low heat distortion temperature<br />

of L-lactide restricts its use to ambient temperatures.<br />

In terms of consumption, North America accounted<br />

for a major share of the global L-lactide market in 2017.<br />

Implementation of favourable government policies and<br />

regulations on plastic consumption have propelled the<br />

expansion of the L-lactide market in developed countries.<br />

The federal government aims to drive demand for biobased<br />

products through procurement programs. Increased<br />

consumer preference for biodegradable materials and rise in<br />

environmental concerns are anticipated to drive the L-lactide<br />

market in North America. MT<br />

bit.ly/2NKvN5c<br />

Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of the past two months.<br />

The story that got the most clicks from the visitors to<br />

bioplasticsmagazine.com was:<br />

Bio-based multilayer transparent barrier films are now reality<br />

(19 June <strong>2018</strong>)<br />

Four key players in the bioplastics industry - Eurotech Extrusion Machinery,<br />

NatureWorks, Nippon Gohsei and Sukano - have successfully processed a<br />

multilayer transparent bio-based barrier film, offering a potential replacement<br />

for conventional fossil fuel-based structures in dry food packaging...<br />

See also the full article on page 38<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Biocomposite demand driven by<br />

global construction boom, says new report<br />

The vendor landscape for the global market for<br />

biocomposites has seen a significant rise in the number<br />

of manufacturers, leading to intense competition, writes<br />

Transparency Market Research in a recent report.<br />

As the market witnesses the entry of numerous wellestablished<br />

manufacturers of popular composites such as<br />

glass fiber and cotton fiber, the market is expected to become<br />

more competitive in the near future. Despite this, the market<br />

features a vast set of untapped growth opportunities in new<br />

applications across industries such as construction and<br />

automotive.<br />

Tapping these growth opportunities may require strategic<br />

collaborations with companies in emerging economies and<br />

expansion of manufacturing capabilities to effectively serve<br />

the rising demand. Some of the leading companies operating<br />

in the global biocomposites market are Tecnaro, UPM,<br />

FlexForm Technologies, Green Bay Decking, Universal Forest<br />

Products, and Jelu-Werk.<br />

According to the report, the global biocomposites market<br />

will exhibit an impressive 9.46% CAGR over the period<br />

between 2017 and 2025, rising from a valuation of US$4,730.4<br />

mn in 2016 to US$10,549.4 mn by 2025.<br />

Of the key materials used to manufacture biocomposites,<br />

wood presently accounts for a dominant share in the overall<br />

market, thanks to its excellent binding properties and easy<br />

availability. The segment of flax is expected to expand at the<br />

fastest pace over the forecast period, accounting for a notable<br />

share in the overall market by the end of the report’s forecast.<br />

From the geographical standpoint, the market in Asia<br />

Pacific is presently the leading contributor of revenue to the<br />

global biocomposites market, thanks to the rapid pace of<br />

industrialization in emerging economies. The region is also a<br />

key market for biocomposites owing to the massive demand<br />

across industries such as consumer goods, construction, and<br />

automotive.<br />

The key factors working in favor of the global biocomposites<br />

market include stringent government regulations advocating<br />

the increased use of environment-friendly products with the<br />

view of reducing the negative impacts of rising pollution on<br />

the health of environment and global warming. The recyclable<br />

nature of biocomposites, coupled with their much higher<br />

safety quotient as compared to materials such as glass fibers<br />

and carbon fiber when it comes to a number of applications,<br />

could also spell growth for the market.<br />

The easy availability of most raw materials required for the<br />

production of a variety of biocomposites across the globe is<br />

also a key factors expected to work well for the expansion<br />

of the global biocomposites market over the next few years.<br />

However, certain limitations concerning pure biocomposites<br />

in aspects such as mechanical strength, coupled with their<br />

unstable costs and fluctuating availability of raw materials<br />

could cost the market negatively to a certain degree over the<br />

forecast period. MT<br />

tinyurl.com/biocomposites-17-25<br />

Corbion CEO Tjerk de Ruiter appointed as new<br />

EuropaBio Chairman<br />

EuropaBio, the European Association for Bioindustries, has released a statement announcing that its Executive Board and<br />

General Assembly of Members this week confirmed the appointment of Tjerk de Ruiter as Chairman of the association.<br />

De Ruiter is CEO of Dutch industrial biotech innovator Corbion, a global market leader in lactic acid, lactic acid derivatives,<br />

and a leading company in emulsifiers, functional enzyme blends, minerals, vitamins and algae ingredients.<br />

Commenting on his appointment, De Ruiter said: “I am thrilled to become EuropaBio’s new Chairman at a time when our<br />

sector has a great story to tell about the solutions it can provide in response to some<br />

of the bigger questions people and planet are facing today.” EuropaBio, he added, is<br />

uniquely positioned to promote more knowledge about biotech innovation in Europe<br />

and to share the enthusiasm of biotech innovators, researchers and entrepreneurs<br />

with the wider public. “In light of next year’s European elections, one of our first<br />

priorities will be to ensure policymakers understand that Europe's biotech is globally<br />

leading with the innovative solutions the sector provides and that ensuring the right<br />

framework for its growth is key for Europe’s future.”<br />

De Ruiter’s mandate as Chairman is not remunerated and runs until 2020.. MT<br />

www.europabio.org<br />

6 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


News<br />

Bioplastic from frying oil<br />

Used frying oil is a hazardous waste,<br />

available in large quantities around<br />

the world. If it can be used to make<br />

polyhydroxybutyrate (PHB) instead<br />

of having to be treated as waste, the<br />

environment benefits.<br />

Save the date<br />

see page 10-11 for details<br />

Professor Pavel Alexy of the STU Faculty of<br />

Chemical and Food Technology in Bratislava is currently<br />

collaborating intensively with the scientists of the Technical<br />

University of Brno and a commercial company, developing<br />

the technology for processing waste oils to secondgeneration<br />

polyhydroxybutyrate.<br />

The STU team is collaborating with a number of<br />

companies and universities on the practical application<br />

of the material. Among the commercial uses under<br />

consideration are plastic containers, cutlery, packaging<br />

foils and mulch foils.<br />

And together with a design agency called the crafting<br />

plastics! studio, the STU chemical engineers have come<br />

up with an idea of using bioplastics for sunglasses frames;<br />

their design won the 2017 National Design Award in the<br />

category of Value-added Design. It was also nominated<br />

for the German Design Award and currently is exhibited at<br />

the Venice Biennale of Design and Architecture. The young<br />

designers managed to get support for the project through<br />

the Kickstarter.com. crowdfunding portal.<br />

Medical applications also present new opportunities.<br />

The STU is currently collaborating with specialists at the<br />

Comenius University Faculty of Medicine in Bratislava and<br />

the top experts in implants development at the Technical<br />

University in Košice. Bioplastics may serve as temporary<br />

implants supporting complicated fractures. Research is<br />

also being carried out in the field of tissue engineering; in<br />

the laboratories, complete substitute organs are grown on<br />

a bio-substrate that will gradually decompose. MT<br />

Elephant grass is new<br />

local feedstock for<br />

bioplastics<br />

Although indigenous to the sub-tropic, Miscanthus<br />

Giganteus, or elephant grass, as it is more commonly<br />

known, has put down roots in Europe as well.<br />

In the Netherlands, it has been planted around the<br />

country’s major airport, Schiphol, to keep the geese<br />

away. A start-up company is now a making bioplastic<br />

called Vibers from it.<br />

According to Jan-Govert van Gilst elephant grass<br />

contains "‘the same energy value as coal and lots of<br />

cellulose fibers", making it suitable as an alternative<br />

resource to produce various materials. An idealist who is<br />

set on eliminating fossil-based plastic packaging, he saw<br />

potential in the crop and founded his company, NNRGY,<br />

in Honselersdijk, the Netherlands.<br />

Elephant grass is a fast-growing crop, which absorbs<br />

four times as much CO 2<br />

as a forest. It requires neither the<br />

use of pesticides or fertilizer to thrive and is not invasive.<br />

NNRGY developed a biodegradable, compostable<br />

bioplastic called Vibers that is made from elephant grass<br />

and residual product from the potato processing industry.<br />

In 2017, a new film was successfully developed for<br />

the packaging industry. It is thermoformable on existing<br />

machinery and at low temperatures, which saves energy.<br />

It can be processed as biodegradable waste. The seedling<br />

logo has been applied for, however, the testing process is<br />

still ongoing. MT<br />

www.vibers.nl<br />

tinyurl.com/fryingoil2phb<br />

Avantium opened pilot biorefinery<br />

Avantium; Amsterdam, The Netherlands officially opened<br />

a pilot biorefinery for its Zambezi technology in Delfzijl,<br />

Netherlands. The opening ceremonies took place in<br />

Amsterdam on 10 July and in Delfzijl on 13 July.<br />

The Delfzijl plant will pilot Avantium’s latest technology<br />

to convert plant-based non-food feedstock to high purity<br />

industrial sugars and lignin. The industrial sugars are used<br />

in chemistry and fermentation processes to produce a broad<br />

range of durable materials, while lignin is used in energy<br />

generation.<br />

Tom van Aken, Chief Executive Officer of Avantium, called<br />

the opening ‘a milestone in our work to support the transition<br />

to a circular economy’. “We are already looking beyond the<br />

pilot phase. We have a consortium of partners committed to<br />

developing a commercial-scale plant,” he said.<br />

Avantium previously announced it had founded a consortium<br />

to develop an ecosystem for the biorefinery technology. The<br />

consortium consists of AkzoNobel, RWE, Staatsbosbeheer<br />

and Chemport Europe, an incubator for green chemistry. Each<br />

brings specific expertise for the planned commercial-scale<br />

biorefinery.<br />

Gert-Jan Gruter, Chief Technology Officer of Avantium,<br />

said that “glucose is a core building block for the transition<br />

towards a bio-based economy”. He noted that all materials<br />

made from petroleum today can be replaced by with materials<br />

derived from glucose.<br />

Patrick Brouns, regional minister of the province of<br />

Groningen, is pleased to welcome Avantium to Delfzijl, and<br />

the “innovation, green chemistry and highly skilled jobs”<br />

the company is bringing to the region, which fit well with<br />

the existing local chemistry, energy and agricultural sectors<br />

and knowledge institutions. “With Chemport Europe, we also<br />

support the future commercial-scale biorefinery in Delfzijl, ”<br />

he said. MT<br />

www.avantium.com<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 7


News<br />

EU project seeks to improve<br />

sustainability in aviation industry<br />

Modern aircraft are made from synthetic, non-renewable<br />

materials. Many of these are composites such as carbon and<br />

glass-fibre-reinforced plastics that are man-made through<br />

energy-intense processes.<br />

To improve the sustainability of the aviation industry,<br />

researchers are investigating renewable and recycled<br />

materials to replace such composites. However, biobased<br />

and recycled alternatives must meet the strict requirements<br />

required for safe and efficient flight.<br />

The EU-funded ECO-COMPASS project has identified<br />

potential bio-sourced and recycled materials that can be<br />

developed into eco-friendly composites for aircraft. Fibre<br />

reinforcements are used throughout aircraft and can<br />

contribute more than half of their structural mass.<br />

The project team set out to look for alternative materials<br />

to create fibre reinforcements in planes and found that<br />

biobased fibres from plants and recycled carbon fibres have<br />

great potential. The team has also developed a biobased resin<br />

system that has promising properties for a range of in-aircraft<br />

applications.<br />

“The bio-materials, recycled carbon fibres and bio-resins<br />

should be suitable for use in the secondary structure and<br />

interior of aircraft,” says project coordinator Jens Bachmann<br />

of the German Aerospace Center (DLR, Deutsches Zentrum<br />

für Luft- und Raumfahrt). “They typically require less energy<br />

to produce than the materials used at present.”<br />

Collaboration with China<br />

Key to the success of this project is the collaboration with<br />

researchers in China and industrial partners such as Airbus<br />

and Comac. By working together on a global scale, experts are<br />

combining their knowledge and expertise so that sustainable<br />

composites will be available to the aviation industry globally.<br />

“The aviation industry continues to grow worldwide – global<br />

partnerships help us share knowledge and make rapid<br />

improvements to technologies,” notes Bachmann. “This<br />

collaboration has helped us learn more about fibres grown in<br />

China, such as ramie, that could be a good alternative to flax<br />

which is a standard fibre grown and used in Europe.<br />

“Now, we are improving their properties by combining<br />

Chinese expertise in materials development with European<br />

expertise in modelling and simulation.”<br />

Identifying the materials to develop<br />

In future, the composite materials identified and developed<br />

during this project could become a part of planes in the<br />

form of interior panelling, gear doors, winglets and other<br />

secondary structures. Initial results have shown that biobased<br />

composites made from flax and ramie plant fibres have the<br />

potential to be used in natural-fibre-reinforced plastics for<br />

aviation.<br />

In addition, the Sino-European team is developing a new<br />

biobased epoxy resin made from rosin derivatives obtained<br />

from conifer plants. It is likely that this technique of embedding<br />

natural fibres into the resin will enable one component of<br />

the fibre-reinforced composite to be replaced with biobased<br />

constituents.. MT<br />

tinyurl.com/biocomposites-aviation<br />

United Caps added bio-PE caps to its portfolio<br />

UNITED CAPS, an international manufacturer of caps and closures, has announced it is making significant progress on its<br />

growth initiatives.<br />

The company has completed an extension of its R&D facility in Messia, France, to meet the demands of business growth and<br />

deliver faster time to market for customers. It also recently acquired Spanish closures company Embalatap and has added<br />

bioplastics-based GREENER closures sourced from sugar cane and new anti-counterfeiting measures to its portfolio.<br />

In pursuit of more environmentally sustainable solutions, Uited Caps has collaborated with<br />

Braskem to deliver eco-friendly United Caps Greener bio-sourced plastic caps and closures<br />

made from sugar cane as an addition to the United Caps product portfolio.<br />

"We already have added bioplastics-based products to our portfolio: such as the victoria<br />

closure, a 30/25 screw closure designed for still drinks; and the Proflat Seal, ideal for dairy<br />

products and still drinks," said Benoit Henckes, CEO of United Caps. "These are being warmly<br />

received by our customers, and we expect their availability to drive new customer interest<br />

as well."<br />

www.unitedcaps.com<br />

generic photo<br />

8 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


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Cover-Story<br />

New convenient and compostable waste<br />

bags have hit German retail stores<br />

Frankenthal, Germany-based RKW has launched a<br />

biodegradable star-sealed bag for organic household waste<br />

in Germany. Certified as fully compostable, it is also the first<br />

T-shirt star-sealed bag available on the market made from<br />

more than 50 % renewable PLA - material.<br />

For family-owned film manufacturer<br />

RKW, sustainability is an integral part of its<br />

business mission, and this includes the use<br />

of biodegradable or biobased films. RKW<br />

Vietnam, which is specialized in consumer<br />

packaging, produces the compostable bags<br />

in Ho Chi Minh City.<br />

Star-sealed, the new bag is created<br />

without gussets and sealed in a single spot,<br />

making it highly practical and virtually leakproof.<br />

For organic waste, many people use<br />

paper bags, which, while fully biodegradable, tend to become<br />

soggy and tear easily when taken out of the bin. The bags come<br />

with carrying handles that can be used to tie them shut, and<br />

the star-sealed bottom that consumers are familiar with from<br />

conventional plastic-based trash bags. Fully compostable and<br />

hence suited for organic waste, the bags will be supplied by<br />

major retailers.<br />

“RKW is a pioneer on the market,” says Manh-Hung Ngo,<br />

Product Manager at RKW Vietnam. “So far,<br />

bags with up to 40 % renewable content have<br />

been available in markets such as France<br />

or Italy. We were able to design bags with a<br />

significant higher proportion. Hence, these<br />

waste bags are another milestone towards<br />

a more sustainable future.” The bag is fully<br />

compostable and certified to European<br />

standard EN13432 by the DIN Certco<br />

institute in Berlin (Germany).<br />

The bag is suited for bins with different<br />

shapes and prevents the leakage of liquids.<br />

Multiple layers strengthen the bottom,<br />

avoiding damage to the bag. Combining the practical features<br />

with benefits in terms of sustainability, the new bags are a<br />

more environmentally friendly and a convenient option for<br />

consumers. MT<br />

www.rkw-group.com<br />

ALL ABOUT POLYMERS<br />

DKT <strong>2018</strong>-Vorbericht<br />

DKT <strong>2018</strong> preview<br />

tpe markets<br />

POLYURETHANES MAGAZINE INTERNATIONAL<br />

03/<strong>2018</strong> JUNE/JULY<br />

Interview with R. Trippler, Hennecke &<br />

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Blowing agents<br />

Polyisocyanurate insulation<br />

Additives for PIR rigid foams<br />

YOUR MACHINES AT YOUR<br />

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FORUM FÜR DIE POLYURETHANINDUSTRIE<br />

PU MAGAZIN<br />

03/<strong>2018</strong> Juli<br />

Interview mit N. Beyl, Fa. KraussMaffei<br />

Interview mit A. Fi l, Fa. Fi l<br />

Europäischer Weichschaummarkt<br />

CO 2 -basierte Polyole<br />

Polyisocyanurat-Dämmstoffe<br />

QUALITY PERFORMS.<br />

Qualität von LANXESS<br />

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SAVE<br />

THE DATE<br />

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Prognose für den Naturkautschukmarkt<br />

Amine in Kieselsäure/Silan-NR-Systemen<br />

Entwicklungen für Lkw-Reifen<br />

Schwefeldiffusion in Rezyklatmischungen<br />

DESMA 4.0<br />

PRODUKTE UND PROZESSE<br />

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Your experts in rubber and<br />

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24/7<br />

Outlook for the NR market<br />

Shape memory polymers<br />

CO 2 diffusivity<br />

Magazine for the Polymer Industry<br />

Revisiting sulfur vulcanisation<br />

The Drop That Makes The Difference<br />

Hansen & Rosenthal is the Producer<br />

of Anti Ozone Waxes and Plasticizers<br />

sustainable edpm for tpv<br />

high molecular weight mineral oil<br />

3d printing of tpe<br />

dkt <strong>2018</strong> preview<br />

<br />

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info@hexpolTPE.com<br />

www.hexpolTPE.com<br />

<br />

<br />

www.pu-magazin.de<br />

71. Jahrgang, Juni <strong>2018</strong><br />

06| <strong>2018</strong><br />

Volume 13, June <strong>2018</strong><br />

3| <strong>2018</strong><br />

Volume 9, April <strong>2018</strong><br />

2| <strong>2018</strong><br />

info@gupta-verlag.de · www.gupta-verlag.com<br />

Stay informed with our free newsletters:<br />

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bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 9


Events<br />

organized by<br />

Co-organized by Jan Ravenstijn<br />

www.pha-world-congress.com<br />

Programme: 1st PHA platform World Congress<br />

Tuesday, Sep <strong>04</strong>, <strong>2018</strong><br />

08:45-09:15 Jan Ravenstijn Biomaterials Consulting Dealing with the opportunities and challenges of the PHA-platform.<br />

09:15-09:40 Mats Linder – circular economy consultant The role of PHA in a circular economy for plastics<br />

09:40-10:05 Andrew Falcon, FullCycle Bioplastics A Circular Economy Solution: PHA Bioplastics from Organic Waste<br />

10:05-10:30 Michael Carus, nova Institute<br />

11:10-11:35 Jos Lobée, Modified Materials<br />

Production capacities of bio-based polymers – status and outlook & political and<br />

social framework for further growth<br />

Replacing lead weights in angling, the long road from obvious<br />

problem to actual change.<br />

11:35-12:00 Erwin LePoudre, Kaneka Marketing of Biodegradable Polymer PHBH as a Solution to Plastic Waste <strong>Issue</strong>s<br />

Phil van Trump, Danimer<br />

12:00-12:30<br />

& Garry Kohl, PepsiCo<br />

Applications of PHA polymers in Barrier food packaging films<br />

12:30-12:55 Eligio Martini, MAIP The first biotechnopolymer: PHBH compounds, e.g. for electrical switches (ABB)<br />

14:05-14:30 Remy Jongboom, Biotec Industrial applications of PHBH in compounds<br />

14:30-14:55 Harald Kaeb, narocon Pitfalls and opportunities for marketing PHA products<br />

14:55-15:20 Sam Deconinck, OWS Biodegradation of PHAs: not simply a fixed feature<br />

Eike Langenberg &<br />

15:55-16:20<br />

Carsten Niermann, FKuR<br />

Meet the needs for future legislations: Innovative PHA compounds<br />

16:20-16:55 Fred Bollen, LifetecVision<br />

Exploiting competitive advantage and creating market attractiveness<br />

for PHA-polymers<br />

16:55-17:20 Karel Wilsens, AMIBM Nucleating agents for PHAs and other biopolymers<br />

Wednesday, Sep. 05, <strong>2018</strong><br />

08:40-09:05 Lenka Mynářová, Hydal/Nafigate PHA – Circular Economy Concept<br />

09:05-09:30 Ruud Rouleaux, Helian Polymers PHBV, manufacturing, applications and its use in 3D printing compounds.<br />

09:30-09:55 René Rozendal, Paques<br />

09:55-10:20 Martijn Bovee & Leon Korving – Phario High quality PHBV from wastewater<br />

10:55-11:20 Christophe Collet, Scion Research From pine to PHA products<br />

11:20-11:45 Li Teng, Bluepha<br />

Demonstration of PHBV production from waste streams at large scale: the link to<br />

the PHBV market<br />

Industrial-scale Low-cost P(3HB-co-4HB) Production via an open<br />

Fermentation Process<br />

11:45-12:10 Stefan Jockenhövel, AMIBM Role of Biodegradable Polymers for (Regenerative) Medicine<br />

12:10-12:35 Murray Hasinoff, Purcell Agri-Tech PHA coating for slow release fertilization<br />

13:50-14:15 Guy Buyle, Centexbel The use of PHA polymers for textile applications<br />

14:15-14:40 Molly Morse, Mango Materials Production of PHA-polymers from waste methane<br />

14:40-15:05 Shunsuke Sato, Kaneka<br />

Fermentative production of PHBH and metabolic engineering for regulation of its<br />

material properties<br />

15:40-16:05 Urs Hänggi, Biomer Virgin PHB has thermoplastic properties, but is not a thermoplast<br />

16:05-16:30 Silvia Kliem, IKT, Univ. Stuttgart Impact modification of PHB by building of a blockcopolymer<br />

16:30-17:05 Pieter Samyn, Hasselt University<br />

Formulation and processing of PHB with fibrillated cellulose for nanocomposite<br />

films and paper coatings<br />

Subject to changes. Please visit the conference website<br />

for the current version of the programme. Here you also<br />

find more info on the speakers ans well as abstracts of all<br />

presentations<br />

10 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Automotive<br />

Register now<br />

<strong>04</strong>-05 Sep <strong>2018</strong><br />

Cologne, Germany<br />

organized by<br />

Co-organized by<br />

Jan Ravenstijn<br />

www.pha-world-congress.com<br />

PHA (Poly-Hydroxy-Alkanoates or polyhydroxy fatty acids)<br />

is a family of biobased polyesters. Examples for such<br />

Polyhydroxyalkanoates are PHB, PHV, PHBV, PHBH and<br />

many more. That’s why we speak about the PHA platform.<br />

Depending on the type of PHA, they can be used for applications<br />

in films and rigid packaging, biomedical applications,<br />

automotive, consumer electronics, appliances, toys, glues,<br />

adhesives, paints, coatings, fibers for woven and non-woven<br />

and inks. So PHAs cover a broad range of properties and<br />

applications.<br />

Also depending on the type, most PHAs are biodegradable in<br />

a wide range of environments, such as industrial and home<br />

composting, anaerobic digestion (AD), in soil, fresh- and even<br />

seawater.<br />

As PHAs are gaining more and more interest, bioplastics<br />

MAGAZINE and Jan Ravenstijn are now organizing the 1st PHAplatform<br />

World Congress on 4-5 September <strong>2018</strong> in Cologne<br />

/ Germany.<br />

Platinum Sponsor:<br />

Gold Sponsor:<br />

Silver Sponsor:<br />

Bronze Sponsor:<br />

1 st Media Partner<br />

Media Partner:<br />

MODERN<br />

PLASTICS<br />

INDIA<br />

Supported by:<br />

bioplastics MAGAZINE [03/18] Vol. 13 11


News<br />

IKEA and Neste go for bio-PE<br />

IKEA and Neste are now able to utilize renewable residue<br />

and waste raw materials, such as used cooking oil, as well<br />

as sustainably-produced vegetable oils in the production<br />

of plastic products. The pilot at commercial scale starts<br />

during fall <strong>2018</strong>. It will be the first large-scale production of<br />

renewable, biobased polypropylene plastic globally.<br />

Ikea wants to have a positive impact on people and the<br />

planet while growing the business, which includes using more<br />

renewable and recycled materials and explore new materials<br />

for Ikea products. As part of this journey, Ikea is working to<br />

change all of the plastic used in Ikea products to plastic based<br />

on recycled and/or renewable materials by 2030.<br />

By changing to plastic based on renewable material, Ikea<br />

can secure the production for the future, and eliminate the<br />

need for extraction of finite fossil fuel for the purpose of<br />

making plastic and thus reduce the impact on climate change.<br />

One of the ongoing projects towards eliminating virgin fossilbased<br />

raw materials in plastic products is a collaboration<br />

between Ikea and Neste, which was initiated in 2016. Thanks<br />

to this collaboration, Ikea and Neste are now able to turn<br />

waste and residue raw materials, such as used cooking oil, as<br />

well as sustainable vegetable oils into polypropylene (PP) and<br />

polyethylene (PE) plastic.<br />

“This new material represents a significant step towards<br />

a fossil free future. No one has ever before been able to<br />

produce PP<br />

plastic from<br />

a fossil-free<br />

raw material<br />

other than<br />

on a laboratory scale. Together with Neste, we are ensuring<br />

that there is an opportunity to scale up the production of this<br />

material”, says Erik Ljungblad, Category Manager Plastic<br />

Products at Ikea of Sweden.<br />

“The production of biobased plastics at a commercial<br />

scale is a major achievement in the cooperation between<br />

Neste and Ikea, while it also marks a significant milestone<br />

in Neste’s strategy. Ikea is the first company to benefit from<br />

the developed supply capability that helps companies and<br />

brand owners towards replacing fossil-based raw materials<br />

with sustainable biobased raw materials,” says Senior Vice<br />

President Tuomas Hyyryläinen from Neste’s Emerging<br />

Businesses business unit.<br />

The pilot at commercial scale of PP and PE plastic, chosen<br />

to contain 20 % renewable content, will start during fall <strong>2018</strong>.<br />

The production of biobased plastics will be based on Neste’s<br />

100 % renewable hydrocarbons. Ikea will use the new plastic<br />

in products that are part of the current product range, such<br />

as plastic storage boxes, starting with a limited number of<br />

products. As capacities improve, more products will follow. MT<br />

www.neste.com | www.ikea.com<br />

nova-Institute Events in <strong>2018</strong>/2019<br />

18 September <strong>2018</strong> · Airport Cologne/Bonn, Germany<br />

www.bio-based.eu/nova-sessions<br />

1 – 2 October <strong>2018</strong> · Maritim Hotel, Cologne, Germany<br />

www.REFAB.info<br />

6 – 8 November <strong>2018</strong> · Messe Stuttgart, Germany<br />

www.composites-europe.com<br />

20 – 21 March 2019 · Maternushaus, Cologne, Germany<br />

www.co2-chemistry.eu<br />

16 th International Conference<br />

of the European Industrial<br />

Hemp Association<br />

June 5 th – 6 th 2019<br />

15-16 May 2019 · Maternushaus, Cologne, Germany<br />

www.bio-based-conference.com<br />

5-6 June 2019 · Maternushaus, Cologne, Germany<br />

www.eiha-conference.org<br />

Contact: Mr. Dominik Vogt, +49 (0) 2233 48 14 49, dominik.vogt@nova-institut.de · All conferences at www.bio-based.eu<br />

12 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


io PAC<br />

organized by bioplastics MAGAZINE<br />

call for papers<br />

biobased packaging conference 28 - 29 may 2019 düsseldorf<br />

supported by<br />

Coorganized by<br />

www.greenserendipity.nl<br />

Packaging is necessary for:<br />

» protection during transport and storage<br />

» prevention of product losses<br />

» increasing shelf life<br />

» sharing product information and marketing<br />

BUT :<br />

Packaging does not necessarily need to be made from petroleum based plastics.<br />

Most packaging have a short life and therefore give rise to large quantities of waste.<br />

Accordingly, it is vital to use the most suitable raw materials and implement good<br />

‘end-of-life’ solutions. Biobased and compostable materials have a key role to play<br />

in this respect.<br />

Biobased packaging<br />

» is packaging made from mother nature‘s gifts.<br />

» can be made from renewable resources or waste streams<br />

» can offer innovative features and beneficial barrier properties<br />

» can help to reduces the depletion of finite fossil resources and CO 2<br />

emissions<br />

» can offer environmental benefits in the end-of-life phase<br />

» offers incredible opportunities.<br />

That‘s why bioplastics MAGAZINE (in cooperation with Green Serendipity is now<br />

organizing the third edition of bio!PAC<br />

Call for Papers now open: Please send your proposal to mt@bioplasticsmagazine.com<br />

www.bio-pac.info<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 13


Events<br />

Nature always finds the solution<br />

Bio-on inaugurated first plant for the production of special PHA bioplastics<br />

By Michael Thielen<br />

Bio-on (Bologna, Italy), a company that describes itself<br />

as an Intellectual Property Company (IPC) that supplies<br />

technologies to produce or use Polyhydroxyalkanoates-<br />

(PHAs) through licenses, officially inaugurated a production<br />

plant of its own during a ceremony on June 20 th . The new plant<br />

will produce PHB and PHBVV bioplastics for high added value<br />

niche markets such as the microbeads used in the cosmetics<br />

sector.<br />

All PHA bioplastics developed by Bio-on under the brand<br />

name Minerv are made from renewable plant sources<br />

with no competition with food supply chains. They guarantee<br />

the same thermo-mechanical properties as comparable<br />

conventional plastics with the advantage of being 100% ecosustainable<br />

and naturally biodegradable<br />

The new plant is located in Castel San Pietro Terme, near<br />

Bologna, Italy. The theme of the grand opening was “La natura<br />

trova sempre la soluzione” (Nature always finds the solution).<br />

In an impressive multimedia presentation, Bio-on’s<br />

Chairman and CEO Marco Astorri first showed to the more<br />

than 300 invited guests the shocking reality of marine<br />

pollution caused by plastic waste. Video clips showed birds<br />

on a picturesque Pacific atoll, dead from ingesting bottle tops<br />

and other litter they had mistakenly thought to be food.<br />

Astorri then showed a few ancient 1950s commercials and<br />

the famous scene from “The Graduate”, in which plastics are<br />

lauded as the material of the future, The further presentation<br />

focused on the use of microbeads in cosmetics: an exemplary<br />

case of plastic waste that is literally washed down the drain.<br />

These microbeads, which serve as thickeners or stabilisers<br />

in such widely used products as lipstick, lip gloss, mascara,<br />

eye-liner, nail polish, creams, shampoo, foam bath and even<br />

toothpaste, pollute the environment; once they are rinsed off<br />

after use, they become a permanent part of the natural cycle:<br />

they are swallowed by plankton in the rivers and seas and<br />

thus enter the food chain, to ultimately end up on our plates.<br />

The level of pollution is so serious that the USA was the<br />

first country to bring in a law (Microbead-Free Waters Act<br />

of 2015) banning the use of oil-based polymers in body care<br />

products. Some countries, such as Canada, UK, Sweden and<br />

France, recently followed suit while others, such as Ireland,<br />

Netherlands, Italy, have announced they will do so, as stated<br />

in Bio-on’s press release accompanying the inauguration.<br />

This provided a convenient segue to introduce PHAs as a<br />

family or platform of biobased and biodegradable polyesters<br />

in general - and the Minerv PHAs which are to be produced in<br />

the new plant, in particular. The first product to be produced<br />

at the new plant will be Minerv Bio Cosmetics, the bioplastic<br />

microbeads for cosmetics designed to replace the oil-based<br />

and non-biodegradable plastic particles currently used<br />

Using Minerv Bio Cosmetics bioplastic in cosmetics<br />

products eliminates these pollutants because the micro<br />

particles of bioplastic are naturally biodegradable in water<br />

and, therefore, do not enter the food chain. What is more,<br />

the biopolymer developed at the Bio-on laboratories actually<br />

decomposes into a nutrient for some micro-organisms and<br />

plants present in nature. The benefit for the environment is<br />

therefore two-fold.<br />

In his presentation Marco Astorri went on to introduce<br />

Professor Jian Yu from the University of Hawaii in Manoa,<br />

with whom Bio-on has been working for 10 years on<br />

the development of their Minerv PHA products. And the<br />

cooperation will continue. “We have big and (still) secret plans<br />

for the future,” Marco Astorri said with a smile.<br />

The new plant is located on a plot measuring some<br />

30,000 m 2 ; it has 3,700 m 2 covered space and 6,000 m 2 land<br />

for development. The current production capacity is 1,000<br />

tonnes per year, rapidly expandable to 2,000 tonnes/a. The<br />

plant, managed by Bio-on Plants, the division responsible<br />

for production, future expansion and new plants, is equipped<br />

with the very latest technologies and the most advanced<br />

research laboratories. Here, over 20 researchers in the CNS<br />

division (Cosmetic, Nanomedicine & Smart Materials) can<br />

test new carbon sources from agricultural waste to produce<br />

new types of biodegradable bioplastic and increase the<br />

range of technologies offered by Bio-on. The company also<br />

demonstrates its focus on sustainability in its choice of site,<br />

opting to convert a former factory without occupying any new<br />

land. The overall investment in the production hub and new<br />

research laboratories is EUR 20 million.<br />

“We are very pleased because since March 2017, when the<br />

first stone was laid, we have kept to our schedule and kept<br />

the promises we made to the market,” says Marco Astorri.<br />

“Our technicians and partners have been incredibly reliable<br />

throughout the process.”<br />

“Like all complex industrial plants, the new production hub<br />

is running a series of tests before becoming fully operational<br />

in autumn. The entire production cycle is run from an<br />

innovative control room at the heart of the plant,” explains<br />

Riccardo Casoni, Bio-on Plants director, “and this is where<br />

the entire industrial process will be tested before production<br />

begins 24/7.<br />

The new production hub is also the headquarters of the<br />

Business Unit RAF (Recovery And Fermentation), which<br />

develops and optimises bioplastic fermentation and extraction<br />

processes to obtain the best possible product yield; and<br />

CNS (Cosmetic, Nanomedicine & Smart Materials), which<br />

uses cutting-edge scientific equipment to test new types of<br />

bioplastic and develop new applications. The areas of operation<br />

are Cosmetics, Nanomedicine, Biomedical, Nutraceuticals,<br />

Bioremediation, Organic Electronics and Advanced Materials.<br />

CNS laboratories are the base for over 20 researchers from<br />

various parts of the world and many different scientific<br />

disciplines, such as chemistry, physics, biology, pharmacy,<br />

14 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Save the date<br />

Events<br />

see page 10-11 for details<br />

materials engineering, biotechnologies, electronics, and mathematics<br />

with an average age of 30.<br />

In the meantime Bio-on announced that it has successfully<br />

completed the first test phase. So far, all tests have been successful<br />

and performed on schedule. “As announced during the inauguration,<br />

we expect to be fully operational by autumn” explained Riccardo<br />

Casoni, “and to be able to produce and to market as early as <strong>2018</strong> a<br />

quantity of PHAs micro powders of about 150 tonnes”.<br />

“Respecting the project deadlines and being able to increase the<br />

production is fundamental”, said Marco Astorri, “since it does not escape<br />

anyone that the new European directive on the reduction of pollution<br />

caused by traditional plastic, which the European Parliament will have<br />

to approve in September, will open a huge market for biodegradable<br />

plastics. And Bio-on has a unique competitive advantage since our<br />

bioplastic is 100 % biodegradable not only on land but also in water”.<br />

Marco Astorri opening the presentation<br />

In a separate meeting on the sidelines of the inauguration in June<br />

bioplastics MAGAZINE spoke to Diego Torresan, Business Development<br />

Manager of Bio-on.<br />

Asked about my introductory sentence of this article, Diego confirmed<br />

tha Bio-on is not the standard biopolymer producer. Their core business<br />

is and will continue to be related to the intellectual properties. So their<br />

main customers are companies that own the biomass, or plastic users<br />

that want to convert from oil-based to renewably based plastics or as<br />

a third group companies that want to buy the biomass and produce<br />

PHA for the plastic users. And the inauguration of the new plant<br />

- a reference plant - does not change this core business, as Diego<br />

emphasised. The products from the new plant - powders - will be used<br />

and sold as powders, mainly for these cosmetic applications or to do<br />

more research, “just like the polymers coming from the pilot plant that<br />

we are running since 2011”, Diego said.<br />

Apart from the cosmetics sector, Bio-on sees a lot of similar niche<br />

markets, such as nanomedical applications, industrial 3D-printing,<br />

and a lot of application in agriculture, e.g. for controlled release<br />

encapsulation and the like. Possible market segments can also be<br />

found in structural applications such as furniture, automotive parts<br />

or toys. Another interesting field of application the so-called bioremediation.<br />

bioplastics MAGAZINE reported in issue <strong>04</strong>/2017 about Bioon’s<br />

revolutionary new technology to eliminate oil pollution in the sea<br />

within 3 weeks.<br />

Claudio Luti, President of Kartell (left) and Marco Astorri<br />

Grand Opening Ceremony and Party<br />

Another question concerned the abovementioned renewable plant<br />

sources with no competition with food supply chains. Diego explained<br />

that the sources for Minerv resins are agro-industrial co-products such<br />

as the molasses from sugar cane, crude glycerol from the biodiesel<br />

production or co-products from dates to name just a few.<br />

Concerning potential pressure from shareholders Diego said that<br />

the company that was founded and owned by Marco Astorri and Guy<br />

Cicognani only sold 10% of the company to shareholdes in 2014. Today<br />

30% is owned by shareholders, so there is no pressure influencing any<br />

decisions.<br />

www.bio-on.com<br />

The new plant (Photo:Bio-on)<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 15


Blow moulding<br />

No message in the bottle –<br />

NaKu’s PLA bottle offers a responsible alternative<br />

Established in 2007, Vienna, Austria-based NaKu has<br />

garnered acclaim for its use of innovative technologies<br />

in the development of sustainable packaging solutions.<br />

NaKu launched its first plant-based bottle for exclusive<br />

customers back in 2011 and has since built up extensive<br />

experience in meeting the challenges regarding production,<br />

filling and shelf life.<br />

“Our NaKu bottle is now used by special customers, who<br />

are breaking new ground in packaging solutions,” says<br />

Johann Zimmermann, Managing Director of NaKu.<br />

Conventional bottles claim to be made without harmful<br />

substances such as phthalates, Bisphenol A (BPA), antimony<br />

or endocrine disrupting substances. The NaKu bottle offers<br />

all of that, but much more as well. As it is made from PLA,<br />

the NaKu bottle is derived from 100 % renewable resources.<br />

Its uniqueness is due to the main ingredient, lactic acid, a<br />

natural compound that is also produced and metabolized<br />

in the human body. Non-toxic and environmentally friendly,<br />

lactic acid is naturally present in many foodstuffs, and<br />

therefore also edible (E270, consumption without any limit<br />

according to EFSA positive listing 2011).<br />

The PLA used to produce the NaKu bottle is obtained from<br />

sugar or starch. The bottle is about 10 times cheaper and 20<br />

times lighter than comparable solutions made out of glass.<br />

It is the ideal packaging material for still water, fruit<br />

juices, smoothies and milk products as well as solid foods,<br />

including pills, herbs, sweets, nutritional supplements and<br />

much more. Even cosmetics may someday be packaged in<br />

PLA packaging.<br />

“For me as a (bio)plastics technician, it doesn’t matter<br />

which kind of form I produce. Of course I am also able to<br />

produce cans, container, basins, and bowls etc… whatever<br />

you need for your product package,” asserts Johann<br />

Zimmermann.<br />

The NaKu bottle is fully biodegradable and can be<br />

incinerated in a carbon neutral natural cycle. But PLA is<br />

also recyclable, which is the preferred option for the NaKu<br />

bottle in the future. However, until production of the bottles<br />

reaches the critical volume needed to make recycling<br />

commercially feasible , waste-to-energy incineration<br />

remains, at least for now, the best end- of-life solution.<br />

“Our aim is the use of natural plastics to design the next<br />

generation of convenient products satisfying both economic<br />

and ecologic requirements. Short transport distances and<br />

local production is the key to keep this cycle as small as<br />

possible,” Zimmermann says, thereby setting the bar high.<br />

To meet this standard, the material must have a minimal<br />

environmental impact and comply with the concept of<br />

closed cycles (cradle to cradle). The properties of the<br />

material used for the bottle are very similar to PET and it is<br />

easy to process on conventional machines. Hence there is<br />

no need to buy new equipment in order to produce the PLA<br />

bottle. Due to the 7 % weight advantage, fewer transports<br />

are required, and CO 2<br />

emissions can be drastically reduced.<br />

Further reduction in emissions – up to by 50 % - is possible<br />

during the production process itself, as processing takes<br />

place at lower temperatures and requires less energy. The<br />

carbon footprint of these bottles is 75 % lower compared to<br />

glass bottles.<br />

16 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Blow moulding<br />

the bottle is the message!<br />

to conventional options<br />

By:<br />

Johann Zimmermann<br />

NaKu, Vienna, Austria<br />

The material is biodegradable under certain conditions.<br />

However, this should be communicated very carefully, as<br />

it should not encourage people to litter. Biodegradability<br />

is never an excuse for littering nor is it a solution for<br />

littering. Proper disposal, whether through waste-toenergy<br />

incineration, recycling (when feasible) or industrial<br />

composting where possible, should always to be pursued.<br />

The NaKu bottle is safe to use, light, break resistant and<br />

cheap. More importantly, it offers options for responsible<br />

disposal at the end of its life cycle and is the first plantbased<br />

bottle that leaves no trace behind, either in the body<br />

or in nature.<br />

In a nutshell: the innovative NaKu bottle is clear and<br />

bright, can be dyed and individual designed, it is stiff and<br />

firm, break resistant, safe to use, 7 % lighter than PET,<br />

suitable to food, stable to oils, fats and water. The bottle can<br />

be used at temperatures up to 55-65 °C. First transparent<br />

prototypes can withstand 90°C and NaKu is working to<br />

improve this. More importantly, being reusable, recyclable<br />

and biodegradable under certain conditions it offers options<br />

for responsible disposal at the end of its life cycle. And it<br />

is available for competitive prices. NaKu also offers caps<br />

made of bio-PE as well as compostable PLA labels and<br />

shrink sleeves.<br />

The bottle made of plants is the first of its kind that leaves<br />

no trace behind in the body or in nature.<br />

www.naku.at<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 17


Blow moulding<br />

100 % biobased PET bottle<br />

closer to reality<br />

Commercializing cost-competitive renewable aromatics<br />

Momentum is building as Anellotech, headquartered at Pearl River New York, USA, moves closer to<br />

commercializing its Bio-TCat TM catalytic technology and developing a 100 % biobased PET bottle.<br />

A<br />

sustainable technology company, Anellotech is focused<br />

on the innovative production of cost-competitive<br />

renewable chemicals and fuels from non-food<br />

biomass. Their Bio-TCat technology uses efficient thermal<br />

catalytic processes to converts biomass feedstocks materials<br />

(e.g. wood, sawdust, sugar cane bagasse, and other<br />

non-food materials) into BTX aromatics (a mixture of benzene,<br />

toluene and xylene) which are chemically identical to<br />

petroleum-based counterparts. They can be used in a range<br />

of chemical applications and as a biofuels blendstock for<br />

gasoline.<br />

The first shipment of BTX has recently been sent to joint<br />

development partners IFPEN and its subsidiary Axens (both<br />

Rueil-Malmaison, Paris, France) for purification studies to<br />

make bio-paraxylene – the key aromatic chemical needed<br />

to make 100% renewable beverage bottles a reality. Bioparaxylene<br />

from TCat-8 ® will be used to make purified<br />

terephthalic acid (PTA) and subsequently 100% bio-based<br />

PET bottles a reality. The other monomer, monoethylene<br />

glycol (MEG) to make fully biobased PET is already<br />

commercially available made from sugar cane.<br />

BTX aromatics are currently used to make commodity<br />

plastics such as polyester, polystyrenes, polycarbonates,<br />

nylons and polyurethanes, which are subsequently used<br />

to manufacture consumer goods such as food packaging,<br />

clothing, footwear, carpeting, automotive and electronic<br />

components – as well as beverage bottles. Creating<br />

biobased BTX aromatics from renewable materials could<br />

dramatically alter the basic raw material sourcing for a<br />

wide range of consumer goods with important sustainability<br />

implications for society.<br />

Striving for 100 % bio-based<br />

Anellotech knows that strategic collaboration is key for<br />

faster and more efficient technology development. One of<br />

their main partnerships is with global consumer beverage<br />

company Suntory (Minato, Tokyo, Japan). Anellotech has<br />

collaborated with them since 2012 to advance development<br />

and commercialization of cost-competitive bio-aromatics,<br />

including bio-paraxylene.<br />

Suntory currently uses plant-derived MEG (30 %) for its<br />

Mineral Water Suntory Tennensui ® brands. Together, the<br />

two companies want to create a 100 % biobased PET bottle<br />

through this alliance, part of their joint commitment to<br />

sustainable business practices.<br />

Work is progressing to make this a reality. The first steps<br />

towards making prototype bottles have already begun. Since<br />

the announcement of a successful two-week continuous<br />

18 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Blow moulding<br />

trial in March <strong>2018</strong> in Anellotech’s pilot plant in Silsbee,<br />

Texas, USA, over 1,200 hours of cumulative on-stream time<br />

have been achieved at TCat-8, while BTX has been generated<br />

for product testing and evaluation and process development<br />

data collected for future commercial plant design.<br />

David Sudolsky, President & CEO of Anellotech, said<br />

“Following our announcements earlier this year on process<br />

development and continuous operation, we are glad that<br />

significant progress continues at our TCat-8 pilot plant. We<br />

continue to move the technology towards commercialization<br />

and shipping the pilot plant’s product for downstream<br />

evaluation is another major milestone. Having collaborated<br />

with Suntory since 2012 to advance development of costcompetitive<br />

bio-aromatics, we hope bio-based plastics<br />

made from our Bio-TCat process and a 100 % biobased<br />

(PET) bottle soon become a reality.”<br />

Anellotech is keen to partner with other innovative<br />

consumer product companies and brand owners aiming<br />

to meet sustainability goals with a low carbon footprint<br />

technology using non-food biomass feedstock. Producing<br />

BTX aromatics using the Bio-TCat technology can<br />

dramatically reduce industrial carbon footprints and provide<br />

a reliable and economical source of bio-aromatics.<br />

A biobased future is a more sustainable future<br />

If the industry can ensure performance, delivery and<br />

quality, the renewable chemicals sector will help take biobased<br />

chemicals into the mainstream.<br />

Anellotech is confident that biobased plastics made<br />

from its Bio-TCat process are becoming ever-closer to<br />

commercial status and they hope the dream for a 100 %<br />

bio-based bottle soon becomes a reality. MT<br />

www.anellotech.com<br />

Join us at the<br />

13th European Bioplastics<br />

Conference<br />

– the leading business forum for the<br />

bioplastics industry.<br />

4/5 December <strong>2018</strong><br />

Titanic Chaussee Hotel<br />

Berlin, Germany<br />

REGISTER<br />

NOW!<br />

@EUBioplastics #eubpconf<br />

www.european-bioplastics.org/events<br />

For more information email:<br />

conference@european-bioplastics.org<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 19


Blow Moulding / Bottle Applications<br />

New bio-MEG<br />

demonstration plant<br />

Avantium N.V., a leading technology development<br />

company and forerunner in renewable chemistry, has<br />

started construction of a new demonstration plant<br />

that will help advance the production of bio-based monoethylene<br />

glycol (MEG) made directly from renewable sugars.<br />

As MEG is a component for making everyday consumer<br />

goods, such as PET and PEF (cf. pp. 48) plastics and<br />

polyester textiles, the development of an environmentally<br />

friendly plant-based alternative has strong potential. Today,<br />

more than 99% of MEG is produced from fossil resources<br />

and the market demand for this product is expected to<br />

grow from 28 million to 50 million tons in the next 20 years.<br />

Biobased MEG, as for example used for bio-PET30 (e.g.<br />

Coca-Cola Plant Bottle) has been available for quite a<br />

while, mainly from India or Brazil.<br />

“Our novel single-step process can finally fulfil this<br />

demand in an environmentally sustainable manner that<br />

both consumers and leading brands have been seeking. I am<br />

proud of our team for making this important technological<br />

breakthrough. This enables renewable products growth for<br />

consumers that increasingly demand products brought to<br />

them in a responsible manner,” said Tom van Aken, Chief<br />

Executive Officer of Avantium.<br />

The new plant will use Avantium’s pioneering Mekong<br />

technology to convert renewable sugars into bio-based<br />

MEG. The plant – part of a previously disclosed €15-20<br />

million investment in our most advanced technologies – will<br />

be operational in 2019, employing up to 20 people.<br />

Alongside this important investment decision by<br />

Avantium, the European Innovation Council has selected the<br />

Mekong technology as part of its €146 million investment in<br />

top-class innovators, entrepreneurs, small companies and<br />

scientists with bright ideas and the ambition to scale up<br />

internationally. “We are honored to be selected among the<br />

79 innovative projects following face-to-face interviews with<br />

a jury of innovators, entrepreneurs and venture capitalists,”<br />

said Van Aken.<br />

The objectives of the demonstration plant are to scale<br />

up the novel bio-MEG technology, validate the technical<br />

and economic feasibility of the process, and to collect<br />

data to execute an environmental life-cycle analysis (LCA)<br />

quantifying the sustainability benefits of the Avantium<br />

technology. The demonstration plant site has not yet been<br />

announced, said the company, who added it was in the<br />

process of deciding between two locations. Construction<br />

will take place at an offsite location to control environmental<br />

conditions for complex chemistry and to protect the<br />

intellectual property of the technology. The plant will be<br />

delivered fully assembled to the chosen location and is<br />

expected to be completed in the second half of 2019.<br />

“This is a major step forward in the development of<br />

our Mekong technology,” said Zanna McFerson, Chief<br />

Business Development Officer of Avantium. “In addition to<br />

the environmental benefits, this demonstration plant will<br />

replicate commercial scale conditions of producing costeffective<br />

bio-MEG; a drop-in product identical to the fossilderived<br />

product. We are exploring partnership opportunities<br />

in bringing this technology to full-scale commercialization<br />

globally.” MT<br />

www.avantium.com<br />

Monoethylen glycol (MEG)<br />

20 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Blow Moulding / Bottle Applications<br />

VELOX offers newly developed<br />

transparent bio-plastic by SK<br />

Chemicals for hot-fill applications<br />

(Photo Syda Productions/Fotolia)<br />

Bio-copolyester for<br />

cans and bottles<br />

Newly developed transparent bio-plastic as an alternative to<br />

aluminium for aerosols and to heat-set PET for hot-fill applications<br />

VELOX and SK Chemicals recently presented ECOZEN<br />

HF ® , a bio-copolyester range especially suitable for the<br />

aerosol and food packaging industries<br />

VELOX GmbH (Hamburg, Germany), one of Europe’s leading<br />

solution providers of raw material specialities for the plastics,<br />

composites, additives and paint & coatings industries, and<br />

its long-term partner SK Chemicals Co. Ltd. (Seongnam,<br />

Gyeonggi-do province, South Korea) are presenting the next<br />

innovation for plastic packaging applications such as aerosol<br />

containers as well as cosmetic and hot fill bottles. Ecozen HF<br />

is a newly developed bio-copolyester range that is perfectly<br />

suitable for aluminum, glass and pet replacement wherever<br />

heat and pressure resistance combined with transparency is<br />

required. first customers have already started sampling the<br />

grades.<br />

“Ecozen HF has similar processing requirements to PET<br />

and can be used in the same injection-stretch blow moulding<br />

(ISBM) process. However, the new grades by SK Chemicals<br />

perform perfectly in areas where PET can sometimes fail,<br />

such as in high temperature and high-pressure applications”,<br />

explains François Minec, General Manager at Velox. “For<br />

example, PET is sometimes used to produce aerosol bottles.<br />

These bottles can often fail due to high residual stress and<br />

the low temperature resistance of PET, especially in the<br />

summer months when possible leakage is the result. Ecozen<br />

HF offers an ideal alternative here.”<br />

Besides remarkable resistance to pressure, stresscracking<br />

and high temperatures, Ecozen HF is characterised<br />

by excellent transparency and easy processing. As a glass<br />

replacement, e.g. for food packaging, it not only helps to<br />

reduce weight and transportation costs but can also be<br />

used to produce hot-fill containers without the need for<br />

an expensive PET heat-setting process or the need for<br />

crystallising the bottle or jar neck. Similarly, as an aluminum<br />

substitute in the cosmetics packaging industry, Ecozen HF<br />

combines high pressure-resistance with design flexibility<br />

and transparency. In addition, Ecozen HF is totally miscible<br />

with PET in the recycling stream. MT<br />

www.velox.com | www.skchemicals.com<br />

HIGH WE DRIVE THROUGHPUT. THE<br />

DIAMEETS CIRCULAR ECONOMY. QUALITY.<br />

Whether it is inhouse, postconsumer<br />

or bottle recycling:<br />

you can only close loops in a<br />

precise and profitable way if<br />

machines are perfectly tuned<br />

for the respective application.<br />

Count on the number 1<br />

technology from EREMA<br />

when doing so: over 5000<br />

of our machines and systems<br />

produce around 14 million<br />

tonnes of high-quality pellets<br />

like this every year –<br />

in a highly efficient and<br />

energy-saving way.<br />

That’s Careformance!<br />

CAREFORMANCE<br />

We care about your performance.<br />

1710013ERE_ins_bioplastics magazine.indd 1 bioplastics MAGAZINE 18.10.17 [<strong>04</strong>/18] Vol. 14:313 21


Application AutomotiveNews<br />

Foldable reusabel transport packaging<br />

WALTHER Faltsysteme sets new standards for<br />

sustainability in returnable logistics: The specialist for<br />

foldable reusable transport packaging presents for the first<br />

time a plastic folding box, 93 % of which was produced from<br />

renewable raw materials (a blend of sugar based resins,<br />

minerals and natural waxes). The folding<br />

box will initially be available in the<br />

external dimensions 600 x<br />

400 x 220 mm. The future<br />

areas of application for<br />

the innovative container<br />

are diverse: standard<br />

dimensions and the latest<br />

RFID technology guarantee<br />

reliable processes from highly<br />

automated intralogistics and supplier<br />

transport to the use in stores. With this<br />

pilot project, Walther Faltsysteme is further<br />

developing its proven GREENLINE product range: the<br />

company manufactures 100 % of its Greenline transport<br />

boxes from regenerative plastic.<br />

The latest innovation in the Greenline product line is<br />

produced by injection moulding and shall be available in<br />

all colours. Reason for the further development from using<br />

regenerative plastics towards using more and more lastics<br />

from renewable raw materials is the increasing demand<br />

for lean and environmentally friendly reusable transport<br />

packaging in all sectors. “With around 17 million tonnes of<br />

packaging waste per year, producers, suppliers and dealers<br />

are looking for an efficient solution. The product<br />

development of a folding box made of<br />

renewable raw materials brings<br />

us one step closer to our goal of a<br />

low-pollution recycling economy”,<br />

explains Thomas Walther, Managing<br />

Director of Walther Faltsysteme.<br />

The Greenline product line convinces<br />

with its sustainable development concept:<br />

with proper handling, the containers score<br />

with a comparatively long service life of<br />

around 100 cycles. The regenerative material<br />

can also be used for about two to three additional<br />

product life cycles after the recycling process. Walther<br />

Faltsysteme has already circulated more than 500,000<br />

transport containers made of regenerative material. MT<br />

www.faltbox.com<br />

New organic almondmilk<br />

with cashew in its first plant based bottle<br />

or fewer, such as vanilla extract and responsibly sourced<br />

coconut sugar. These new nutmilks avoid excessive use of<br />

stabilizers and thickeners, allowing the taste of the real<br />

ingredients to shine.<br />

“Every ingredient has a purpose, and every flavor comes to<br />

life in its own unique way,” said Aubrey Yuzva, Senior Brand<br />

Manager, So Delicious Dairy Free. “It’s so delicious, you’ll be<br />

so surprised it’s such a simple recipe with no extra.”<br />

So Delicious ® Dairy Free, Eugene, Oregon, makers of<br />

delicious dairy-free foods and beverages, is expanding its<br />

nutmilks with the launch of three new So Delicious Organic<br />

Almondmilks with Cashew – in primarily plant-based<br />

packaging, i.e. bottle mede of Braskem’s Green PE. A leader<br />

in dairy-free products for the past 30 years, So Delicious has<br />

made its mark on the industry with over 100 delicious dairyfree<br />

choices.<br />

The brand continues its legacy with this launch of organic<br />

almondmilk with cashew, which has seven ingredients<br />

In an effort to continue to grow as a clean and sustainable<br />

brand, So Delicious has also developed the first primarily<br />

plant-based bottle in the refrigerated dairy case for the new<br />

line of organic almondmilk with cashew, so consumers can<br />

fall in love with the bottle, too. The recyclable bottles are at<br />

least 80 % plant-based, reducing the brand’s dependence<br />

on fossil fuels.<br />

Their latest Non-GMO Project Verified, Gluten-Free,<br />

Certified Vegan and Certified Organic nutmilk is available in<br />

three flavors; vanilla, unsweetened and original, all of which<br />

are 50 calories or fewer per serving. Each flavor includes<br />

cashews for added creaminess and is free of carrageenan,<br />

artificial flavors, artificial colors, dairy and soy. MT<br />

www.sodeliciousdairyfree.com<br />

22 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Application Automotive News<br />

Materials from Total Corbion PLA used to build<br />

world’s first biobased circular car<br />

The world’s first biobased circular car, designed and<br />

built in the Netherlands by the Technical University of<br />

Eindhoven, was presented earlier this month by the team<br />

of students responsible for its design and realization.<br />

This is the first time that a car chassis and all bodywork<br />

has been made from natural and biobased materials - no<br />

metal or traditional plastics were used for the structural<br />

parts of the car. The parts are made up of light and strong<br />

sandwich panels, based on natural fiber flax and Luminy ®<br />

PLA supplied by Total Corbion PLA.<br />

The car, named Noah by the TU/ecomotive student team,<br />

was designed as a city car and features two seats and a<br />

spacious trunk. Noah is currently undertaking a European<br />

tour of car manufacturers, suppliers and universities to<br />

inspire others.<br />

In addition to its biobased composition, it is also ultralight<br />

and electrically-powered. Noah reaches a top speed<br />

of 110 km/h and the battery range lasts up to 240 km. At<br />

360kg, the weight of the car excluding batteries is less than<br />

half the weight of comparable production cars. In addition<br />

to being biobased, the parts are also recyclable, resulting<br />

in a 100% circular car, sustainable in all life phases.<br />

The PLA supplied by Total Corbion PLA for use in the<br />

car is biobased and recyclable and made from renewable<br />

resources, offering a reduced carbon footprint versus<br />

many traditional plastics. High heat Luminy PLA grades<br />

were used to construct the car, in order to ensure durability<br />

and sufficient heat resistance.<br />

François de Bie, Senior Marketing Director at Total Corbion<br />

PLA, is pleased with the achievement: ‘The result of this<br />

fantastic project shows just how far biobased materials have<br />

come, to produce such a complex product as a car. Noah is the<br />

proof that PLA is suitable for so much more than packaging.<br />

This is the first ever car to feature a fully biobased chassis<br />

and body panels. At Total Corbion PLA, we look forward to<br />

working together with the entire value chain to bring more<br />

high performance, durable and circular applications to<br />

market’. MT<br />

www.tuecomotive.nl | www.total-corbion.com<br />

Sustainable skin care products in sustainable packaging<br />

Denmark-based grums Aarhus produces scrub products<br />

without microbeads. Their secret ingredient? Coffee<br />

grounds.<br />

According to grums, coffee grounds refresh and firm<br />

the skin, are anti-inflammatory and enhance<br />

the circulation. Best of all, they don’t harm the<br />

environment when they go down the drain.<br />

For this company, choosing the right packaging<br />

was very important. Braskem’s I’m Green sugarbased<br />

polyethylene offered the sustainablility<br />

credentials grums was looking for. The company<br />

opted to plant-based plastic for all its packaging<br />

and by doing so, will significantly reduce the carbon<br />

footprint of its packaging, as well as the use of fossil<br />

resources. For every kg of I’m green polyethylene<br />

used ,more than 5 kg of CO 2 is saved.<br />

“We contacted more than 50 packaging suppliers to<br />

find exactly what we needed - a green solution. When<br />

making an innovative and sustainable product as a<br />

brand you also want the packaging of the product<br />

to share the same values. By using packaging<br />

made from sugar cane our products are complete. This<br />

is also one of our selling points and it adds storytelling to<br />

our products which we, and our customers, enjoy. We are<br />

very glad that Braskem is making these greener solutions<br />

that we want to support and make use of in our company,”<br />

says Mikkel Knudsen, founder of grums.Their latest<br />

Non-GMO Project Verified, Gluten-Free, Certified<br />

Vegan and Certified Organic nutmilk is available in<br />

three flavors; vanilla, unsweetened and original, all of<br />

which are 50 calories or fewer per serving. Each flavor<br />

includes cashews for added creaminess and is free of<br />

carrageenan, artificial flavors, artificial colors, dairy and<br />

soy. MT<br />

www.grumsaarhus.com<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 23


Applications<br />

Natural fibres for motorsports<br />

Bcomp’s high performance renewable fibres vs. standard carbon fiber<br />

layup for motorsports<br />

• Maintained performance at lower weight, or increased<br />

stiffness at maintained weight (compared to standard<br />

carbon fibre composites)<br />

• Safer crash behaviour without sharp shattering, and<br />

increased vibration damping<br />

• Up to 30 % cost savings<br />

• Lower eco footprint – more sustainable material, less<br />

material, and used material can be taken care of within<br />

the standard waste management system<br />

Bcomp, Fribourg / Switzerland announced a few new<br />

applications in motosports applications. The Flax fibre<br />

based powerRibs proprietary reinforcement technology<br />

forms a unique grid that supports thin-walled shell<br />

structures for e.g. motorsport body parts or automotive<br />

interiors. Combining extremely high performance (stiffness,<br />

vibration damping) with low weight, safer crash behaviour,<br />

powerRibs can be combined with ampliTex technical<br />

fabrics for a high-performance, full flax panel; alternatively,<br />

the flax-based powerRibs can also be combined to a glassor<br />

carbon fibre base.<br />

The ampliTex technical fabrics combine the finest flax<br />

fibres with a radical composites approach, and Bcomp’s<br />

cutting edge natural fibre know-how. This results in the<br />

highest performing natural fibre fabrics on the market,<br />

yielding the perfect partner for powerRibs to form superior<br />

lightweight panels with high vibration damping, stiffness<br />

and safer crash behaviour, all using natural flax fibres.<br />

DAB Motors for Yamaha, Biarritz<br />

The Alter XSR900 commissioned by Yamaha is a prime<br />

example of Simon Dabadie‘s (founder of DAB motors)<br />

constant search to push the limits of motorcycle building<br />

using the latest technology and materials to create<br />

an extraordinary combination of futurism and vintage.<br />

The result is a stunning motorcycle where the highperformance<br />

ampliTex technical fabrics not only contribute<br />

to light-weight and more sustainable body parts with a flirt<br />

to vintage looks, but also enables the unique front light with<br />

their translucency.<br />

race ready EPCS V2.3 Tesla P100DL<br />

Electric GT Holdings Inc. (headquartered at Circuit Pau-<br />

Arnos, France) and SPV Racing just unveiled the raceready<br />

version of the EPCS V2.3 Tesla P100DL at Circuit de<br />

Barcelona-Catalunya. Under the foil there is another layer<br />

to the story: the racing edition is lightweighted with body<br />

parts in natural fiber ampliTex and powerRibs, contributing<br />

to the 500kg weight reduction vs. the road edition. The<br />

EPCS edition Tesla also leverages the flax fibres unique<br />

translucency as the roof has a fully inte-grated LED screen<br />

that will display statistics and information during the<br />

races – an entirely new and revolutionising grip to bring<br />

the audience closer to the race and a part of modernising<br />

racing to attract new audiences. MT<br />

www.bcomp.ch | www.dabmotors.com/alter.html<br />

www.spv.racing | www.electricgt.co<br />

24 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Automotive<br />

PRESENTS<br />

The Bioplastics Award will be presented<br />

during the 13 th European Bioplastics Conference<br />

December <strong>04</strong>-05, <strong>2018</strong>, Berlin, Germany<br />

THE THIRTEENTH ANNUAL GLOBAL AWARD FOR<br />

DEVELOPERS, MANUFACTURERS AND USERS OF<br />

BIOBASED AND/OR BIODEGRADABLE PLASTICS.<br />

Call for proposals<br />

Enter your own product, service or development,<br />

or nominate your favourite example from<br />

another organisation<br />

Please let us know until August 31 st<br />

1. What the product, service or<br />

development is and does<br />

2. Why you think this product,<br />

service or development should win an award<br />

3. What your (or the proposed) company<br />

or organisation does<br />

<strong>2018</strong><br />

Your entry should not exceed 500 words (approx. 1 page)<br />

and may also be supported with photographs, samples,<br />

marketing brochures and/or technical documentation<br />

(cannot be sent back). The 5 nominees must be prepared<br />

to provide a 30 second videoclip and come to Berlin on<br />

December 4 th , <strong>2018</strong>.<br />

More details and an entry form can be downloaded from<br />

www.bioplasticsmagazine.de/award<br />

supported by<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 25


Report<br />

20 years Tecnaro<br />

Congratulations – but also some serious words of the founders<br />

Helmut Nägele and Jürgen Pfitzer<br />

Gucci sunglasses and shoe<br />

Biobrush<br />

A<br />

pioneer in bioplastics for 20 years, TECNARO from<br />

Ilsfeld, Germany is still acting with a fighting spirit.<br />

“First be smiled at, then fought against and finally<br />

regarded as a matter of course” - this was formulated<br />

by Arthur Schopenhauer for the truth and has now been<br />

transferred by the laudator in his speech to two pioneers<br />

from Heilbronn, Germany. Helmut Nägele and Jürgen<br />

Pfitzer, Managing Directors of Tecnaro, have resolutely<br />

pursued their idea of using renewable resources in order<br />

to manufacture their bioplastics named liquid wood-<br />

ARBOFORM ® , ARBOBLEND ® and ARBOFILL ® - with all<br />

properties of plastic. Today, in the company’s twentieth<br />

year of existence, they proudly say “we have succeeded”.<br />

All over the world, their formulas are contained in everyday<br />

objects such as fashion, automobiles, facades, craftsmen-,<br />

trade and industrial needs. Tecnaro’s formulas are used for<br />

Benetton hangers or Friedwald forest cemetery urns, for<br />

example.<br />

Of course, so many times Nägele und Pfitzer and their<br />

team have continued in research and development, have<br />

transferred their ideas into practice, have selected and<br />

discarded all changes and started again – until they<br />

developed formulas for a wide/broad application range.<br />

However, they are made from sugar, starch, natural wax,<br />

organic oil or wood extractives like cellulose and lignin.<br />

According to Helmut Nägele, up to 70 % of all conventional<br />

plastic may be replaced technically by Tecnaro resins or<br />

compounds. Tecnaro’s recipes are used in Audi R8, in<br />

punches and staplers from Novus, in shoes and sun glasses<br />

from Gucci and in the multiple-award-winning Biobrush<br />

toothbrushes. In Addition, the bio version of the glue sticks<br />

ReNature“ and the text markers Edding 24 which are<br />

well-known worldwide, are made from Tecnaro materials.<br />

For a long time, a leading manufacturer of corn mills has<br />

been using casings made of wood. Now, with good reason<br />

Mockmill as a first kitchen appliance wears a dress made<br />

from bio plastics Arboblend.<br />

Strong network created around the Tecnaro Team<br />

During the last 20 years, a most remarkable and strong<br />

plastic technology network has been created around the<br />

Tecnaro Team which comprises innovative customers,<br />

research and development partners, flexible suppliers,<br />

authorities and associations acting in a prudent manner,<br />

fair market players, keen understanding consultants and<br />

auditors as well as strong financial partners. Thanks to its<br />

competent sales representatives and Albis Plastic GmbH<br />

Hamburg, Tecnaro materials are reaching even the most<br />

far-away countries.<br />

“We need to grow even more but have already amazingly<br />

powerful partners in the entire world“, say the two managing<br />

directors and add “together we are everywhere!”<br />

26 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Report<br />

“There’s nothing left to desire“ results Öko-Test<br />

Besides Arboform und Arbofill, Arboblend is one of<br />

Tecnaro’s basic formulas. And whether it concerns returnable<br />

coffee-to-go beakers, organic freezer bags, coffee capsules,<br />

cooking- or baby spoons, highest standards are valid for<br />

food contact. Therefore, the German magazine Öko-Test<br />

thoroughly tested the Ajaa Lunchbox made from Arboblend<br />

and awarded it the overall rating “very high quality” and drew<br />

a positive conclusion “there’s nothing left to desire“(6/<strong>2018</strong><br />

issue).<br />

Tecnaro‘s biopolymers leave the factory in form of<br />

granules. They are made from renewable raw materials and<br />

are biodegradable or long term resistant. The materials can<br />

be processed, for example, by injection molding, extrusion,<br />

calendering, pressing, thermoforming and blow molding.<br />

The trophies of Green Brands Germany, for example, are<br />

made via 3D printing process. And by using an additive<br />

manufacturing system Freeformer which is a revolutionary<br />

manufacturing technology from Arburg, functionally<br />

planetary gears (working similarly like a clockwork) are<br />

made in a single work step, without further assembly.<br />

Tecnaro also scores at another place on the playing<br />

field: the ball Binabo from TicToys (Leipzig, Germany) has<br />

accurately landed to the <strong>2018</strong> Football World Cup. Before<br />

they start playing with the Binabo, children can assemble<br />

it from pieces. However, from the Binabo parts, something<br />

else may be assembled, too. This different football made<br />

from Arboblend was designed based on an example from<br />

Myanmar which is made from rattan fencing. And of course,<br />

the new one is made from 100% renewable raw materials,<br />

too.<br />

Steadily in upward trend<br />

With a team of more than 30 employees and thereof a lot of<br />

highly qualified academics, the trend for Tecnaro is upwards.<br />

Besides a high media attention, the number of prizes and<br />

awards is increasing almost every year (see separate infobox).<br />

Today, the level of being laughed at has overcome. Does<br />

everything fit now? Shouldn’t the world embrace the German<br />

pioneers for their rescue visions about plastic replacement?<br />

And this in times in which the world’s oceans are in danger<br />

of suffocating in plastic waste whirls. The reversal away from<br />

fossil raw materials and oil to sustainable and renewable<br />

resources was never before as topical as today.<br />

Helmut Nägele, Managing director of Tecnaro, says: “like<br />

the turn in energy politics, the raw material shift should be<br />

propagated accordingly and repeated continually. It’s a fact<br />

that the world’s resources of oil are finite. Already today, oilmultis<br />

are buying forests on a large-scale in order to keep<br />

at least their market power within global competition. “<br />

Ajaa lunch-boxes<br />

Binabo toy<br />

Edding highlighters<br />

Nighthawk Headphones<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 27


Opinion<br />

Bioplastics facade mock-up, Campus University Stuttgart, Germany<br />

ReNature glue stick<br />

Punch and stapler (Novus)<br />

Questionable closeness to industry<br />

Meanwhile, Nägele und Pfitzer see themselves<br />

having reached step two which means to be<br />

combated. Here, the main challenge will not be the<br />

competition to the oil industry but even hostility out<br />

of a totally unexpected corner, from acteurs which<br />

Tecnaro thought they would give backing. However,<br />

a world-wide environmental organization has<br />

just thrown down a gauntlet. “Initially, this nonprofit<br />

environmental organization tackled with<br />

questionable theses against a near to finalization<br />

contract concerning a product being developed<br />

over months for a large customer. Afterwards, the<br />

related partners of this organization took benefit<br />

of this business opportunity based on Tecnaro’s<br />

development”, says Pfitzer.<br />

“We’ve lost our faith”, say the two Tecnaro<br />

leaders.<br />

“As a manufacturer of biobased granules from<br />

renewable resources we constantly have to answer<br />

questions from anywhere and have to keep expensive<br />

records additionally. However, this procedure<br />

would not have to be performed by manufacturers<br />

of oil-based polymers. It seems really bizarre<br />

that such environmental organizations have now<br />

discovered established bioplastics for themselves<br />

and are commercializing this technology and,<br />

against their better knowledge, create distortions<br />

of competition – and in this case even in favor of<br />

conventional oil-based plastics”, says Jürgen<br />

Pfitzer.<br />

In this context, Pfitzer cites an Italian proverb<br />

which says: “Anyone who does everything for the<br />

sake of money will soon do everything for the<br />

money.”<br />

Fiscal advantage for oil-based plastics<br />

This year, Tecnaro is focusing on other topics<br />

witch are especially its 20-years anniversary and<br />

the trend-setting market movement thus arriving<br />

even under the wide knowledge of the fact that<br />

oil-based plastics has still favorable terms of tax<br />

(at least in Germany). This special position within<br />

fiscal legislation goes back to the 60’s and has<br />

today only little public awareness. In this context,<br />

it is remarkable that at that time, their justification<br />

was that oil-based plastic waste would not be<br />

burnt, in contrast to fuel.<br />

Nägele and Pfitzer are not alone in considering<br />

the subsidy for oil-based plastics as unjustified.<br />

In this context, just recently, Robert Habeck,<br />

Chairman of the German Green party, has required<br />

to introduce an EU-wide tax on oil-based plastics<br />

for disposable items. This was published in the<br />

media accordingly. Nägele und Pfitzer consider<br />

it absurd that there is a tax allowance of several<br />

millions of euros per year for the plastic flood. “For<br />

years, we have been recommending an additional<br />

CO 2<br />

-emission tax on products made of fossil<br />

raw materials and now, we found out that these<br />

28 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Opinion<br />

are even exempt from mineral oil tax“, says Jürgen<br />

Pfitzer, shaking his head.<br />

“And this has an influence on the whole biobased<br />

industry, too. Within our industry, the price is an<br />

important decision criterion“, says Helmut Nägele.<br />

Jürgen Pfitzer adds: “Especially in terms of fossil<br />

raw materials or for uranium and rare earth, for<br />

example, but also on use of pesticides and on bottling<br />

water in Africa it has shown that opportunities and<br />

profits are always privatized and risks and losses<br />

socialized!<br />

The ecological footprint of products is usually<br />

excluded from the account. Besides tax allowances,<br />

this procedure results in a further distortion of<br />

competition at the expense of environment and<br />

common public.<br />

“It is not acceptable that a few big oil companies<br />

and multi-billionaires and its shareholders take profit<br />

from generally available but globally limited resources<br />

of raw materials or to throw toxic pesticides on the<br />

market that simply kill everything except their own<br />

cereals. Equally worrying is the fact that bottlingwater<br />

in Africa with the “innovation” of simply digging<br />

deeper wells than it is possible for the villagers.<br />

Simultaneously, the general public has to carry the<br />

risks and costs for climate changes through CO 2<br />

-<br />

emissions, oil rig- or oil tanker accidents, defective<br />

pipeline, polluted oceans, dying bees, insects,<br />

animals and plants, Destruction of arable land due to<br />

rising sea levels, devastation of entire regions or other<br />

environmental disasters with irreparable damage,<br />

global wars for oil and resulting refugee flows.<br />

However, if these costs were to be distributed<br />

according to the polluter-pays principle, as is usual<br />

everywhere else, and preferably with a share of the<br />

costs shared by the arms industry, peace in the world<br />

would be achieved tomorrow,” said Managing Director<br />

Jürgen Pfitzer.<br />

Customized for double production capacity<br />

Above all – on the 2 nd of July, <strong>2018</strong>, Tecnaro<br />

celebrated its 20 th anniversary. A further reason<br />

to be pleased is the investment in a factory-new<br />

machine. It is a twin-screw extruder delivered by<br />

KraussMaffei Berstorff and allows, thanks to the<br />

added sophisticated plant engineering, to double<br />

production capacity at Tecnaro. With this plant, the<br />

specialists from Ilsfeld are optionally prepared for the<br />

increasing demand of custom-made organic plastic<br />

compounds. Furthermore, the machine is planned<br />

to be used for research and development purposes<br />

and to conduct extensive tests using an upscaling<br />

procedure, for example. Here, formulations can be<br />

tested for practicality with a throughput of up to one<br />

ton per hour.<br />

Once again: First be smiled at, then fought against<br />

and finally regarded as a matter of course. However,<br />

the Binabo ball is now in everyone’s court and stands<br />

for a better future without fossil plastics. MT<br />

www.tecnaro.de<br />

Awards and Prizes:<br />

• 1999<br />

• 2000<br />

• 2001<br />

ZDF WISO German Founders Award<br />

Euromold Award in Gold<br />

1. Einfach Genial Preis of the MDR<br />

• 2002 Award from the Material ConneXion New York for<br />

ARBOFORM as “Best Product in Show 2002“<br />

• 2007 VR-Innovationspreis 2007<br />

• 2008 Werkbund Label 2008<br />

• 2009 Deutsche Industriepreis 2009<br />

• 2010<br />

• 2011<br />

European Inventor Award (handed over at a<br />

ceremony in Madrid by the European Patent Office<br />

and today’s Spanish royal couple Queen Letizia and<br />

King Felipe<br />

Diesel Medal for the most sustainable innovation<br />

of the year<br />

• 2015/16/17 Green Brand Germany Siegel<br />

Awards eceived by Tecnaro’s customers:<br />

• 2008<br />

• 2016<br />

• 2017<br />

• 2017<br />

German Design AWARD <strong>2018</strong> – WINNER<br />

Deutscher Verpackungspreis<br />

reddot Award 2017-best of the best<br />

GreenTEC Award 2017 (2. Place)<br />

• <strong>2018</strong> Green Good Design Award <strong>2018</strong><br />

• <strong>2018</strong> German Innovation AWARD <strong>2018</strong><br />

Mockmill cereal grinder<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 29


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30 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Materials<br />

New biocomposite for<br />

thermally formable products<br />

VTT, Espoo, Finland, has developed a<br />

thermally formable, biodegradable<br />

material, which is 100 % biobased. Its<br />

suitability for applications such as furniture<br />

makes it an attractive alternative to wood and<br />

biocomposite materials available in the market,<br />

not only because of its biodegradability but<br />

also due to its formability and colouring properties.<br />

Biocomposites made from entirely biobased raw<br />

materials can be used to replace fossil raw material<br />

derived plastics, which have traditionally been used<br />

in industrial applications. Being thermoformable,<br />

the material is well suited for various manufacturing<br />

processes and products.<br />

“All the goals we set were achieved: the material is 100 %<br />

biobased, cellulose fibres account for a significant proportion,<br />

it looks good and it has excellent performance characteristics”,<br />

says Lisa Wikström, Research Team Leader from VTT.<br />

At the end of their life-cycle, products made from this material<br />

can either be re-used, composted, or burned to generate energy<br />

without any fossil-based carbon dioxide emissions making it kind<br />

of “renewable energy”.<br />

“New biobased, thermally formable materials<br />

and composites are a promising alternative<br />

for the plastic products market. However, a<br />

big breakthrough is yet to come. A major<br />

shift requires cooperation between<br />

material and process developers as well<br />

as designers,” Wikström concludes.<br />

The first model product is a designer<br />

chair manufactured as a joint effort<br />

between VTT, Plastec Finland and KO-<br />

HO Industrial design (Jurva, Finland).<br />

The chair, manufactured using traditional<br />

compounding and injection moulding technologies, is<br />

made from wood-based cellulose fibres, renewable and<br />

industrially compostable, thermoformable polylactide, and<br />

biobased additives.<br />

VTT developed the material in the ACEL research<br />

programme funded by Clic Innovations Ltd. (Helsinki, Finland)<br />

and the proof of concept stage was carried out with Plastec<br />

Finland an injection moulding company from Vimpeli.<br />

www.vtt.fi<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 31


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32 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13<br />

Visit our bookstore for prices and many more books!


Materials<br />

New compound certified<br />

as biodegradable in soil<br />

The injection moulding material M·VERA ® GP1012 by BIO-<br />

FED, Cologne, Germany, a branch of AKRO-PLASTIC GmbH,<br />

Hamburg, Germany), has been tested by TÜV AUSTRIA<br />

Belgium and has been awarded the OK biodegradable SOIL<br />

certificate as per EN 13432.<br />

This bio-polyester compound is suitable for<br />

processing in injection moulding and can be easily<br />

processed by all commercial machines. It consists of<br />

100 % renewable materials, is heat resistant to over<br />

100 °C and has an excellent balance of stiffness<br />

and toughness. This compound is suitable for<br />

use in agriculture and horticulture and can also<br />

be used for coffee capsules. Due to its light color,<br />

M·Vera GP1012 can be coloured with the AF-Eco<br />

biomasterbatch from Bio-Fed’s sister branch AF-<br />

Color.<br />

To qualify for the OK biodegradable SOIL TÜV<br />

certificate, at least 90 % of the material must degrade<br />

into carbon dioxide and water. The degradation is tested by<br />

accredited laboratories under controlled and standardised<br />

conditions over a period of no longer than two years.<br />

Coffee capsules – a<br />

possible application for<br />

M·Vera GP1012<br />

All elements of the compounds meet the FDA<br />

requirements for use in products that come into contact<br />

with foodstuffs. The requirements for other certificates<br />

such as “OK compost HOME”, as well as approval for<br />

products intended to come into contact with food as per EU<br />

10/2011, are expected to be met in the first half of 2019.<br />

Since 2014 Bio-Fed produces and markets biodegradable<br />

and/or biobased compounds under the M∙Vera brand.<br />

As a branch of Akro-Plastic, a specialist for innovative<br />

customer-oriented plastic compounds, Bio-Fed is part of<br />

the international Feddersen Group which has its head office<br />

in Hamburg.<br />

The Bio-Fed product portfolio consists a broad range<br />

of bioplastics compounds with different properties, such<br />

as biodegradability and/or high biobased content. The<br />

M·Vera products are already well-established in a number<br />

of applications and can be used with various processing<br />

methods. In addition, all M·Vera compounds can be colored<br />

individually – for example with the AF-Eco biopolymerbased<br />

masterbatches which are certified in accordance with<br />

EN 13432. The AF-Eco range consists of color and carbon<br />

black masterbatches as well as additive masterbatches.<br />

In addition to materials for processing in the field<br />

of injection moulding, Bio-Fed also manufactures<br />

biocompounds for use in extrusion, e.g. blown film that<br />

meets the strict legal requirements in France and Italy.<br />

A large proportion of these compounds are renewable<br />

materials (biobased carbon content over 40 %) and meet the<br />

requirements for the relevant ‘end-of-life’ scenarios such<br />

as “OK compost INDUSTRIAL” and “OK compost HOME”.<br />

We STARCH<br />

your plastics.<br />

Made in Austria.<br />

AMITROPLAST ®<br />

THERMOPLASTIC STARCH<br />

BIO-BASED & HOME-COMPOSTABLE.<br />

PERFORMING. COST COMPETITIVE. FOR YOU.<br />

AMITROPLAST ® allows you to incorporate 50 % or more of<br />

thermoplastic starch in your compound for film extrusion<br />

and injection moulding.<br />

www.bio-fed.com<br />

bioplastics.starch@agrana.com<br />

AGRANA.COM<br />

THE NATURAL UPGRADE<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 33


Cover-Story<br />

Vienna schoolgirls develop<br />

home- compostable<br />

coffee capsules<br />

By Michael Thielen<br />

Avoid waste, save aluminium: Two students of the TGM Austrias<br />

biggest engineering college located in Vienna, developed<br />

a biobased material for coffee capsules that actually<br />

biodegrades well, even in the compost box at home.<br />

“We are very proud that it works,” says Samantha Onderka (19),<br />

graduate at the TGM. Together with Katharina Schleinzer (18),<br />

she observed how the novel coffee capsules in their self-made<br />

compost box disintegrated within a few weeks. “It’s great to see<br />

the capsules change and degrade.”<br />

Coffee capsules for espresso machines are a convenient thing,<br />

but they generate a lot of waste. A typical capsule is made of 1.13<br />

grams of aluminium. Three cups of coffee a day create more than<br />

1.2 kilograms of aluminium-waste in one year.<br />

The two students of the TGM therefore hurled themselves<br />

particularly eagerly at a diploma project in preparation for their<br />

matura (A-levels) that could make the world a little bit better:<br />

Gabriel-Chemie, an international company with headquarters in<br />

Gumpoldskirchen, Lower Austria, needs a new, environmentally<br />

friendly material for coffee capsules. Andreas Höllebauer, Head<br />

of Research at Gabriel-Chemie, explained the idea: “We are<br />

looking for a bioplastic for coffee capsules. The material should<br />

be of natural origin and demonstrably very easy to degrade, not<br />

only in industrial composting plants, but quite normally in the<br />

home and garden”. Gabriel-Chemie mainly produces colours and<br />

additives for plastics and is therefore interested in the subject of<br />

coffee capsules. “We have been working with the TGM for many<br />

years,” explained Höllebauer, “so it made sense to advertise this<br />

research task as a Matura project.”<br />

Katharina and Samantha added: Common bioplastic capsules<br />

are only compostable under industrial composting conditions<br />

(temperatures between 50 °C and 80 °C, humidity around 50 % and<br />

the right population of microorganisms) in corresponding plants. At<br />

the same time, legal regulations in certain regions (such as Austria<br />

or Germany) prohibit the disposal of coffee capsules via a composting<br />

plant. The capsules currently available on the market that we know of<br />

are also not really suitable for biodegradation in home composting, as<br />

degradation would take far too long without ideal conditions. However,<br />

we wanted to develop a material that could be composted in our own<br />

garden even under sub-optimal conditions.<br />

Plastic from nature<br />

Katharina and Samantha experimented with various mixtures<br />

based on natural, renewable raw materials. Bioplastics are often<br />

made from sugar, starch or biomass. However, the final result<br />

should be waterproof and easy to form. The girls tested seven<br />

different bioplastics, which they produced themselves from<br />

various ingredients. Which took a lot of patience. Although the<br />

TGM is equipped with a machine for this purpose, it is of course a<br />

laboratory device designed for small sample quantities and filled<br />

by the spoonful.<br />

“To produce five kilograms of each new material, we had to<br />

spoon granules into the hopper for hours,” sighed Katharina. The<br />

granules were mixed and melted until the new material flowed<br />

out of a die. “Then we tested extensively whether the material<br />

should meet certain criteria. The bioplastics had to pass a tensile<br />

test and a tensile impact test and of course also needed the right<br />

properties for processing”.<br />

Of seven mixtures, exactly one was left to be considered as a<br />

candidate. It consists of materials entirely made from renewable<br />

raw materials. Using a special 3D laser printer (stereolithography),<br />

the students designed and built a mould with which they could<br />

actually produce coffee capsules from their new material in a<br />

thermoforming process.<br />

End-of-life more important than production<br />

The most important thing about this invention is its end-oflife<br />

solution. Would the coffee capsules actually completely<br />

biodegrade in a normal compost heap? Samantha and Katharina<br />

built a compost box suitable for domestic use and threw their<br />

coffee capsules literally “on the dung”. The experiment was<br />

successful. In the course of the weeks up to their Matura exam<br />

the girls could observe and document how the capsules became<br />

ever smaller and smaller.<br />

“We have found a bioplastic that can solve the problem with<br />

coffee capsules in the long term,” says Samantha happily.<br />

Outlook<br />

The current discussion about resource-efficient use and<br />

the avoidance of waste from disposable products offers great<br />

potential for ecologically more sustainable materials that were<br />

previously not commercially competitive. The Austrian Eco-Label<br />

is currently being awarded to biodegradable biopolymers used in<br />

the packaging sector. The material solution developed within this<br />

project would qualify for this. In the meantime, the project also<br />

was praised with the Borealis Innovation Award <strong>2018</strong>.<br />

And the project will be continued. TGM and Gabriel-Chemie<br />

want to take a closer look at the degradation mechanism and<br />

further refine the formulation. Further processing tests will also<br />

be carried out in addition to the previous work.<br />

www.tgm.ac.at www.gabriel-chemie.com<br />

34 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Cover-Story<br />

Industrial Solutions for Polymer Plants<br />

Polylactide Technology<br />

Uhde Inventa Fischer Polycondensation Technologies has expanded its product portfolio to<br />

include the innovative state-of-the-art PLAneo ® process for a sustainable polymer. The<br />

feedstock for our PLA process is lactic acid, which can be produced from local agricultural<br />

products containing starch or sugar. The application range of PLA is similar to that of polymers<br />

based on fossil resources as its physical properties can be tailored to meet packaging, textile<br />

and other requirements. www.uhde-inventa-fischer.com<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 35


Coffee capsules & pods<br />

By:<br />

Martin Bussmann<br />

BASF<br />

Ludwigshafen, Germany<br />

Enjoying coffee with<br />

compostable coffee capsules<br />

Coffee capsules are convenient for consumers, easy to dispense and practical. However, in Germany<br />

alone, they generate around 5,000 tonnes of waste each year. Compostable bioplastics by BASF for the<br />

manufacture of coffee capsules set an example against this trend – with tailored ecovio ® grades for the<br />

production of a wide range of flexible and rigid compostable packaging.<br />

Cappuccino for breakfast, an espresso in the afternoon<br />

– simply by pushing a button on your own coffee<br />

machine. Portioned capsules are particularly popular<br />

with coffee lovers as they are easy to use and make quality<br />

coffee quickly. However, the packaging potentially pollutes<br />

the environment. Commercially available capsules consist<br />

of aluminium and conventional plastic and are either burned<br />

after use or are difficult to recycle. At the same time, there<br />

is increasing public interest in sustainable products that<br />

contribute to circular economy.<br />

As early as 2013, BASF developed a biodegradable coffee<br />

capsule with Swiss Coffee Company for gourmet coffee using<br />

its certified compostable and partly biobased ecovio, which<br />

was optimised for injection moulding for this purpose. While<br />

the material had until then only been used in mulch films<br />

and bags, it was now possible for the first time to implement<br />

ecovio commercially in an injection moulding application -<br />

and at the same time meeting the particular requirements<br />

of coffee capsules: The capsule can withstand the high<br />

pressure and the heat that are generated by the machine<br />

in the brewing process. Flavour-tight barrier secondary<br />

packaging, which is also compostable, ensures that the<br />

coffee aroma is optimally maintained. The application<br />

won the 2014 Global Bioplastics Award presented by<br />

bioplastics MAGAZINE.<br />

Since this breakthrough, BASF has been working<br />

continuously on its product portfolio to enable different<br />

processing technologies for the manufacture of coffee<br />

capsules. It is focusing on improving application-specific<br />

requirements such as dimensional stability under heat and<br />

an oxygen barrier. For thin-walled capsules, the injection<br />

moulding grade ecovio IA1652 offers a greater dimensional<br />

stability under heat along with ideal mechanical stability.<br />

Now also on the market: the grade ecovio T2308, which<br />

allows thin-walled capsules to be manufactured also by<br />

thermoforming. Another milestone is the development of<br />

technologies for inserting an oxygen barrier, which means<br />

that both the injection moulding grade ecovio IA1652 and<br />

the thermoforming material ecovio TA1241 can be given an<br />

oxygen barrier during the production of the capsules.<br />

In 2017, BASF and the French company Capsul’in were<br />

awarded the Pierre Potier innovation prize for a coffee<br />

capsule made of ecovio IA1652. The award, presented by<br />

the French Ministry of Economy and Industry on behalf<br />

of the French Federation for Chemistry Sciences and<br />

the Federation of the Chemical Industry, recognises<br />

innovation in sustainable development and encourages<br />

environmentally friendly approaches. The ecovio coffee<br />

capsules, which are certified compostable, are broken down<br />

in industrial composting plants into water, CO 2<br />

and quality<br />

compost, and metabolised by microorganisms. Within<br />

twelve weeks the capsules are degraded into industrial<br />

compost. The development of compostable coffee capsules<br />

therefore allows not only a more responsible handling of<br />

packaging, but also a transformation of the raw material<br />

back to valuable compost at the end of its life cycle and a<br />

reduction of unnecessary waste.<br />

www.ecovio.basf.com<br />

Manufactured by injection moulding: thin-walled coffee capsules<br />

made of ecovio IA1652 (Photo: BASF)<br />

Thermoformed coffee capsules made of ecovio TA1241 enable<br />

high dimensional stability under heat, good mechanical stability<br />

and at the same time a reliable oxygen barrier. (Photo: BASF)<br />

36 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Coffee capsules & pods<br />

Replacing<br />

aluminium<br />

with paper<br />

The world’s first mass produced coffee capsule<br />

made of paper is set to replace aluminum and plastic<br />

capsules.<br />

The Bremen, Germany based coffee capsule company<br />

Velibre brings onto the market the first Nespresso ® -<br />

compatible coffee capsule made of paper.<br />

“After more than two years of development, which required<br />

over a million Euros of investment, Velibre can finally present<br />

the finished version of our new paper capsule. This capsule<br />

can be put into the home compost as well as in the biowaste<br />

collection bin”, says managing director David Wolf- Rooney.<br />

The serial production has just started and the finished<br />

capsule will be available in the third quarter of <strong>2018</strong>. Wolf-<br />

Rooney expects Velibre to produce over 300 million capsules<br />

in the next Year. “We are more than convinced of the giant<br />

potential of our paper capsule. This belief comes from the<br />

enormous interest in the Velibre capsule from various market<br />

leaders in the coffee capsule industry. It also comes from the<br />

concrete offers related to the purchase of Velibre which is in<br />

the double-digit millions. The value of the capsule will develop<br />

throughout the next years towards the 100 Million Euros<br />

level”, reveals David Mr. Wolf-Rooney. He adds: “traditional<br />

coffee capsules produce a huge amount of waste and our<br />

vision is to completely banish the use of plastic or aluminum<br />

capsules from the market. To secure this vision we will make<br />

the Velibre know-how, our technology and our production<br />

capacities freely available to all manufacturers of coffee<br />

capsules. From now on, no company<br />

has to produce environmentally harmful<br />

variants as they can get all the capsules they<br />

want from Velibre. This is the real revolution behind Velibre”.<br />

The newly developed paper capsule supports the<br />

company’s goal to systematically revolutionizing the coffee<br />

capsule market. The paper capsule can be easily recycled via<br />

home compost and – as the only capsule in the world so far –<br />

via organic waste collection systems. The capsule completely<br />

biodegrades to CO 2<br />

, water and biomass after a few weeks,<br />

depending in the composting environment.<br />

The capsule is made of sugarcane fibers. These fibres<br />

are a residual material created in large volumes during the<br />

production of sugar. Therefore, it does not need its own land<br />

for production and it is not in any competition with food. All<br />

materials used are also 100 % free of genetically modified<br />

raw materials. The components of the capsule are already<br />

certified according to the standard EN 13432 for industrial<br />

composting facilities. For the standards Vincotte OK<br />

compost HOME and DIN-certified garden compostable the<br />

corresponding certification processes are in process.<br />

A global patent was established in 2016 for the unique<br />

product and a German utility patent has already been<br />

registered. MT www.velibre.com<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 37


Coffee capsules & pods<br />

Coffee klatch<br />

Aldo Zanetti,<br />

Business Unit<br />

Manager at<br />

Trinseo<br />

Single-serve Coffee Capsules and<br />

Biodegradable Material – the Perfect Match – an Interview<br />

Trinseo, headquartered in Berwyn, Pennsylvania, USA, is a global materials<br />

company that has acquired API (Mussolente, Italy), a producer of thermoplastic<br />

elastomeric compounds and bioplastics. Trinseo has recently launched new grades of biodegradable<br />

and compostable bioplastics for single-serve coffee capsules. bioplastics MAGAZINE spoke with Aldo<br />

Zanetti, Business Unit Manager at Trinseo.<br />

When did Trinseo enter the bioplastics market?<br />

In 2006, Trinseo, formerly known as API, launched the<br />

first soft biodegradable and compostable material – APINAT<br />

BIO ® . In those early days, this was still a novel approach.<br />

Still we felt the time had come to add sustainability as a<br />

core competence to our already innovative conventional<br />

compounds. We protected this biodegradable compound<br />

technology with an international patent.<br />

How did biodegradable products progress from<br />

here?<br />

Over the years, we developed biodegradable materials for<br />

a variety of different applications. In 2011, conforming to the<br />

new Italian regulation, we introduced a biodegradable and<br />

compostable film solution to replace<br />

polyethylene shopping bags. In 2014,<br />

we launched the first biodegradable<br />

and compostable compound<br />

for single-serve coffee capsules.<br />

Additionally, we have developed a unique<br />

and wide-ranging spectrum<br />

of biodegradable color<br />

masterbatches compatible<br />

with all of our bio resins.<br />

Since the acquisition of API, Trinseo has<br />

introduced further innovations and new materials suitable<br />

for various applications, particularly in the packaging and<br />

agricultural sectors.<br />

In your opinion, why should companies use<br />

biodegradable material when producing coffee<br />

capsules?<br />

Global coffee consumption is continuously progessing<br />

towards single-serve capsule machines. Every year<br />

around 50 billion capsules are sold worldwide. Although<br />

single-serve capsules are extremely convenient, they<br />

have the downside that the aluminum and plastic create<br />

a lot of waste. Single-serve coffee capsules are not easily<br />

recyclable and mixed materials such as exhausted coffee<br />

powder, plastic and aluminum are sent to a landfill without<br />

being separated. The coffee industry urgently needs a<br />

more sustainable packaging option. Biodegradable and<br />

compostable capsules are, in my opinion, therefore one of<br />

the most viable solutions.<br />

Why are single serve coffee capsules so suitable<br />

assuming they are collected and sent to a<br />

composting facility?<br />

The combination of coffee powder with biodegradable<br />

material constitutes a ‘perfect match’. Coffee powder is<br />

organic and is itself a good fertilizer. The brewing process<br />

adds temperature and humidity, thereby triggering the<br />

biodegradation of the capsule into compost, CO 2<br />

and water.<br />

What about other material properties? Can your<br />

material compete with conventional plastics?<br />

Besides being biodegradable under EN 13432, our new<br />

APINAT BIO® grades are derived from 60 to 90 % biobased<br />

sources. Our grades fully comply with both<br />

U.S. FDA and EU food contact regulations.<br />

Our materials exemplify exceptional<br />

dimensional stability and easy<br />

processability at the manufacturer’s<br />

site. They can be processed with<br />

cycle times comparable to those of<br />

conventional plastics, maintaining a<br />

manufacturer’s hourly output at the<br />

same levels. The material grades have<br />

been successfully tested and approved<br />

in all current production technologies such<br />

as injection molding, extrusion and extrusion-compression<br />

molding. So, yes, we can compete with conventional plastics<br />

in the coffee capsule business.<br />

Which material properties would you now like<br />

to further improve?<br />

Our first priority is to enhance the barrier towards water<br />

vapor and oxygen, thereby extending capsule shelf-life. This<br />

is the area where developments are most concentrated.<br />

We are also working on improving our material’s thermal<br />

stability for the purpose of extending its use in complex<br />

capsules and for higher brewing temperatures and<br />

pressures.<br />

What about your participation in the EU LIFE-<br />

PLA4Coffee project?<br />

Because of our extensive knowledge and experience in<br />

the development of biodegradable plastic compounds, ICA,<br />

38 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Coffee capsules & pods<br />

biopolymere.<br />

6. Kooperationsforum mit Fachausstellung<br />

a manufacturer of automatic packaging machinery<br />

and coffee capsules (headquartered in Bologna,<br />

Italy), selected us as a project partner. The aim of<br />

LIFE-PLA4Coffee project was to validate PLA based<br />

compound formulations with improved functional<br />

properties for the production of compostable<br />

coffee capsules. This interesting and productive<br />

collaboration has helped us to deepen our knowledge<br />

about the specific needs of this sector.<br />

How does your experience help<br />

customers to decide whether to invest in<br />

biodegradable solutions?<br />

We have a long and deep knowledge in diverse<br />

application fields like packaging, footwear, automotive<br />

and technical products. We understand the complexity<br />

of many different applications so when customers<br />

approach us asking about biodegradable solutions<br />

for specific applications, our experience enables<br />

us to evaluate the technical feasibility and provide<br />

advice on environmental benefits and suitability for<br />

each single application. We do not support projects<br />

in which the use of biodegradable solutions does not<br />

constitute a measurable environmental advantage.<br />

In addition we support our customers on legal<br />

framework conditions, which can vary depending on<br />

country and application.<br />

Over the years and through joint developments with<br />

customers, combined with our technology expertise,<br />

we have expanded our biodegradable compounds<br />

portfolio, ranging from low to high rigidity, to meet a<br />

wide spectrum of requirements for packaging and<br />

agricultural applications. MT<br />

www.trinseo.com<br />

18091 werbersbuero.de | Foto: ©artemegorov - stock.adobe.com<br />

B a y e r n<br />

Innovativ<br />

Joseph-von-Fraunhofer-Halle<br />

Straubing, 24. Oktober <strong>2018</strong><br />

www.bayern-innovativ.de/biopolymere<strong>2018</strong><br />

Cluster<br />

Neue Werkstoffe<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 39


Coffee capsules & pods<br />

Bio-PBS to<br />

increase<br />

benefits<br />

of PLA coffee<br />

capsules<br />

BIO PBS<br />

Flexible<br />

Higher<br />

Faster<br />

Translucent<br />

Higher<br />

Lower<br />

Lower<br />

By:<br />

Fabien Resweber & Pissapak Srihaphan<br />

PTT MCC Biochem Company Limited<br />

Bangkok, Thailand<br />

Flexibility<br />

Impact strength<br />

Biodegradability<br />

Heat resistance<br />

Process temp.<br />

Heat-seal temp.<br />

Transparency<br />

Rigid<br />

Lower<br />

Slower<br />

Lower<br />

Higher<br />

Higher<br />

PLA<br />

Transparent<br />

The coffee capsules sold by one major brand in 2013 alone<br />

created enough waste to encircle the earth more than<br />

ten times. The high fraction of water and coffee grounds<br />

makes them difficult to incinerate or recycle, a problem that<br />

could easily be circumvented by using compostable capsules<br />

based on BioPBS. The benefits of BioPBS were introduced<br />

during a presentation at two separate Single Serve Capsules<br />

conferences, one last year in Berlin, the other this year in Chicago,<br />

in which the outstanding compostability of this material<br />

was highlighted.<br />

BioPBS reduces cycle time while increasing HDT<br />

and Izod Impact strength<br />

One key benefit of blending BioPBS with PLA for injection<br />

moulding is that the degree of crystallinity of the matrix<br />

increases. PLA is an amorphous material with<br />

a very long cooling time. Adding BioPBS can<br />

therefore significantly shorten its cycle time. In a<br />

PLA blend with 20% BioPBS, the crystallization<br />

process is accelerated, reaching a percentage of<br />

crystallinity of 50 %; in a 40/60 blend of BioPBS/PLA<br />

a peak level of 80 % can be reached. Cycle time<br />

can be cut in half compared to cPLA , without<br />

compromising capsule mould productivity.<br />

Increasing the BioPBS content to 60 % or higher<br />

also improves the thermal properties of PLA,<br />

allowing the HDT A (0.45 MPa) value to be increased to<br />

almost 100 °C. As a result, BioPBS-based capsules<br />

will not twist or lose their shape during use, nor clog<br />

up the coffee machine. Increasing the BioPBS ratio<br />

from 20 to 40 has the additional advantage of improving<br />

the Izod impact strength of the material. Even better<br />

results are achieved if a 60/40 blend of BioPBS/PLA is used.<br />

Basically, the more BioPBS that is added, the more flexibility<br />

that can be expected from the compound. On the other hand,<br />

the PLA component increases the biobased content and adds<br />

solidity to the cap body.<br />

BioPBS meets new challenges for coffee capsules<br />

Previously, compostable coffee capsules had a limited<br />

oxygen barrier and required secondary packaging for<br />

wrapping. New solutions for compostable oxygen barriers<br />

now exist for all coffee capsule designs, decreasing the<br />

total amount of packaging needed. Barrier solutions mainly<br />

include the use of compostable IML (In-Mould-Labelling) or<br />

a compostable barrier layer injection molded in a co-injection<br />

process, and are perfectly compatible with BioPBS-based<br />

compostable capsules.<br />

In countries or cities where organic waste is collected, fully<br />

compostable capsules can be included in that composting<br />

stream, increasing the amount of waste being recycled through<br />

this organic recycling process. However, since industrial<br />

composting facilities are not yet accessible worldwide, there<br />

is now a strong market demand for a coffee capsule that will<br />

biodegrade in a home composting environment at ambient<br />

temperatures. BioPBS offers a way to make this possible,<br />

as this material provides a fast degrading polymer matrix,<br />

even at ambient temperature. BioPBS is increasingly gaining<br />

acceptance and is used as the raw material in various global<br />

sustainable coffee capsule brands for injection<br />

moulded and mesh parts.<br />

Total solution for compostable coffee<br />

capsules<br />

BioPBS can be applied in all the various parts<br />

of the coffee capsule, depending on the grade<br />

used. BioPBS lidding film (BioPBS sealant +<br />

barrier cellulose) provides an excellent oxygen<br />

barrier; BioPBS body or cap offers flexibility,<br />

heat resistance, and reduced cycle time. Finally,<br />

BioPBS can be used in a mesh (nonwoven filter)<br />

part on the bottom of the capsule to retain the<br />

ground coffee.<br />

The burgeoning popularity of single serve coffee<br />

capsules is cause for concern, as their use generates<br />

a vast amount of waste. Changing to a BioPBS capsule<br />

could definitely help solve this waste problem.<br />

Environmental benefits<br />

Formulating a coffee capsule material with a high BioPBS<br />

content can contribute to the reduction of non-recyclable<br />

waste and decrease the impact on the environment. Capsules<br />

made with BioPBS can be treated as organic waste, which<br />

means they can be disposed of in the organic waste bin (where<br />

available and permitted) without separating them from the<br />

coffee grounds. In applications like this, where it is impossible<br />

to re-use or recycle, compostable materials definitely<br />

contribute to cleaner end-of-life options and lower disposal<br />

costs.<br />

www.pttmcc.com<br />

40 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Coffee capsules & pods<br />

PürPod100<br />

In 2015 Club Coffee, Toronto, Ontario, Canada, introduced<br />

PürPod100, what was, as stated by the company, the<br />

world’s first 100 % compostable, fully certified singleserve<br />

pod.<br />

“The amount of used single-serve pods sent into the<br />

waste stream last year could have circled the earth eleven<br />

times. That’s not acceptable,” said John Pigott, CEO, Club<br />

Coffee. “We have the most viable solution available to that<br />

issue – a pod that will be certified as 100 % compostable<br />

and can be converted to useful compost.”<br />

“As a large manufacturer and distributor of packaged<br />

coffee, we have a responsibility to our customers, and<br />

to society, to reduce the environmental impact of our<br />

activities.”<br />

The PürPod100 is made from renewable, biobased<br />

materials (more details were not disclosed) that are 100 %<br />

compostable, and the ring of the pod is made using coffee<br />

chaff – the skin of the coffee bean that comes off during<br />

the roasting process. Every single part of the PürPod100 is<br />

designed to be digestible by, and accessible for, bacteria.<br />

The PürPod100 is compatible with most Keurig brewing<br />

systems, including the new Keurig 2.0 brewers.<br />

“Still, plastic (and aluminium – MT), single serve coffee<br />

pods are included in this disposable waste stream. Where<br />

curbside food scrap collection programs exist, certified<br />

compostable products have the ability to help increase<br />

waste diversion while reducing contamination in the finished<br />

compost,” said Al Rattie, Director of Market Development,<br />

US Composting Council. “We hope that companies like Club<br />

Coffee will continue to work with the USCC to not only develop<br />

products that are tools for diversion, but also help support<br />

the growth of the food scrap collection and processing<br />

infrastructure needed to close the loop on products like<br />

compostable coffee pods. The resulting production and<br />

land application of high quality compost is essential for the<br />

creation of healthy soils and a sustainable society.”<br />

The PürPod100 was developed in conjunction with international<br />

experts and scientists at the University of Guelph.<br />

“Science shows that composting is an effective and<br />

conscientious solution to this growing environmental<br />

problem”, added Pigott. “Recycling isn’t a convenient or welldeveloped<br />

solution because hot pods full of coffee grounds<br />

must be carefully separated and cleaned before collection.”<br />

Steve Mojo, then executive director of the certifying body<br />

BPI, said, “Club Coffee’s () pods represent a significant<br />

improvement in single-serve coffee. Everyone involved in this<br />

technological advancement are commended for their hard<br />

work. All BPI approved products meet ASTM D6400 or ASTM<br />

D6868 based on independent lab testing, whose results are<br />

verified by NSF International.” In the meantime Club Coffee<br />

received certification for the PürPod 100 products.MT<br />

www.clubcoffee.ca<br />

RING<br />

Made with coffee bean skins and<br />

other compostable materials<br />

LID<br />

Made with paper and<br />

other compostable materials<br />

FILTER<br />

Made with plant-based materials<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 41


Materials<br />

Multilayer transparent<br />

barrierfilms<br />

Four key players in the bioplastics industry - Eurotech Extrusion Machinery, NatureWorks, Nippon<br />

Gohsei and Sukano - have successfully processed a multilayer transparent biobased barrier film. This<br />

allows packaging manufacturers to count coextruded film structure as a potential replacement for<br />

conventional fossil fuel-based structures in dry food packaging.<br />

Flexible multilayer plastic packaging design remains<br />

a major challenge, as most conventional multilayer<br />

films are neither recyclable nor compostable. As of today,<br />

there is a lack of recyclability for this kind of packaging<br />

that still makes up over 75 % of the food industry usage.<br />

Understanding this gap in the market, four key players<br />

in the bioplastics industry have joined together to find a<br />

solution. Eurotech Extrusion Machinery (Tradate, Italy),<br />

NatureWorks (Minnetonka, Minnesota, USA), Nippon Gohsei<br />

(headquartered in Osaka, Japan) and Sukano (Schindellegi,<br />

Switzweland) have now successfully processed a multilayer<br />

transparent biobased barrier film.<br />

Ingeo resin processed into a film is already used in many<br />

types of flexible packaging. Using Ingeo provides for a<br />

reduced carbon footprint, as well as compostability as an<br />

end of life option. For higher gas barrier requirements, a<br />

coating or a metallization surface treatment of the film<br />

is typically required. However, the need for this coating<br />

or metallization can be eliminated through the use of a<br />

barrier polymer to produce a coextruded structure. This<br />

provides an additional, new option for packing foods which<br />

require an extended shelf life, while still offering clarity and<br />

compostability.<br />

The coex film processed at Eurotech used a K5A 5<br />

layer blown film lab machine in a configuration using two<br />

extruders 25 mm, and three extruders 20 mm, including the<br />

die lip of 100 mm diameter and 1.4 mm gap.<br />

The total film thicknesses of 45 µm, 280 mm width,<br />

contains Ingeo PLA 4<strong>04</strong>3D from NatureWorks and is used<br />

in the inner A layer, with an outer bubble layer E including<br />

Sukano masterbatches processing aids. These PLAbased<br />

Sukano masterbatches were specifically designed<br />

for this application. The tie layers use BTR8002P and the<br />

barrier layer uses G-polymer both from Nippon<br />

Gohsei. This combination of formulation<br />

and process conditions yielded a<br />

stable bubble, excellent film<br />

transparency, and good roll<br />

quality.<br />

Testing showed that<br />

the use of Sukano<br />

masterbatches<br />

offered increased melt<br />

strength, and therefore<br />

better processability,<br />

good transparency and<br />

better adhesion during sealing.<br />

Mechanical properties were also<br />

maintained. As an additional benefit<br />

each material used in the film has either been tested and<br />

certified or assessed to be biodegradable and industrially<br />

compostable according to European norm EN 13432. Less<br />

film sticking was managed via the use of slip agent biobased<br />

masterbatches, which increased the processing window<br />

and ensured good processability conditions and a lower<br />

COF (coefficient of friction), therefore conferring better film<br />

properties for secondary fabrication steps.<br />

For the barrier layer Nichigo G-Polymer, the World’s first<br />

Extrudable High Barrier Amorphous Vinyl Alcohol Resin,<br />

was used. This provided key benefits in packaging, such<br />

as excellent gas and aroma barrier and high transparency,<br />

while supporting compostability and recyclability properties<br />

of the final film produced. Outstanding water solubility for<br />

solution coating barrier applications and extrudability were<br />

also evident. The G-Polymer barrier is so effective that it can<br />

replace Alu-foil in many packaging applications. And even<br />

at 4mm thickness of mono-layer G-Polymer, transparency<br />

was glass-like. The tie layer BTR8002P gives high adhesion<br />

between layers, maintaining high transparency<br />

The achievement of this multilayer transparent biobased<br />

barrier film allows packaging manufacturers to count<br />

multilayer film structure as a potential replacement for<br />

conventional fossil fuel-based structures in dry food<br />

packaging such as lid films for coffee capsules or lidding<br />

films for cups and trays, flow packs, trays for snacks, and<br />

biscuits packages. And it may even extend to certain humid<br />

foods such as ham, fish, and meat when used with proper<br />

packaging design. MT<br />

www.sukano.com | www.natureworksllc.com<br />

www.nippon-gohsei.com | www.eurexma.com<br />

Bio-Barrier<br />

with<br />

Nichigo<br />

G-Polymer<br />

Existing<br />

Barrier<br />

(PP/EVOH/PP)<br />

Barrier Layer [µm] 13 12<br />

Humidity in Barrier [%] 26 4<br />

WVTR [g/capsule<br />

day]<br />

OTR [cm 3 /capsule<br />

day Air]<br />

38°C 90%RH 0.059 0.007<br />

23°C Inner Dry,<br />

Outer 50%RH<br />

0.0002 0.0008<br />

42 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


From Science & Research<br />

Bioplastic made of cactus<br />

(Photo: EFE)<br />

With the juice of nopal, a plant of the cactus family and<br />

basic ingredient in Mexican cuisine, a Mexican researcher<br />

has created a natural biodegradable plastic<br />

that can reduce pollution.<br />

Sandra Pascoe, from the Universidad del Valle de Atemajac<br />

(Univa) in Guadalajara, western Mexico, developed this plastic<br />

after several experiments with this cactus often used in salads<br />

and traditional Mexican stews.<br />

At first, she experimented with dried pieces of nopal, which<br />

she mixed with additives, but the process was slow and the<br />

physical and chemical characteristics changed a lot. “The<br />

material oxidized quickly”, she told the Mexican news agency<br />

EFE.<br />

Sandra then began to use the juice of the species’opuntia<br />

ficus indica’, the most common among the nopal trees and<br />

widely used as a vegetable. Later she took the so-called<br />

opuntia megacantha, which is famous for its fruit called tuna,<br />

very juicy but covered all over with thorns.<br />

“Basically, the plastic is made from the sugars in the nopal<br />

juice, the monosaccharides and polysaccharides it contains,”<br />

the researcher explained.<br />

Sandra pointed out that the cactus has a very viscous<br />

consistency that comes from these sugars, pectin and organic<br />

acids and “that viscosity is what we are taking advantage of so<br />

that a solid material can be produced”, she said.<br />

In her lab at the Department of Exact Sciences and<br />

Engineering, Pascoe glycerol, natural waxes, proteins and<br />

colorants with the juice after it has been strained to remove its<br />

fibers, creating a formula that is then dried on a hot plate to<br />

produce thin sheets of plastic.<br />

This process was registered with the Mexican Institute<br />

of Intellectual Property (IMPI) in 2014 and the development<br />

became possible with funding from the National Council of<br />

Science and Technology (Conacyt) of Mexico.<br />

The researcher told EFE that with the support of the<br />

campus of Biological and Agricultural Sciences of the<br />

University of Guadalajara, she is in the process of investigating<br />

the degradation characteristics of this plastic, i.e. in what<br />

conditions and how long it takes to decompose in a natural<br />

environment.<br />

“We have done very simple degradation tests in the<br />

laboratory. We have put it for example in water and we found<br />

that it does disintegrate. However, we still need to do a<br />

chemical test to see if the material has really been completely<br />

disintegrated. We have also done tests on moistened compost<br />

soil and the material is also disintegrated”, she added.<br />

Sandra said that in addition to shopping bags, the nopal<br />

juice plastic could be used for applications such as cosmetic<br />

containers, imitation jewelry and toys.<br />

Tests are currently being conducted to establish how much<br />

weight the plastic can bear which will help determine what<br />

other products it could be used for.<br />

She explained that projects have already been done at<br />

student level to generate prototypes “very simple and it is clear<br />

that there is potential to do a lot more with this material”.<br />

At the moment thermal properties and the density of the<br />

plastic are being determined to learn how much weight it<br />

can resist in case of being transformed into bags and other<br />

products.<br />

The next step on the path towards commercialization will be<br />

to make or buy a machine that can produce prototypes of the<br />

plastic bags in order to market them to businesses.<br />

The innovation is in the process of being patented. Once this is<br />

granted by the IMPI, it will be possible to generate agreements<br />

to transfer the technology to interested companies, Sandra<br />

Pascoe concluded. MT Source: EFE tinyurl.com/cactusplastic<br />

(Photo: Kerstin Neumeister)<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 43


From Science & Research<br />

From coffee grounds to plastic<br />

Introduction<br />

Europe is one of the largest importers of coffee. However,<br />

currently industrial utilization of the coffee grounds generated<br />

during production is carried out only to a limited extent [1], [2].<br />

Some companies already have recognized the potential of<br />

the “coffee ground” residue and have even brought plastic<br />

products to the market containing coffee grounds (3D printing<br />

filaments, cappuccino cups, yarns, etc. [3] [4] [5]). However,<br />

there are no (biobased) plastic compounds containing coffee<br />

grounds commercially available on the market, which are<br />

suitable for processing methods like injection molding or<br />

extrusion blow molding.<br />

In a first feasibility study in 2016, the processing as well as<br />

the effect of the residues on biobased polymers were analyzed<br />

at the IfBB - Institute for Bioplastics and Biocomposites,<br />

University of Applied Sciences and Arts Hanover [2]. To save<br />

fossil raw materials like crude oil, coffee grounds have been<br />

primarily used as a filler to substitute conventional polymers.<br />

Furthermore, the residues were used as a colouring agent<br />

in different kinds of polymers. In the current project, novel<br />

fully biobased composites, especially for applications such<br />

as coffee consumer goods, computer accessories and for the<br />

office sector are being developed and modified.<br />

Used material<br />

The additivation of the coffee grounds was carried out in a<br />

PLA matrix (injection molding type). Other additives such as<br />

an impact modifier (IPM) and wood fibers (NF) were also used<br />

to enhance the performance (improved load transmission<br />

through fiber reinforcement) and appearance.<br />

Coffee Grounds<br />

Large differences in the particle size or agglutination of the<br />

coffee grounds leads to agglomeration during extrusion, as<br />

previous studies show. Therefore, a non-homogenous dosage<br />

of the coffee grounds into plastic would hinder an industrial<br />

processing [2]. For an optimized process and to control, as<br />

well as to determine, material properties (stiffness, strength,<br />

crystallization, etc.), the quality control of particle size and<br />

distribution of the coffee grounds are decisive.<br />

Figure 1: SEM image (magnification: 100X) PLA + Coffee grounds + NF<br />

coffee grounds<br />

NF<br />

44 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


From Science & Research<br />

By:<br />

Daniela Jahn, Sebastian Spierling, Andrea Siebert-Raths<br />

IfBB – Institute for Bioplastics and Biocomposites,<br />

Hanover University of Applied Sciences and Arts – IfBB<br />

Hanover, Germany<br />

Experimental Procedure<br />

For extrusion processing, a technical co-rotating<br />

KraussMaffei twin-screw extruder ZE 34 Basic was used. The<br />

matrix and impact modifier were added at the beginning of the<br />

extruder in the melting zone. The dosage of coffee grounds<br />

and natural fibers was conducted via a side feeder unit.<br />

Adapted screw configurations enabled a cautious<br />

incorporation without damaging the PLA, the residue or the<br />

fibers. Due to specific screw configurations, predrying of the<br />

material was not required, i.e. prior opened vacuum degassing<br />

extracts the remaining humidity during the process.<br />

For production of test specimens via injection moulding, a<br />

KraussMaffei KM50-180 AX injection moulding machine was<br />

used (tensile test bars type 1A DIN EN ISO 527).To prevent<br />

molecular chain degradation by hydrolysis, pellets were dried<br />

before processing under 500 ppm) [6]. Subsequently, the<br />

microstructures and mechanical and thermal-mechanical<br />

properties of the coffee ground compounds were determined.<br />

Material Properties<br />

To analyze the connection of coffee particles and natural<br />

fibers in the PLA, the samples were analyzed by scanning<br />

electron microscopy (SEM). Figure 1 shows the coffee particles<br />

and natural fibers fully embedded in the PLA matrix. Thus, a<br />

good fiber-matrix adhesion, which results in an optimized load<br />

transmission of the fibers/coffee particles under mechanical<br />

loads, could be realized.<br />

As known from the literature, by adding fillers or fibers as a<br />

function of the concentration the flowability (MFR) and impact<br />

strength is reduced. By implication, the tensile modulus is<br />

increased [7]. The situation is similar with the coffee grounds<br />

used (Figure 2). Both with coffee grounds and with natural<br />

fibers, the impact strengths are reduced, which in turn<br />

increased the tensile modulus of elasticity. Due to the<br />

addition of particles and fibers, a reduction in the cycle<br />

time during the injection molding process was identified<br />

for all the materials. This positive effect suggests that the<br />

crystallinity (K) of the materials was increased.<br />

Figure 2: Thermomechanical<br />

properties<br />

of coffee grounds<br />

compounds<br />

Tensile<br />

strength<br />

150%<br />

PLA<br />

Cycle<br />

time<br />

100%<br />

50%<br />

Tensile<br />

modulus<br />

PLA + Coffee<br />

grounds<br />

PLA + 10% NF<br />

0%<br />

HDT-B<br />

Impact<br />

strength<br />

PLA + 10% Coffee<br />

grounds + 10% NF<br />

PLA + 10% Coffee<br />

grounds + 10% NF<br />

+ 8% IPM<br />

MFR<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 45


From Science & Research<br />

This usually leads to the fact, that the materials in the injection<br />

molding process achieve the dimensional stability in such a<br />

way that they can be ejected earlier (reduced cycle time).<br />

However, the increase of K is not apparent from the HDT-B.<br />

The degree of crystallization (K) is determined according to<br />

a melting enthalpy (ΔHm) of the second DSC heating curve<br />

(DSC 2<strong>04</strong> F1 Phoenix Netzsch) using the material dependent<br />

theoretical value for a 100% crystalline material. For PLA, this<br />

theoretical value is 93 J/g (ΔHLit )(Figure 3) [8].<br />

The degree of crystallization can be calculated by the<br />

formula (K = (∆Hm )/(∆HLit.)*100 [%] ) [9].<br />

Depending on PLA, the melting enthalpy and the crystallinity<br />

is increased by the addition of residues and / or fibers from<br />


©<br />

©<br />

-Institut.eu | <strong>2018</strong><br />

-Institut.eu | 2017<br />

Full study available at www.bio-based.eu/reports<br />

Full study available at www.bio-based.eu/reports<br />

©<br />

-Institut.eu | 2017<br />

Full study available at www.bio-based.eu/markets<br />

Bio- and CO 2 -based Polymers & Building Blocks<br />

The best market reports available<br />

Data for<br />

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and Polymers – Global Capacities<br />

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E-mail: j.ravenstijn@kpnmail.nl<br />

Mobile: +31.6.2247.8593<br />

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July 2017<br />

This and other reports on the bio-based economy are available at<br />

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Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />

April 2017<br />

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Policies impacting bio-based<br />

plastics market development<br />

and plastic bags legislation in Europe<br />

Asian markets for bio-based chemical<br />

building blocks and polymers<br />

Market study on the consumption<br />

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A comprehensive market research report including<br />

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Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />

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www.bio-based.eu/reports<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 47


Basics<br />

Biocatalytic process<br />

to produce FDCA<br />

By:<br />

Stephan Roest<br />

Market Development Manager<br />

Corbion<br />

Gorinchem, The Netherlands<br />

PEF has become the popular new plastic on the block,<br />

and companies like Corbion (Gorinchem, The Netherlands)<br />

are working hard on its market introduction.<br />

The new monomer FDCA is key to the plastic, and makes<br />

it possible to produce PEF as an alternative to for instance<br />

PET. Of all the companies working on the commercial-scale<br />

production of FDCA, Corbion is the only one that uses a biocatalytic<br />

route to produce FDCA from sugars.<br />

Corbion is pioneering a highly efficient biocatalytic<br />

process to produce 2,5-Furandicarboxylic acid (FDCA) as<br />

a monomer for the bioplastic PEF (polyethylenefuranoate).<br />

Corbion has been developing this route since 2013, when<br />

it obtained the biotechnology route with the acquisition of<br />

biotech company Bird Engineering. The biocatalytic route<br />

to FDCA is a perfect match with Corbion’s fermentation and<br />

purification experience and capabilities in lactic acid.<br />

Like a jacuzzi<br />

Starting from C6 sugars, Corbion first produces the<br />

intermediate 5-hydroxymethylfuryfral (HMF). The raw-<br />

HMF is then fed to microorganisms that transfers the HMF<br />

into FDCA. Conventional ways use selective oxidation with<br />

platinum (or other noble metal or non-noble metal) catalysts.<br />

One advantage of Corbion’s biocatalytic process is that is<br />

has very mild conditions: to get the best production from<br />

the microorganisms, the process has to be as comfortable<br />

as possible for them, being: neutral pH, no-pressure, 37 °C<br />

and a bit of aeration. You can picture it as a jacuzzi!<br />

On top of that, due to the enzymatic conversion, the<br />

process shows very high yields (>99%) and has a very high<br />

selectivity resulting in high purity FDCA with virtually no byproduct.<br />

This also allows to use raw-HMF without the need<br />

to purify the HMF inbetween.<br />

Corbion has been purifying organic acids from<br />

fermentation-broths for over 85 years which is a great<br />

experience to build on when it comes to purifying the FDCA<br />

from the broth. This process results in a very pure polymergrade<br />

FDCA that has found its use in many polymer and<br />

chemical applications already, that are now being tested<br />

and validated for market introduction.<br />

Making PEF a reality<br />

FDCA can replace oil-based purified terephthalic<br />

acid (PTA), as used to produce PET and a wide variety<br />

of other plastics. FDCA is not a direct replacement for<br />

PTA, as PEF is not a direct replacement for PET since<br />

their chemical structures are slightly different. However,<br />

they are sufficiently similar to allow FDCA to be used in<br />

combination with monoethylene glycol (MEG) in existing<br />

PET polymerization plants , making FDCA an infrastructure<br />

drop-in.<br />

PEF is a sustainable bioplastic that – if combined with<br />

biobased MEG - can be produced 100% biobased, boosting<br />

the sustainability credentials in key applications such as<br />

packaging.<br />

PEF bioplastic has already attracted a lot of attention<br />

as promising material across several industries, as<br />

manufacturers can see its potentially huge impact on the<br />

world. The benefits are clear (see table below). For food<br />

and beverages, for example, PEF enables to keep the<br />

products fresh longer than PET, due to the higher barrierproperties<br />

of the material. This also reduces the amount<br />

of food waste. Compared to PET, PEF is stronger allowing<br />

for further light weighting of a packaging product, saving<br />

material and transportation costs. Also the higher glass<br />

transition temperature is of value: as it is above 85 °C, the<br />

PEF allows for hot-filling of nutritious or oxygen sensitive<br />

drinks, like sports-drinks, without the need to enforce the<br />

top and shoulder of the bottle with extra material, that is<br />

nowadays is required for PET.<br />

Choosing biobased plastics like PEF means contributing<br />

to the transition towards a circular economy. Not only can<br />

PEF be recycled, just as well as PET, but it is also fully<br />

biobased which means a decoupling from fossil resources.<br />

With these advantages, it’s not hard to see why PEF has<br />

become so popular in the last couple of years.<br />

PEF properties table<br />

PEF PET Benefit<br />

Barrier O 2<br />

6 – 10 x 1 x<br />

• Increased shelf life / reduced food waste<br />

• No need for additional barrier layers<br />

CO 2<br />

4 – 6 x 1 x<br />

• Increased shelf life / reduced food waste<br />

• No need for additional barrier layers<br />

H 2<br />

O 2 x 1 x • Better performance in warm and humid areas<br />

Mechanical<br />

Tensile<br />

Modulus<br />

~1.6 x 1 x<br />

• Perfect for rigid bottles / Increased top load<br />

• Allow for further light-weighting<br />

Thermal T g<br />

(°C) 86 – 87 74 – 79 • Hot-filling at 85 °C of oxygen sensitive drinks (PET bottle needs enforcement to allow this)<br />

T m<br />

(°C)<br />

213 –<br />

235<br />

234 –<br />

265<br />

• Co-extrusion possibilities<br />

• Reduced processing temperatures<br />

48 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Basics<br />

COMPEO<br />

Corbion makes it happen<br />

The people at Corbion are excited to be at the<br />

forefront of this innovation in this field. For FDCA and<br />

PEF, they are actively working together with partners<br />

throughout the value chain – from sugar suppliers to<br />

brand owners – to introduce this new material to the<br />

market on commercial scale, and make it happen.<br />

Leading compounding technology<br />

for heat- and shear-sensitive plastics<br />

HO<br />

O<br />

O<br />

O<br />

O<br />

OH<br />

O<br />

FDCA<br />

HO<br />

OH<br />

PTA<br />

www.corbion.com<br />

Development of PEF film by Corbion<br />

Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />

With its new COMPEO Kneader series, BUSS continues<br />

to offer continuous compounding solutions that set the<br />

standard for heat- and shear-sensitive applications, in all<br />

industries, including for biopolymers.<br />

• Moderate, uniform shear rates<br />

• Extremely low temperature profile<br />

• Efficient injection of liquid components<br />

• Precise temperature control<br />

• High filler loadings<br />

www.busscorp.com<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 49


Basics<br />

PEF and PET bottle recycling<br />

Last year Synvina, the joint venture of Avantium and BASF,<br />

received interim approval from the European PET bottle<br />

platform (EPBP) for the market introduction of PEF up to<br />

2 % of the total European PET consumption. The actual recyclability<br />

of a PEF end-product, as any product, will however depend<br />

on how it is designed and where it is launched, influencing<br />

what type of collection and sorting infrastructure is present and<br />

if this can divert the products components to recycled material<br />

streams. Why then, did the EPBP already grant an interim approval?<br />

One of the reasons was that Synvina already at an early<br />

stage gathered and shared a significant amount of data that<br />

demonstrated that PEF is not only sortable, but that low levels of<br />

PEF are compatible with PET. Although not unique, this is a rare<br />

feature for plastics while the more common incompatibility has<br />

caused issues for some bioplastics in the past. In this article we<br />

take a deeper look into the nature of this compatibility and how<br />

it can put PEF in a unique position for a circular bottle economy.<br />

Why introduce a new bottle material?<br />

PET bottles are amongst the most successful examples<br />

of plastics recycling. However, in smaller size bottles, PET by<br />

itself is not always able to reach a logistically relevant shelf life.<br />

For example the mechanical criteria of a 8 oz (237ml) bottle<br />

can be met with 9-13 grams of PET while yielding a CO 2<br />

shelf<br />

life of only 4-6 weeks (4.2→3.5 Vol). To increase this, a bottle<br />

is often complemented by a coating or barrier layer. Coating<br />

equipment is not always economically attractive, for example<br />

if (seasonal) demand changes require flexible output. Using<br />

multilayer preforms for bottle production on the other hand may<br />

impose recyclability limitations for the bottles; infrared sorting<br />

equipment may still recognize them as PET while the barrier<br />

layer, if not removed, may disrupt rPET quality.<br />

PEF has been previously shown to enable logistically<br />

attractive shelf lives in small bottles and this is continuously<br />

being improved, as exemplified by the recent achievement of 16<br />

and 20 weeks shelf life in 10g and 14g PEF bottles respectively.<br />

Simultaneously PEF more and more exceeds mechanical<br />

performance over PET, while PET remains economically<br />

unattractive to produce from 100 % renewable sources. As such,<br />

PEF is becoming increasingly attractive as a bioplastic that<br />

brings material reductions beyond any other solution for small<br />

size plastic bottles. And because PEF is chemically different<br />

than any other plastic, near-infrared sorting equipment can<br />

automatically sort them from the PET stream.<br />

Controlling after-use material streams<br />

As most new (non-drop-in) bioplastics, PEF is chemically<br />

different from known materials and therefore has a unique<br />

infrared spectrum. This allows PEF bottles to be sorted out<br />

using automated near-infrared (NIR) sorting technology.<br />

Recent ambitions for higher recycling targets drive increased<br />

use of such technology to create separate streams beyond<br />

the most common streams of PET and HDPE, for example<br />

PP, PS and opaque PET. These infrastructure changes may<br />

also accommodate the creation of streams for bioplastics with<br />

interesting end-of-life options such as composting or recycling<br />

into new high value products. In the case of PEF, the similar<br />

chemistry to PET may even allow the use of existing PET<br />

Vol. CO2<br />

Vol. CO2<br />

4,30<br />

4,20<br />

4,10<br />

4,00<br />

3,90<br />

3,80<br />

3,70<br />

3,60<br />

3,50<br />

3,40<br />

3,30<br />

0 5 10 15 20 25<br />

4,30<br />

4,20<br />

4,10<br />

4,00<br />

3,90<br />

3,80<br />

3,70<br />

3,60<br />

3,50<br />

3,40<br />

Weeks<br />

3,30<br />

0 5 10 15 20 25<br />

Weeks<br />

237 mL Bole<br />

-17.5% CO 2<br />

237 mL Bole<br />

-17.5% CO 2<br />

recycling technology and assets. Nevertheless, automated<br />

sorting is not fail-safe and many recovery systems rely to a<br />

large extent on human sorting, either by the consumer or by<br />

professional sorters, for whom a PEF bottle is not always easy<br />

to distinguish from PET.<br />

PEF and PET compatibility<br />

Synvina has done multiple recycling tests using PEF and<br />

PET resins and bottle flakes, and consistently found that low<br />

levels of PEF did not affect the thermal profile of PET in a DSC<br />

experiment, while increasing levels started to induce melt point<br />

depression particularly at longer extrusion times. Furthermore,<br />

extrudates remained transparent. Further analysis by 13C NMR<br />

showed increased splitting of the furan ring ipso carbon with<br />

increased residence time, which an earlier study on PET copolyesters<br />

attributed to a transition from a blocky long-segment<br />

to a random co-polyester [1]. These observations confirm that<br />

PEF and PET undergo trans-esterification during processing,<br />

yielding a random co-polyester as the end-product. Extruded<br />

pellets remained transparent and had a lower tendency to form<br />

crystalline haze than neat reprocessed PET.<br />

50 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Basics<br />

By:<br />

Jesper van Berkel, Technical Application Manager, Synvina<br />

Amsterdam, The Netherland<br />

The 2 % and 5 % concentrations were selected for testing<br />

following the EPBP protocol at PTI Europe, which comprises<br />

the typical steps of a recycling process at 5kg-scale. These<br />

steps are outlined below with some of the critical control<br />

points.<br />

• Bottle grinding g Dust formation<br />

• Flake washing & Drying g Flake and/or water<br />

discoloration, sticking<br />

PEF in PET T g, mid<br />

T m, peak<br />

0 % 79 °C 249 °C<br />

2 % 79 °C 248 °C<br />

5 % 78 °C 247 °C<br />

10 % 78 °C 245-247 °C<br />

25 % 76 °C, 86 °C 207 °C, 240-246 °C<br />

• Re-extrusion into pellets g IV loss, side products or<br />

fumes<br />

• Solid State Polymerization g IV build, sticking of pellets<br />

• Injection into plaques/bottles with 50 % vPET g<br />

Transparency, color, bottle properties<br />

PEF in RPET (plaques following EPBP route with 50 % vPET)<br />

2x<br />

g<br />

PEF Molecule<br />

PET Molecules<br />

{<br />

None of the steps in the recycling process were found to<br />

display surprising phenomena in the presence of PEF, and all<br />

intermediate and final intrinsic viscosity measurements yielded<br />

comparable values. The only notable difference was that for<br />

the 5% loading the coloration of final plaques, as expressed by<br />

Δb* = 2.1 compared to the PET reference, was higher than the<br />

acceptable range of Δb* = 1.5. This is an aspect which we expect<br />

to improve with further improvements in PEF resin color. 1.5 L<br />

Bottles could be blown of the final resin, yielding properties as<br />

per the table below.<br />

Conclusion<br />

PEF can serve as a high value bioplastic material for<br />

applications where PET alone is not sufficient, and opposed<br />

to other barrier technologies this value can be retained when<br />

the bottles are recycled. Although yet to be demonstrated at<br />

scale, this can offer many opportunities; PET bales with nonrecyclable<br />

barrier bottles can be avoided, while PET bales with<br />

PEF may be used to reduce haze formation or as a source of<br />

separately accumulated PEF for individual rPEF campaigns<br />

with high value output. Ultimately, a separate stream of PEF<br />

bales can be created for an effective after-use economy.<br />

[1] H. Ma, M. Hibbs, D.M. Collard, S. Kumar, D.A. Shiraldi, Macromolecules<br />

2002 (35), 5123-5130<br />

www.synvina.com<br />

Property<br />

(1.5L 43g<br />

bottle)<br />

Final<br />

composition<br />

Burst<br />

Pressure<br />

Vol incr. at<br />

burst<br />

Thermal<br />

stability<br />

Drop test<br />

vertical 4°C<br />

Drop test<br />

vertical 22°C<br />

Top Load<br />

@1.0 mm<br />

deflection<br />

Method<br />

Mass<br />

balance<br />

Linear<br />

increase<br />

Linear<br />

increase<br />

4.25 vol CO 2<br />

,<br />

24h 38°C,<br />

Base pushup<br />

1.8 m,<br />

vertical<br />

bottom<br />

down, 72h<br />

1.8 m,<br />

vertical<br />

bottom<br />

down, 72h<br />

Typical<br />

Result<br />

PET<br />

2% Route 2 5% Route 2<br />

PET+<br />

1% PEF<br />

PET+2.5%<br />

PEF<br />

11.0 bar 11.8 bar 11.5 bar<br />

565 mL 594 mL 565 mL<br />

-4.0 mm -4.2 mm -4.1 mm<br />

8/8 OK 8/8 OK 8/8 OK<br />

8/8 OK 8/8 OK 8/8 OK<br />

Empty 225 N 240 N 225 N<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 51


Automotive<br />

Surr<br />

complex<br />

of<br />

10<br />

Years ago<br />

Published in<br />

bioplastics MAGAZINE<br />

Electronics<br />

Surround system of loudspeaker boxes with<br />

spherical shape: housing material Arboform<br />

of 10 mm wall thickness, lacquer coated<br />

Lignin Matrix Composites<br />

for Loudspeaker Boxes<br />

Article contributed by<br />

H. Nägele, J. Pfitzer, both of Tecnaro<br />

GmbH, Ilsfeld-Auenstein, Germany<br />

N. Eisenreich, W. Eckl, E. Inone-<br />

Kauffmann, E. Walschburger all<br />

Fraunhofer-ICT, Pfinztal,Germany<br />

B<br />

iocomposites obtained exclusively from renewable<br />

resources meet the requirements of sustainable<br />

processes and eco-innovation, and will expand future<br />

material research for engineering applications in industry.<br />

The properties, treatment and processing of these<br />

materials have to meet industrial standards concerning<br />

raw materials from biomass, fibres, wood extraction constituents<br />

and biopolymers, to enable their supply to mass<br />

consumer goods manufacturers, the construction industry,<br />

and the automotive and electronics industries. Thermoplastic<br />

matrices of composites include biopolymers such as<br />

polylactide (PLA), polyhydroxy-butyrate (PHB) and starch,<br />

as well as lignin from the paper industry. Reinforcement is<br />

carried out by the use of natural short fibres from hemp,<br />

flax and wood 1-4 . The natural polymer lignin is generated<br />

as a by-product of the pulp and paper industry, at a rate<br />

of approximately 60 million tonnes in chemical pulp mills<br />

every year, worldwide. This biomass extraction can also be<br />

carried out in an environmentally friendly way by using only<br />

water 5,6 . Thermal use of lignin for the power supply of the<br />

chemical pulp mills dominates its current utilisation rather<br />

than its use as a material for components. Its integration as<br />

a component in engineering materials has proven to be difficult<br />

7,8 . However, recent work has succeeded in establishing<br />

lignin as the main component of a new class of engineering<br />

materials: Arboform®, based only on renewable resources,<br />

applicable for use in industrial equipment parts 9,10 . Technical<br />

advantages of these materials over synthetic polymers,<br />

such as the acoustic properties of lignin matrix composites<br />

(Arboform), could strongly support their application.<br />

The material consists of lignin, natural fibres for<br />

reinforcement, and natural additives to support processing<br />

and performance. It exhibits wood-like properties. Various<br />

sources of lignin - from different pulping procedures - and<br />

of natural fibres such as wood, hemp, flax, sisal, kenaf<br />

etc. - can be used. The choice of the lignin depends on the<br />

application field of the product. However, the material can<br />

be processed like a thermoplastic material and used for<br />

various engineering products. The processing includes:<br />

• Mixing of the constituents: ligni<br />

(30-60%) and natural additives<br />

mixer.<br />

• Pelletizing of the mixture at amb<br />

granules. This step avoids comp<br />

used for plastic compounds<br />

• Processing of the granules at rela<br />

by standard injection moulding (<br />

facture parts<br />

This processing of lignin com<br />

on standard industrial injection m<br />

synthetic plastic resins. The tempe<br />

from 100°C in zone 1 to 170°C in z<br />

temperature can be between 155 and<br />

nozzle (2.5 – 4.0 mm). The back-pr<br />

high enough to enable a smooth rotat<br />

injection pressure is relatively high (>1<br />

injection speed. The holding pressure<br />

of the machine’s capacity and the rela<br />

seconds. The cooling time must be ext<br />

compared to that of a synthetic thermo<br />

The mould tools should be desig<br />

production of special materials. Impor<br />

design should take into account:<br />

• The shrinkage on injection moulding i<br />

not exceed 0.3%<br />

• Core-pullers should be foreseen for d<br />

are useful to achieve fast working cycle<br />

• Hot runner nozzles work only in limited<br />

Depending on the fibre content the<br />

can vary between 2 and 8 GPa and th<br />

Strength between 2 and 6 kJ/m 2 , but the<br />

be extended to 16 by the use of impac<br />

elongation at fracture is between 0.3-0.6<br />

expansion coefficient establishes below 5<br />

no resonance frequencies are found and a<br />

of vibration leads to excellent acoustic pr<br />

enables the material to be used in loudspeak<br />

Two types of loudspeaker housings wer<br />

manufactured according to the procedures d<br />

The material itself exhibits a unique structu<br />

from part to part (see fig. 1). Original colour<br />

brown, green and red. Figures 2 and 3 show<br />

boxes including a lacquered surface finish.<br />

info@tecnaro.de<br />

eri@ict.fraunhofer.de<br />

Housing parts of the complex loudspeaker<br />

design as obtained directly from the mould<br />

16 bioplastics MAGAZINE [<strong>04</strong>/08] Vol. 3<br />

52 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Automotive<br />

In July <strong>2018</strong>, Helmut Nägele<br />

Managing Director, Tecnaro says:<br />

ound system of loudspeaker boxes,<br />

shape: housing material Arboform<br />

with 5 mm wall thickness, lacquer<br />

coated<br />

n (40-70%), natural fibres<br />

(


Suppliers Guide<br />

1. Raw Materials<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

bioplastics.starch@agrana.com<br />

www.agrana.com<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel: +49 621 60-9995<br />

martin.bussmann@basf.com<br />

www.ecovio.com<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-018 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.comEurope<br />

contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

1.2 compounds<br />

Cardia Bioplastics<br />

Suite 6, 205-211 Forster Rd<br />

Mt. Waverley, VIC, 3149 Australia<br />

Tel. +61 3 85666800<br />

info@cardiabioplastics.com<br />

www.cardiabioplastics.com<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 <strong>04</strong>24 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Green Dot Bioplastics<br />

226 Broadway | PO Box #142<br />

Cottonwood Falls, KS 66845, USA<br />

Tel.: +1 620-273-8919<br />

info@greendotholdings.com<br />

www.greendotpure.com<br />

39 mm<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631<strong>04</strong>5<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

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= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,4<strong>04</strong>.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 <strong>04</strong>1 5190621<br />

Fax.: +39 <strong>04</strong>1 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 2716865<br />

Mob: +86 18699400676<br />

maxirong@lanshantunhe.com<br />

http://www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

Global Biopolymers Co.,Ltd.<br />

Bioplastics compounds<br />

(PLA+starch;PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 915<strong>04</strong>46<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.kingfa.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

Natureplast – Biopolynov<br />

11 rue François Arago<br />

14123 IFS<br />

Tel: +33 (0)2 31 83 50 87<br />

www.natureplast.eu<br />

54 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Suppliers Guide<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7062/97687-0<br />

www.tecnaro.de<br />

1.3 PLA<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

TIPA-Corp. Ltd<br />

Hanagar 3 Hod<br />

Hasharon 4501306, ISRAEL<br />

P.O BOX 7132<br />

Tel: +972-9-779-6000<br />

Fax: +972 -9-7715828<br />

www.tipa-corp.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.4<strong>04</strong>.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

Total Corbion PLA bv<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem<br />

The Netherlands<br />

Tel.: +31 183 695 695<br />

Fax.: +31 183 695 6<strong>04</strong><br />

www.total-corbion.com<br />

pla@total-corbion.com<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

1.6 masterbatches<br />

4. Bioplastics products<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 051 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

1.4 starch-based bioplastics<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Bio4Pack GmbH<br />

D-48419 Rheine, Germany<br />

Tel.: +49 (0) 5975 955 94 57<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Albrecht Dinkelaker<br />

Polymer and Product Development<br />

Blumenweg 2<br />

79669 Zell im Wiesental, Germany<br />

Tel.:+49 (0) 7625 91 84 58<br />

info@polyfea2.de<br />

www.caprowax-p.eu<br />

2. Additives/Secondary raw materials<br />

BeoPlast Besgen GmbH<br />

Bioplastics injection moulding<br />

Industriestraße 64<br />

D-40764 Langenfeld, Germany<br />

Tel. +49 2173 84840-0<br />

info@beoplast.de<br />

www.beoplast.de<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

6.2 Laboratory Equipment<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

1.5 PHA<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />

45, 0,90, 0<br />

10, 0, 80,0<br />

(ICBP) C, M, Y, KSDN BHD<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

0, 0, 0, 0<br />

12, Jalan i-Park SAC 3<br />

Senai Airport City<br />

81400 Senai, Johor, Malaysia<br />

Tel. +60 7 5959 159<br />

marketing@icbp.com.my<br />

www.icbp.com.my<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6155<br />

Fax: +81-54-623-8623<br />

info_fds@saidagroup.jp<br />

www.saidagroup.jp/fds_en/<br />

7. Plant engineering<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 051 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

91301 Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, COO<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima.com<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13 55


Suppliers Guide<br />

‘Basics‘ book<br />

on bioplastics<br />

110 pages full<br />

color, paperback<br />

ISBN 978-3-<br />

9814981-1-0:<br />

Bioplastics<br />

ISBN 978-3-<br />

9814981-2-7:<br />

Biokunststoffe<br />

2. überarbeitete<br />

Auflage<br />

This book, created and published by Polymedia<br />

Publisher, maker of bioplastics MAGAZINE<br />

is available in English and German language<br />

(German now in the second, revised edition).<br />

The book is intended to offer a rapid and uncomplicated<br />

introduction into the subject of bioplastics, and is aimed at all<br />

interested readers, in particular those who have not yet had<br />

the opportunity to dig deeply into the subject, such as students<br />

or those just joining this industry, and lay readers. It gives<br />

an introduction to plastics and bioplastics, explains which<br />

renewable resources can be used to produce bioplastics,<br />

what types of bioplastic exist, and which ones are already on<br />

the market. Further aspects, such as market development,<br />

the agricultural land required, and waste disposal, are also<br />

examined.<br />

An extensive index allows the reader to find specific aspects<br />

quickly, and is complemented by a comprehensive literature<br />

list and a guide to sources of additional information on the<br />

Internet.<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7013 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

9. Services<br />

Osterfelder Str. 3<br />

46<strong>04</strong>7 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

9. Services (continued)<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62831<br />

silvia.kliem@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

3<strong>04</strong>53 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

10.3 Other Institutions<br />

The author Michael Thielen is editor and publisher<br />

bioplastics MAGAZINE. He is a qualified machinery design<br />

engineer with a degree in plastics technology from the RWTH<br />

University in Aachen. He has written several books on the<br />

subject of blow-moulding technology and disseminated his<br />

knowledge of plastics in numerous presentations, seminars,<br />

guest lectures and teaching assignments.<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

10. Institutions<br />

10.1 Associations<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

www.greenseredipity.nl<br />

Order now for € 18.65 or US-$ 25.00<br />

(+ VAT where applicable, plus shipping and handling,<br />

ask for details) order at www.bioplasticsmagazine.de/<br />

books, by phone +49 2161 6884463 or by e-mail<br />

books@bioplasticsmagazine.com<br />

Or subscribe and get it as a free gift<br />

(see page 57 for details, outside Germany only)<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

56 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


Events<br />

Subscribe<br />

now at<br />

bioplasticsmagazine.com<br />

the next six issues for €169.– 1)<br />

Event<br />

Calendar<br />

The 15 th ISBBB<br />

24.07.<strong>2018</strong> - 27.07.<strong>2018</strong> - Guelph, Canada<br />

http://isbbb.org<br />

You can meet us<br />

May / June<br />

Special offer<br />

for students and<br />

young professionals<br />

1,2) € 99.-<br />

2) aged 35 and below.<br />

end a scan of your<br />

student card, your ID<br />

or similar proof ...<br />

03 | <strong>2018</strong><br />

25 th Anniversary meeting of the Bio-Environmental<br />

Polymer Society (BEPS)<br />

15.08.<strong>2018</strong> - 17.08.<strong>2018</strong> - (Troy, 22.<strong>04</strong>.<strong>2018</strong> New York) - Geleen, Niederlande<br />

tinyurl.com/beps<strong>2018</strong><br />

1st PHA platform World Congress<br />

by bioplastics MAGAZINE<br />

<strong>04</strong>.09.<strong>2018</strong> - 05.09.<strong>2018</strong> - Cologne, Germany<br />

www.pha-world-congress.com<br />

Global Congress on Biotechnology<br />

06.09.<strong>2018</strong> - 07.09.<strong>2018</strong> - Bangkok, Thailand<br />

http://biotechnologycongress.alliedacademies.com/<br />

Innovation Takes Root <strong>2018</strong><br />

10.09.<strong>2018</strong> - 12.09.<strong>2018</strong> - San Diego (CA), USA<br />

www.innovationtakesroot.com/<br />

Wissensforum Biobasierte Kunststoff-Verpackungen<br />

25.09.<strong>2018</strong> - Nuremberg, Germany<br />

https://veranstaltungen.fnr.de/biokunststoffverpackung/grusswort/<br />

ISSN 1862-5258<br />

bioplastics MAGAZINE Vol. 13<br />

r1_05.2017<br />

Basics<br />

Castor Oil | 49<br />

Highlights<br />

Injection Moulding | 14<br />

Additives/Masterbatches | 18<br />

Cover Story:<br />

Netherlands to prohibit<br />

Oxo-degradables | 9<br />

... is read in 92 countries<br />

16 th International Symposium on Biopolymers <strong>2018</strong><br />

(ISBP <strong>2018</strong>)<br />

21.10.<strong>2018</strong> - 24.10.<strong>2018</strong> - Beijing, China<br />

www.isbp<strong>2018</strong>.com/<br />

13th European Bioplastics Conference<br />

<strong>04</strong>.12.<strong>2018</strong> - 05.12.<strong>2018</strong> - Berlin, Germany<br />

www.european-bioplastics.org/events/eubp-conference/<br />

Plastics beyond Petroleum - BioMass & Recycling<br />

25.06.2019 - 27.06.2019 - New York City Area, USA<br />

http://innoplastsolutions.com/conference.html<br />

bio!PSC: Conference on biobased packaging<br />

28.-29.05.2019 - Düsseldorf, Germany<br />

www.bio-psc.info<br />

05/05/17 11:39<br />

+<br />

or<br />

Mention the promotion code ‘watch‘ or ‘book‘<br />

and you will get our watch or the book 3)<br />

Bioplastics Basics. Applications. Markets. for free<br />

1) Offer valid until 30 Sep <strong>2018</strong><br />

3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

bioplastics MAGAZINE [<strong>04</strong>/18] Vol. Vol. 13 13 57


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Agrana Starch Bioplastics 33, 54<br />

Airbus 8<br />

Ajaa 26<br />

Albis Plastic 26<br />

AMIBM 10<br />

AMIBM 10<br />

Anellotech 18<br />

API 38 54<br />

Audi 26<br />

Avantium 7, 20, 50<br />

Axens 18<br />

BASF 36 54<br />

Bayern Innovativ 39<br />

Bcomp 24<br />

BeoPlast Besgen 55<br />

Bio4Pack 55<br />

Biobrush 26<br />

Bio-Fed 33 54<br />

Biomaterials Consulting 10<br />

Biomer 10 55<br />

Bio-on 14<br />

Biotec 10 55<br />

Bluepha 10<br />

BPI 41 56<br />

Braskem 8, 22, 23<br />

Buss 49, 55<br />

Caprowachs, Albrecht Dinkelaker 55<br />

Capsul'in 36<br />

Cardia Bioplastics 54<br />

Centexbel, 10<br />

Clic innovations 31<br />

Club Coffee 41<br />

Comac 8<br />

Corbion 6, 48<br />

DAB Motors 24<br />

Danimer 10<br />

DIN-Certco 9<br />

DLR 8<br />

Dr. Heinz Gupta Verlag 9<br />

Edding 26<br />

Electric GT 24<br />

Erema 21, 55<br />

EuropaBio 6<br />

European Bioplastics 19, 56<br />

Eurotech Extrusion Machinery 5, 42<br />

FKuR 10 2, 54<br />

Flex Farm technologies 6<br />

Fraunhofer UMSICHT 56<br />

FullCycle Bioplastics 10<br />

Gabriel Chemie 34<br />

Global Biopolymers 54<br />

GRABIO Greentech Corporation 55<br />

Grafe 54, 55<br />

Green Bay Decking 6<br />

Green Dot Bioplastics 54<br />

Green Serendipity 13 56<br />

grums aarhus 23<br />

Gucci 26<br />

Hallink 55<br />

Hasselt University 10<br />

Helian Polymers 10<br />

Hydal/Nafigate 10<br />

IFPEN 18<br />

Ikea 12<br />

Indochine Bio Plastiques 55<br />

Infiana Germany 55<br />

Inst. F. Bioplastics & Biocomposites 44 56<br />

Inst. f. Kunststofftechnik, Stuttgart 10 56<br />

Jelu Werk 6<br />

JinHui Zhaolong 54<br />

Kaneka 10 55<br />

Kingfa 54<br />

KraussMaffei 45<br />

LifetecVision 10<br />

MAIP 10<br />

Mango Materials 10<br />

Michigan State University 56<br />

Microtec 54<br />

Minima Technology 55<br />

Mockmill 26<br />

Modified Materials 10<br />

NaKu 16<br />

narocon InnovationConsulting 10 56<br />

Natureplast-Biopolynov 54<br />

NatureWorks 5, 42<br />

Naturtec 55<br />

Neste 12<br />

Nippon Gohsei 5, 42<br />

NNRGY 7<br />

nova Institute 10 12, 47, 56<br />

nova-Institut 8 17,32, 56<br />

Novamont 55, 60<br />

Novus 26<br />

NSF International 41<br />

Nurel 54<br />

OWS 10<br />

Paques 10<br />

PepsiCo 10<br />

Phario 10<br />

Plastic 31<br />

plasticker 37<br />

polymediaconsult 56<br />

PTT MCC Biochem 40 54<br />

Purcell Agri-Tech 10<br />

RKW 9<br />

Saida 55<br />

Scion Research 10<br />

SK Chemicals 21<br />

So Delicious 22<br />

STU Faculty Chem Food Tech 7<br />

Sukano 5, 42 54<br />

Suntory 18<br />

Swiss Coffee Company 36<br />

Synvina 50<br />

Tecnaro 6, 26, 52 55<br />

Tesla 24<br />

TGM, Vienna 1, 34<br />

TianAn Biopolymer 10 55<br />

TicToys 27<br />

Tipa 54<br />

Total Corbion PLA 23 55<br />

Trinseo 38<br />

TU Eindhoven 23<br />

Uhde-Inventa Fischer 35, 56<br />

UHU 26<br />

United Caps 8<br />

Univ Brno 7<br />

Univ del Valle de Atemajac 43<br />

Universal Forest Products 6<br />

UPM 6<br />

US Compostinf Council 41<br />

Velibre 37<br />

Velox 21<br />

VTT 31<br />

Walther Faltsysteme 22<br />

Xinjiang Blue Ridge Tunhe 54<br />

Yamaha 24<br />

Zhejiang Hangzhou Xinfu Pharm. 54<br />

Zhejiang Hisun Biomaterials 31, 54<br />

<strong>Issue</strong><br />

Editorial Planner<br />

Month<br />

05/<strong>2018</strong> Sep<br />

Oct<br />

06/<strong>2018</strong> Nov<br />

Dec<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

<strong>2018</strong><br />

01 Oct 18 28 Sep 18 Fiber / Textile /<br />

Nonwoven<br />

03 Dec 18 02 Nov 18 Films/Flexibles/<br />

Bags<br />

Edit. Focus 1 Edit. Focus 2 Edit. Focus 3 Basics<br />

Polyurethanes/<br />

Elastomers/<br />

Rubber<br />

Bioplastics<br />

from Waste<br />

Streams<br />

Poland & Baltic<br />

States Special<br />

t.b.d.<br />

Industrial Composting,<br />

Challenges / Hurdles<br />

Shelf Life of Bioplastics<br />

Trade-Fair<br />

Specials<br />

Subject to changes<br />

58 bioplastics MAGAZINE [<strong>04</strong>/18] Vol. 13


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YOUR NEEDS.<br />

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Made from potato starch, BIOPLAST® resins are designed to work on<br />

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films with a thickness of approx. 10-15 μm.<br />

S002<br />

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OK COMPOST<br />

HOME<br />

FOOD-CONTACT<br />

GRADE<br />

GMO FREE<br />

www.biotec.de<br />

member of the SPHERE<br />

group of companies<br />

LJ Corporate – © JB Mariou – BIOTEC HRA 1183


WWW.MATERBI.COM<br />

EcoComunicazione.it<br />

r1_05.2017

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