Issue 05/2015
bioplasticsMAGAZINE_1505
bioplasticsMAGAZINE_1505
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Fibers & Textiles<br />
By:<br />
Amparo Verdú Solís<br />
Extrusion Department Researcher<br />
AIMPLAS (Technological Institute of Plastics)<br />
Paterna, Spain<br />
PLA has good characteristics, many<br />
of them comparable or even better than<br />
those of conventional plastics derived from<br />
petroleum, which it makes suitable for a<br />
variety of uses. In comparison to PET and<br />
PP, which are the fibres mostly used at the<br />
moment in car interiors, PLA fibre meets<br />
almost all performance specifications of<br />
this application.<br />
The main limitation of conventional PLA<br />
is its thermal resistance; PLA softens at a<br />
temperature of around 52 °C, which limits its<br />
use in applications that require temperature<br />
resistance under pressure and conditions<br />
of environmental and chemical stress. The<br />
interior temperature in modern cars can<br />
easily exceed 80 °C on hot summer days.<br />
Melting temperature (°C)<br />
Modulus (GPa)<br />
260<br />
250<br />
220<br />
200<br />
180<br />
160<br />
140<br />
120<br />
100<br />
80<br />
60<br />
40<br />
20<br />
8<br />
7<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
0<br />
PCL<br />
PCL<br />
Biopolyester<br />
Biopolyester<br />
PHF<br />
PHF<br />
PLA<br />
PLA<br />
PLA blends<br />
PLA blends<br />
Starch blends<br />
Starch blends<br />
Cellulose<br />
derivatives<br />
Cellulose<br />
derivatives<br />
PE-HD<br />
PE-HD<br />
PP<br />
PP<br />
ABS<br />
ABS<br />
PET<br />
PET<br />
PS<br />
PS<br />
PA 6<br />
PA 6<br />
Project development and results<br />
Throughout the project, different<br />
approaches were followed in the quest to<br />
achieve a material with the desired properties.<br />
Aimplas, with Addcomp and Avanzare<br />
contribution, developed a compound<br />
that is able to fulfill the requirements for<br />
automotive interior applications, including<br />
such aspects as thermal resistance, fogging,<br />
odour emissions, VOCs and antimicrobial<br />
resistance.<br />
The PLA blend formulation and the<br />
processing conditions were key factors<br />
that determined the performance of the<br />
materials, since it has been proven that<br />
crystallization of PLA plays a very important<br />
role in the thermal resistance of this<br />
material. It proved possible to increase the<br />
softening temperature from 57 °C to 102 °C,<br />
without compromising the viscosity of the<br />
material, which could then be processed by<br />
extrusion melt spinning in order to obtain<br />
the fibers.<br />
These fibers were succesfuly converted<br />
into fabrics and non-woven samples in order<br />
to obtain a final prototype of a moulded door<br />
panel. Two non-woven layers and a woven<br />
fabric were combined into a composite<br />
consisting of 100% bio-based material.<br />
www.biofibrocar.aitex.es<br />
www.aimplas.es<br />
Tensile strength (MPa)<br />
Vicat (°C)<br />
90<br />
80<br />
70<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
200<br />
180<br />
160<br />
140<br />
120<br />
100<br />
80<br />
60<br />
40<br />
PCL<br />
PCL<br />
Biopolyester<br />
Biopolyester<br />
PHF<br />
PHF<br />
PLA<br />
PLA<br />
PLA blends<br />
PLA blends<br />
Starch blends<br />
Starch blends<br />
Cellulose<br />
derivatives<br />
Cellulose<br />
derivatives<br />
PE-HD<br />
PE-HD<br />
PP<br />
PP<br />
ABS<br />
ABS<br />
PET<br />
PET<br />
PS<br />
PS<br />
PA 6<br />
PA 6<br />
bioplastics MAGAZINE [<strong>05</strong>/15] Vol. 10 17