Issue 05/2015
bioplasticsMAGAZINE_1505
bioplasticsMAGAZINE_1505
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Barrier<br />
The rate of moisture absorption in Plantic is controlled<br />
and limited due to the water resistance of the barrier skin<br />
materials. Independent tests have shown that the barrier<br />
performance remains below instrument detection limits<br />
(typically 0.<strong>05</strong> cm³/m 2 /day) for more than 7 days. Figure 2<br />
demonstrates this for a Plantic sample, equilibrated at<br />
75 % RH, and then exposed to 90 % RH. After 8 days there<br />
is no measurable change in the OTR, which remains below<br />
the instrument detection limit.<br />
The barrier performance of Plantic is even better at<br />
lower temperatures, as shown in figure 3. There is a factor<br />
of 3 decrease in the OTR at 50 % RH as the temperature<br />
is reduced from 20 °C to 5 °C. This is an important factor<br />
in the extended shelf life of fresh meat and poultry stored<br />
under refrigerated conditions.<br />
PLANTIC eco Plastic extends the shelf life of fresh<br />
food.<br />
Plantic have conducted a number of external trials<br />
at certified, independent laboratories to determine the<br />
actual shelf life of fresh meat, such as mince, chicken and<br />
fish compared to conventional polypropylene (PP) barrier<br />
trays currently used in the market. The same top web was<br />
used for all samples in both Plantic and PP trays.<br />
The results also indicated that samples packed in<br />
Plantic trays maintained the original colour for both<br />
chicken and sausage meat for longer than those packed<br />
in conventional PP trays. Shelf life extension was based<br />
on a combination of factors, including Total Plate Count,<br />
Coliform, pH, odour and colour assessment according to<br />
NATA regulations.<br />
The chicken packed in Plantic trays demonstrated a<br />
40 % increase in shelf life and sausage meat packed in<br />
eco Plastic trays demonstrated 15 % increase in shelf life.<br />
Both products maintained their originally packaged colour<br />
(less browning due to oxidation) for longer in eco Plastic<br />
trays than those packed in PP trays.<br />
www.kuraray.co.jp/en<br />
www.plantic.com.au<br />
3·25µ/m 2·day·atm]<br />
OTR [cm<br />
Figure 1: Effect of relative humidity on oxygen transmission rate for<br />
a selection of commercial barrier polymers.<br />
OTR cm 3 /m 2 /day<br />
100.0<br />
10.0<br />
1.0<br />
0.1<br />
0<br />
0.<strong>05</strong><br />
0.04<br />
0.03<br />
0.02<br />
0.01<br />
0<br />
-0.01<br />
-0.02<br />
0<br />
EVOH-32 %<br />
EVOH-44 %<br />
MXD6<br />
Plantic<br />
20 40 60 80 100<br />
% RH<br />
Specimen A, 0.46 mm<br />
Specimen B, 0.47 mm<br />
1 2 3 4 5 6 7 8<br />
Days after RH change<br />
Figure 2: Effect of a change in external relative humidity from 75 %<br />
to 90 % on the barrier performance of Plantic.<br />
(Test Method: ASTM F1927-98: 23 °C (± 0.2 °C),<br />
RH as specified ± 3 %, Test gas 100 % Oxygen)<br />
Table 1: Comparative barrier performance of packaging film<br />
materials.<br />
Material<br />
OTR<br />
cm³/m²/day<br />
25 µm, 23 °C, 50 % RH<br />
WVTR<br />
g/m²/day<br />
25 µm, 38 °C, 90 % RH<br />
LDPE 6,500 18<br />
HDPE 2,300 6<br />
PP 2,300 11<br />
PLA 600 300<br />
PVC 200 46<br />
PET 40 20<br />
Nylon 6 32 160<br />
MXD6 2.0 80<br />
PVDC 2.0 3<br />
EVOH 44 % 1.0 20<br />
EVOH 32 % 0.2 60<br />
Plantic 0.5 150<br />
Figure 3: Effect of temperature on the barrier performance of<br />
Plantic.<br />
OTR [cc·25µ/m 2·day·atm]<br />
1<br />
0.1<br />
0.01<br />
0<br />
5 °C<br />
10 °C<br />
15 °C<br />
20 °C<br />
20 40 60 80<br />
% RH<br />
bioplastics MAGAZINE [<strong>05</strong>/15] Vol. 10 41