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Barrier<br />

The rate of moisture absorption in Plantic is controlled<br />

and limited due to the water resistance of the barrier skin<br />

materials. Independent tests have shown that the barrier<br />

performance remains below instrument detection limits<br />

(typically 0.<strong>05</strong> cm³/m 2 /day) for more than 7 days. Figure 2<br />

demonstrates this for a Plantic sample, equilibrated at<br />

75 % RH, and then exposed to 90 % RH. After 8 days there<br />

is no measurable change in the OTR, which remains below<br />

the instrument detection limit.<br />

The barrier performance of Plantic is even better at<br />

lower temperatures, as shown in figure 3. There is a factor<br />

of 3 decrease in the OTR at 50 % RH as the temperature<br />

is reduced from 20 °C to 5 °C. This is an important factor<br />

in the extended shelf life of fresh meat and poultry stored<br />

under refrigerated conditions.<br />

PLANTIC eco Plastic extends the shelf life of fresh<br />

food.<br />

Plantic have conducted a number of external trials<br />

at certified, independent laboratories to determine the<br />

actual shelf life of fresh meat, such as mince, chicken and<br />

fish compared to conventional polypropylene (PP) barrier<br />

trays currently used in the market. The same top web was<br />

used for all samples in both Plantic and PP trays.<br />

The results also indicated that samples packed in<br />

Plantic trays maintained the original colour for both<br />

chicken and sausage meat for longer than those packed<br />

in conventional PP trays. Shelf life extension was based<br />

on a combination of factors, including Total Plate Count,<br />

Coliform, pH, odour and colour assessment according to<br />

NATA regulations.<br />

The chicken packed in Plantic trays demonstrated a<br />

40 % increase in shelf life and sausage meat packed in<br />

eco Plastic trays demonstrated 15 % increase in shelf life.<br />

Both products maintained their originally packaged colour<br />

(less browning due to oxidation) for longer in eco Plastic<br />

trays than those packed in PP trays.<br />

www.kuraray.co.jp/en<br />

www.plantic.com.au<br />

3·25µ/m 2·day·atm]<br />

OTR [cm<br />

Figure 1: Effect of relative humidity on oxygen transmission rate for<br />

a selection of commercial barrier polymers.<br />

OTR cm 3 /m 2 /day<br />

100.0<br />

10.0<br />

1.0<br />

0.1<br />

0<br />

0.<strong>05</strong><br />

0.04<br />

0.03<br />

0.02<br />

0.01<br />

0<br />

-0.01<br />

-0.02<br />

0<br />

EVOH-32 %<br />

EVOH-44 %<br />

MXD6<br />

Plantic<br />

20 40 60 80 100<br />

% RH<br />

Specimen A, 0.46 mm<br />

Specimen B, 0.47 mm<br />

1 2 3 4 5 6 7 8<br />

Days after RH change<br />

Figure 2: Effect of a change in external relative humidity from 75 %<br />

to 90 % on the barrier performance of Plantic.<br />

(Test Method: ASTM F1927-98: 23 °C (± 0.2 °C),<br />

RH as specified ± 3 %, Test gas 100 % Oxygen)<br />

Table 1: Comparative barrier performance of packaging film<br />

materials.<br />

Material<br />

OTR<br />

cm³/m²/day<br />

25 µm, 23 °C, 50 % RH<br />

WVTR<br />

g/m²/day<br />

25 µm, 38 °C, 90 % RH<br />

LDPE 6,500 18<br />

HDPE 2,300 6<br />

PP 2,300 11<br />

PLA 600 300<br />

PVC 200 46<br />

PET 40 20<br />

Nylon 6 32 160<br />

MXD6 2.0 80<br />

PVDC 2.0 3<br />

EVOH 44 % 1.0 20<br />

EVOH 32 % 0.2 60<br />

Plantic 0.5 150<br />

Figure 3: Effect of temperature on the barrier performance of<br />

Plantic.<br />

OTR [cc·25µ/m 2·day·atm]<br />

1<br />

0.1<br />

0.01<br />

0<br />

5 °C<br />

10 °C<br />

15 °C<br />

20 °C<br />

20 40 60 80<br />

% RH<br />

bioplastics MAGAZINE [<strong>05</strong>/15] Vol. 10 41

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