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60

t o t e l l t h e t r u t h

issue #6 ©

l i n k e d

61

Do you know ...

which came first:

the match

or the lighter?

Night-time in the prairie. A lonesome cowboy casually strikes a match against the

heel of his boot and holds the flame to his cigarette until a glowing red dot

appears. This classic Western scene could never have happened without a chance

discovery by an English pharmacist.

To find out why, we’ll head to Stockton-on-Tees, England. The year is 1826. John Walker,

renowned throughout the town for his extravagant clothing and excellent education,

spent a lot of time conducting chemical experiments. This particular November evening

he was busy mixing antimony-sulphide (a sulphur compound) and potassium chlorate with

gum arabic and starch. We don’t know for sure what he was trying to achieve.

What we do know is that some of the thick paste remained stuck to the little wooden stick

he was using to stir it. Perhaps absent-mindedly, perhaps irritated, he tried to scrape off

the residue along a rough surface. Suddenly, it burst into flame.

He soon saw a practical use for his discovery. He had little wooden sticks

manufactured in the local poorhouse and dipped one end into his

chemical kindling mixture. He sold them in his pharmacy together with

a little piece of sandpaper and called them “friction lights“.

No risk – no light?

Wooden sticks soaked in sulphur were already

used more than a thousand years

ago in ancient China to light fires in fireplaces

and hearths. Not long after that they

came to Europe. However, to get these to

ignite, you needed a spark plus a smouldering

“tinder fungus“. Later, a type of match

was invented with a white phosphorus

and potassium chloride head that would

only ignite when it was dipped into sulfuric

acid. To call this method “playing with fire”

wouldn’t be an exaggeration, since you had

to carry a little bottle of this dangerous liquid

around with you.

Walker’s “friction lights” are based on a different

principle. To ignite the mixture on the

head of the stick, frictional heat was sufficient.

Unfortunately, he neglected to register

a patent for his invention and his matches

were in any case technically flawed. For

one thing, they ignited very easily and were

therefore dangerous; for another, the unevenly

flickering flame gave off a vile smell

of sulphur.

That was why the Londoner Samuel Jones

gave the name “Lucifer” to the product

for which he registered a patent in 1828,

having plagiarised Walker’s discovery.

John Walker’s idea fired imaginations all

over the world. Everywhere chemists

started playing around with different mixtures.

Some of them experimented with –

extremely poisonous – white phosphorus.

Later this was replaced by red phosphorus.

Eventually, around twenty years after

the first “friction light” had seen the light

of day, the ignition and friction substances

were separated, and the handy “safety

matches” that we know today were born.

Walker’s strike-anywhere matches have

not entirely disappeared, though. To this

day, one can light these “cowboy matches”

on any rough surface. They still have

the igniting component in their heads.

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