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longitudinal dispersion in nonuniform isotropic porous media

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110<br />

deviations for these distributions may be assigned (as discussed for<br />

the gra<strong>in</strong> size distributions). The values of a SO for the uniform and<br />

<strong>nonuniform</strong> <strong>media</strong> are 0.0679mm and 0.074Smm, respectively. The nom<strong>in</strong>al<br />

geometric standard deviations for the uniform and <strong>nonuniform</strong> <strong>media</strong> are<br />

1.14 and 1.8S, respectively.<br />

When the sample has been dra<strong>in</strong>ed to its residual saturation, it 1S<br />

transferred from the Buchner funnel to a beaker. The sample is then<br />

weighed and placed <strong>in</strong> an oven to dry the sample completely. After<br />

dry<strong>in</strong>g, the sample is weighed. The weight loss dur<strong>in</strong>g dry<strong>in</strong>g<br />

determ<strong>in</strong>es the volume of water, V , conta<strong>in</strong>ed <strong>in</strong> the sample at residual<br />

w<br />

saturation. The residual saturation for both <strong>porous</strong> <strong>media</strong> is found to<br />

be about 10% of the total saturation volume. The dry weight of the<br />

sample gives the volume of sand, V s ' by assum<strong>in</strong>g the sand density to be<br />

2.6Sg/cc. The total porosity, 0 = V I(v + V ), 1S found to be 0.313<br />

wsw<br />

for the uniform medium and 0.291 for the <strong>nonuniform</strong> medium.<br />

To compute the cumulative probability distribution for pore S1zes<br />

accord<strong>in</strong>g to the frequency of occurrence, we follow a procedure similar<br />

to the analysis of the gra<strong>in</strong> size distribution. The measured<br />

distribution is <strong>in</strong>terpolated to provide the pore radii at 1000 equally<br />

spaced values <strong>in</strong> the cumulative distribution. For probabilities beyond<br />

the range of the experimentally determ<strong>in</strong>ed values, the radius is set to<br />

the maximum or m<strong>in</strong>imum pore size measured. The cumulative distribution<br />

for the occurrence of pore sizes accord<strong>in</strong>g to frequency 1S derived by<br />

not<strong>in</strong>g that (see equation (3.49))

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