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longitudinal dispersion in nonuniform isotropic porous media

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146<br />

of the required number of steps for the asymptotic <strong>dispersion</strong><br />

coefficient to apply to the actual average number of steps downstream<br />

to each of the probes <strong>in</strong>dicates that the experimental measurements have<br />

not been made sufficiently far downstream to reach this criterion for<br />

the asymptotic condition, particularly for the higher Pec1et number<br />

experiments. This fact may expla<strong>in</strong> the <strong>in</strong>crease <strong>in</strong> the calculated<br />

<strong>dispersion</strong> coefficient compared to measured values at the higher Pec1et<br />

numbers. It is difficult, however, to determ<strong>in</strong>e the necessary<br />

downstream distance for the <strong>longitud<strong>in</strong>al</strong> <strong>dispersion</strong> coefficient to<br />

approach the asymptotic value. This difficulty centers on the<br />

<strong>in</strong>ability to say what difference is expected between the asymptotic<br />

<strong>dispersion</strong> coefficient and measured <strong>dispersion</strong> coefficient when the<br />

asymptotic distance requirement is not met. In the Saffman (1959)<br />

model for uniform <strong>media</strong>, the relation derived for the "near-field"<br />

<strong>longitud<strong>in</strong>al</strong> <strong>dispersion</strong> coefficient shows a logarithmic growth <strong>in</strong> time.<br />

This type of slow variation <strong>in</strong> the <strong>dispersion</strong> coefficient would suggest<br />

that the measured <strong>dispersion</strong> coefficients will be close to the<br />

asymptotic value long before the asymptotic distance is reached.<br />

The discrepancy found at the higher Peclet numbers <strong>in</strong> Figure 5.3<br />

was not expected, based on the experimental results and theoretical<br />

predictions shown <strong>in</strong> Figure 2.5. In this figure, the asymptotic<br />

<strong>dispersion</strong> coefficient compares well over a range of Peclet numbers<br />

from 10 to 10 6 , although the typical experiment (us<strong>in</strong>g water) will lie<br />

outside Darcy's regime when Pe > 10 4 • Based on equation (3.23), the<br />

required number of steps at Peclet = 10 3 is n > 3.4x10 4 or a distance

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