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longitudinal dispersion in nonuniform isotropic porous media

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120<br />

When one fluid displaces another immiscibly, the <strong>in</strong>terface<br />

velocity (or seepage velocity, V ) is greater than the Darcy velocity.<br />

s<br />

This is caused by a portion of the cross section's be<strong>in</strong>g occupied by<br />

gra<strong>in</strong>s which reduces the available cross-sectional area for flow. The<br />

average areal porosity is known to be equal to the volumetric porosity<br />

(Bear, 1972), but flow takes place only <strong>in</strong> pores which <strong>in</strong>terconnect.<br />

Thus an effective porosity may be def<strong>in</strong>ed by,<br />

a = VD/V<br />

e s<br />

The difference <strong>in</strong> effective porosity to total porosity gives an<br />

estimate of the amount of fluid which is stagnant. If the miscible<br />

(4.3)<br />

displacement process follows advection-diffusion theory, the seepage<br />

velocity is equal to the velocity of the 50% concentration po<strong>in</strong>t<br />

(assum<strong>in</strong>g adsorption is not significant). Us<strong>in</strong>g the conductivity<br />

measurements, the velocity of the 50% concentration po<strong>in</strong>t is easily<br />

found. Table 4.4 shows the variation <strong>in</strong> average effective porosity<br />

between the top of the sand pack and each probe for both <strong>porous</strong><br />

materials. Experimental error for the effective porosity and total<br />

porosity measurements is ±l%. The effective porosity at the first<br />

probe, which measures over the top 7% of the column, is seen to be<br />

higher than subsequent porosities further down the column. This effect<br />

is most noticeable <strong>in</strong> the <strong>nonuniform</strong> medium, where the smaller gra<strong>in</strong>s<br />

tend to filter down,leav<strong>in</strong>g the top portion of the column with larger,<br />

more uniform gra<strong>in</strong> sizes. Porosities measured at the other two probes<br />

show more uniformity, as expected, s<strong>in</strong>ce these measurements average<br />

over a much greater portion of the column. Comparison of the average

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