longitudinal dispersion in nonuniform isotropic porous media
longitudinal dispersion in nonuniform isotropic porous media
longitudinal dispersion in nonuniform isotropic porous media
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181<br />
a change 1n source strength over an entire doma<strong>in</strong>, imply<strong>in</strong>g an <strong>in</strong>f<strong>in</strong>ite<br />
speed of signal propagation (Sundaresan, et al., 1980).<br />
B.l Ihg Breakthrough Problem<br />
A common experimental method for study<strong>in</strong>g <strong>longitud<strong>in</strong>al</strong> <strong>dispersion</strong><br />
is to displace a resident solution from a <strong>porous</strong> column by cont<strong>in</strong>ually<br />
<strong>in</strong>ject<strong>in</strong>g a solution of different solute concentration at the <strong>in</strong>let of<br />
the column (Rose and Passioura, 1971). The well-known breakthrough<br />
curve results when the change <strong>in</strong> concentration with time is measured at<br />
a particular <strong>longitud<strong>in</strong>al</strong> position along the column. Theoretical<br />
solutions to this problem have employed equation (B.1) along with<br />
appropriate <strong>in</strong>itial and boundary conditions. While the <strong>in</strong>itial<br />
condition poses no difficulty, a significant body of literature is<br />
devoted to the <strong>in</strong>terpretation of the boundary conditions (Pearson,<br />
1959; Werner and Wilhelm, 1956; Gershon and Nir, 1969; Choi and<br />
Perlmutter, 1976; Kreft and Zuber, 1978). The three physical doma<strong>in</strong>s<br />
to be <strong>in</strong>vestigated here are an <strong>in</strong>f<strong>in</strong>ite medium (- 00 < x < + 00), a semi-<br />
<strong>in</strong>f<strong>in</strong>ite medium (0 < x < + 00), and a f<strong>in</strong>ite medium (0 < x < L). The<br />
boundary conditions for the <strong>in</strong>f<strong>in</strong>ite medium are<br />
Lim c(x,t) = Co t > 0<br />
x -+-00<br />
Lim c(x, t) = c<br />
r<br />
x-+ oo<br />
t > 0<br />
(B.2)