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longitudinal dispersion in nonuniform isotropic porous media

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122<br />

proper boundary condition arises s<strong>in</strong>ce the <strong>in</strong>let chamber is a dist<strong>in</strong>ct<br />

physical system which should be considered for a complete solution.<br />

Mass transport <strong>in</strong> the <strong>in</strong>let chamber is not well understood, however,<br />

such that a complete model is not possible. Appendix B discusses the<br />

behavior of the solutions of equation (1.3) for miscible displacements<br />

accord<strong>in</strong>g to various boundary conditions. The important conclusion<br />

from Appendix B is that all of the solutions us<strong>in</strong>g the various boundary<br />

conditions are convergent to the same solution only a short distance<br />

downstream (Vsx/DL > 24). Therefore, to analyze the experimental data<br />

we will use the simpler solution for an <strong>in</strong>f<strong>in</strong>ite medium with the<br />

<strong>in</strong>itial condition<br />

C(x,O) = Co x < °<br />

C(x,O) = ° x > °<br />

In nondimensional form, this solution is (see Appendix B)<br />

where X = Vsx/DL' T = (V s )2t/DL and erfc is the complementary error<br />

function. Equation (4.4) may be used more conveniently <strong>in</strong> the<br />

follow<strong>in</strong>g form<br />

where d is the geometric mean gra<strong>in</strong> size and<br />

g<br />

(4.4)<br />

(4.5)

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