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longitudinal dispersion in nonuniform isotropic porous media

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20<br />

CHAPTER 2<br />

LITERATURE REVIEW<br />

Transport phenomena dur<strong>in</strong>g flow through <strong>porous</strong> <strong>media</strong> have been an<br />

active topic of research over the past 30 years. Dur<strong>in</strong>g this time,<br />

several dist<strong>in</strong>ct classes of <strong>porous</strong> <strong>media</strong> models have been developed.<br />

Consider<strong>in</strong>g the geometrical complexity of a <strong>porous</strong> medium, a crucial<br />

element <strong>in</strong> any model is the conceptual representation of the pore<br />

spaces. The different idealizations used to model a <strong>porous</strong> medium vary<br />

widely, rang<strong>in</strong>g from simple capillary models which bear little<br />

resemblance to a <strong>porous</strong> medium to statistical models <strong>in</strong> which the<br />

complex geometry is modeled through probability density functions.<br />

The results of this effort at model<strong>in</strong>g solute transport 1n <strong>porous</strong><br />

<strong>media</strong> are encourag<strong>in</strong>g but far from complete. The problem <strong>in</strong> this type<br />

of model<strong>in</strong>g appears to be a reluctance to use more detailed <strong>in</strong>formation<br />

on the pore structure to def<strong>in</strong>e the medium. This reluctance is<br />

understandable for two reasons:<br />

1. It is difficult to <strong>in</strong>corporate microscopic structural <strong>in</strong>formation<br />

<strong>in</strong>to a solute transport model, particularly if one is <strong>in</strong>terested <strong>in</strong><br />

eventually us<strong>in</strong>g a macroscopic model such as the advection-diffusion<br />

equation.<br />

2. Pore structural <strong>in</strong>formation 1S difficult to obta<strong>in</strong> and <strong>in</strong>terpret.<br />

Despite the limitations of the theoretical models reviewed here,<br />

they provide reasonably accurate predictions for mass transport 1n

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