C. Cohen-Tannoudji, B. Diu, F. Laloe, Quanten mechanics 1 & 2
C. Cohen-Tannoudji, B. Diu, F. Laloe, Quanten mechanics 1 & 2
C. Cohen-Tannoudji, B. Diu, F. Laloe, Quanten mechanics 1 & 2
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Stationary Solution<br />
assumption: H time independent ⇒ separation into<br />
time dependent and spatially dependent part:<br />
ψ (x, t) =f (t) ψ (x)<br />
(strange notation)<br />
Plugging into Schrödinger eqn.<br />
⇒<br />
i<br />
i ∂ ψ (x, t) =Hψ (x, t)<br />
∂t<br />
∂<br />
∂t f (t) ψ (x) =f (t) Hψ (x)<br />
⇒<br />
i ∂<br />
f (t) ∂t f (t)<br />
<br />
depends only on t<br />
= 1 Hψ (x)<br />
ψ (x)<br />
<br />
depends only on x<br />
= E (constant)<br />
⇒ i ∂ f (t) =Ef (t) ⇒ f (t) =e−iEt/<br />
∂t<br />
and<br />
Hψ (x) =Eψ (x, t)<br />
time independent Schrödinger equation<br />
ψ (x, t) =exp (−iEt/) ψ (x) arecalledstationarystates,<br />
since |ψ (x, t)| 2 = |ψ (x)| 2 is time independent.