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pigmented colorants: dependence on media and time - Cornell ...

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historically <strong>on</strong>e of the best grades of lim<strong>on</strong>ite, c<strong>on</strong>tains about 20% ir<strong>on</strong> oxide <strong>and</strong><br />

is high in silica. Ochres are am<strong>on</strong>g the most permanent hues <strong>on</strong> the palette <strong>and</strong><br />

absorb a medium amount of binder.<br />

Hematite. The native mineral hematite (also hæmatite) is essentially ferric<br />

oxide, occurring almost chemically pure (approximately 95%) without the presence<br />

of water. It has been a source of supply of for natural red pigments since the<br />

earliest classical <strong>and</strong> ancient <strong>time</strong>s–many other pigments are basically hematite<br />

with varying degrees of mineral impurities such as clay, chalk <strong>and</strong> silica. Natural<br />

red ir<strong>on</strong> oxides are mostly of dark hue <strong>and</strong> equally as permanent <strong>and</strong> dependable<br />

as those synthetically prepared. The high purity leads to high tinting strength<br />

<strong>and</strong> opacity. The red ir<strong>on</strong> oxides are am<strong>on</strong>g the basic, original pigments usually<br />

c<strong>on</strong>sidered indispensable–<strong>on</strong>e seldom sees a palette that does not c<strong>on</strong>tain at least<br />

<strong>on</strong>e of them.<br />

Cold hematite. Familiarly known as Caput mortem, this pigment includes small<br />

amounts of ir<strong>on</strong> sulfate <strong>and</strong> other impurities usually associated with hematite,<br />

giving the pigment a deep violet hue. It maintains the same qualities as hematite,<br />

as the c<strong>on</strong>centrati<strong>on</strong> of ferric oxide is comparable.<br />

Lampblack. This pigment is a black of commercially pure carb<strong>on</strong>. The finer<br />

varieties are obtained from wick lamps in which fluid fatty oils rich in carb<strong>on</strong> are<br />

burnt with insufficient air for complete combusti<strong>on</strong>. The soot is collected from<br />

plates held in the flame. Lampblack is a very str<strong>on</strong>g color, whose origin dates back<br />

to antiquity. It has c<strong>on</strong>siderable opacity, <strong>and</strong> is very stable <strong>and</strong> permanent. It is<br />

very fluffy, of a low specific gravity <strong>and</strong> absorbs a large porti<strong>on</strong> of binder.<br />

Titanium dioxide. This pigment is a development of the 20th century. It has<br />

148<br />

eclipsed other traditi<strong>on</strong>al white pigments due to its high opacity, n<strong>on</strong>toxic nature

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