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pigmented colorants: dependence on media and time - Cornell ...

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In summary, our implementati<strong>on</strong> provides a powerful tool in visualizati<strong>on</strong>. Pro-<br />

vided is a simple method for laying down paint of varying pigment c<strong>on</strong>centrati<strong>on</strong>s<br />

to see how they react under different c<strong>on</strong>diti<strong>on</strong>s–all of the variables can be modi-<br />

fied in real <strong>time</strong>. As computer processing improves, more wavelengths can be used<br />

in the lighting computati<strong>on</strong> to better simulate the spectral reflectance. As display<br />

technology improves, the gamut of displayable colors will also exp<strong>and</strong>, improving<br />

the c<strong>on</strong>diti<strong>on</strong>s for which the colors are viewed.<br />

7.1.3 Implementati<strong>on</strong> issues<br />

While this model is effective <strong>and</strong> can be computed in real <strong>time</strong>, there are some lim-<br />

itati<strong>on</strong>s to this theory of pigment modeling [Fis83, CAS + 97]. The model assumes<br />

the paint is homogeneous. In fact, pigment particles tend to clump into aggregates<br />

<strong>and</strong> often c<strong>on</strong>tain inclusi<strong>on</strong>s or impurities. Also, the scattering assumpti<strong>on</strong>s in the<br />

transport theory were based <strong>on</strong> uniformly sized spherical particles. This is rarely<br />

the case for pigment particles as they are often of widely varying shapes <strong>and</strong> sizes.<br />

Further, all colorant layers are immersed in <strong>media</strong> of the same refractive index.<br />

This assumpti<strong>on</strong> is violated at the interface between the air <strong>and</strong> paint <strong>and</strong> paint<br />

to substrate. A fairly simple correcti<strong>on</strong> term for reflecti<strong>on</strong> <strong>and</strong> refracti<strong>on</strong> at the<br />

paint’s surface has been proposed [JW75] that could be used to increase accuracy.<br />

While reas<strong>on</strong>ably accurate, Kubelka Munk theory is <strong>on</strong>ly as good as the mea-<br />

surements behind it. Therefore, for more accurate predicti<strong>on</strong> of color mixtures,<br />

many more mixtures of multiple pigments of varying c<strong>on</strong>centrati<strong>on</strong>s are necessary<br />

to obtain better absorpti<strong>on</strong> <strong>and</strong> scattering coefficients.<br />

In our work, <strong>on</strong>ly c<strong>on</strong>stant volume ratios of pigment-to-<strong>media</strong> are studied. In<br />

194<br />

paint, artists often manipulate the amount of binder <strong>and</strong> vehicle (as well as the

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