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Thermal properties in mesoscopics: physics and ... - ResearchGate

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that for a ”cross” system without the central wire (i.e.,<br />

R5 = 0), this term dom<strong>in</strong>ates V 0<br />

1/2 . Further corrections<br />

to the result (47) are discussed by Kogan et al. (2002)<br />

<strong>and</strong> Virtanen <strong>and</strong> Heikkilä (2004a).<br />

The above theoretical results expla<strong>in</strong> the observed<br />

magnitude <strong>and</strong> temperature dependence of the thermopower<br />

<strong>and</strong> also predict an <strong>in</strong>duced voltage oscillat<strong>in</strong>g<br />

with the phase φ. However, the thermopower calculated<br />

by Seviour <strong>and</strong> Volkov (2000b), Kogan et al. (2002) <strong>and</strong><br />

Virtanen <strong>and</strong> Heikkilä (2004a,b) is always an antisymmetric<br />

function of φ, <strong>and</strong> it vanishes for a vanish<strong>in</strong>g supercurrent<br />

<strong>in</strong> the junction (<strong>in</strong>clud<strong>in</strong>g all the correction<br />

terms). Therefore, the symmetric oscillations of α cannot<br />

be expla<strong>in</strong>ed with this theory.<br />

The presence of the supercurrent breaks the timereversal<br />

symmetry <strong>and</strong> hence the Onsager relation Π =<br />

T α (see Eqs. (39) <strong>and</strong> below) need not to be valid for<br />

φ = 0. Heikkilä, et al. predicted a nonequilibrium<br />

Peltier-type effect (Heikkilä et al., 2003) where the supercurrent<br />

controls the local effective temperature <strong>in</strong> an<br />

out-of-equilibrium normal-metal wire. However, it seems<br />

that the <strong>in</strong>duced changes are always smaller than those<br />

due to Joule heat<strong>in</strong>g <strong>and</strong> thus no real cool<strong>in</strong>g can be realized<br />

with this setup.<br />

Recently, the thermoelectric effects <strong>in</strong> coherent SNS<br />

Josephson po<strong>in</strong>t contacts have been analyzed <strong>in</strong> (Zhao<br />

et al., 2003, 2004). In such po<strong>in</strong>t contacts, the heat transport<br />

is strongly <strong>in</strong>fluenced by the Andreev bound states<br />

form<strong>in</strong>g between the two superconductors.<br />

G. Heat transport by phonons<br />

When the electrons are thermalized by the phonons,<br />

they may also heat or cool the phonon system <strong>in</strong> the film.<br />

Therefore, it is important to know how these phonons<br />

further thermalize with the substrate, <strong>and</strong> ultimately<br />

with the heat bath on the sample holder that is typically<br />

cooled via external means (typically by either a dilution<br />

or a magnetic refrigerator). Albeit slow electron-phonon<br />

relaxation often poses the dom<strong>in</strong>at<strong>in</strong>g thermal resistance<br />

<strong>in</strong> mesoscopic structures at low temperatures, the poor<br />

phonon thermal conduction itself can also prevent full<br />

thermal equilibration throughout the whole lattice. This<br />

is particularly the case when <strong>in</strong>sulat<strong>in</strong>g geometric constrictions<br />

<strong>and</strong> th<strong>in</strong> films separate the electronic structure<br />

from the bulky phonon reservoir (see Fig. 1). In the<br />

present section we concentrate on the thermal transport<br />

<strong>in</strong> the part of the cha<strong>in</strong> of Fig. 1 beyond the sub-systems<br />

determ<strong>in</strong>ed by electronic <strong>properties</strong> of the structure.<br />

The bulky three-dimensional bodies cease to conduct<br />

heat at low temperatures accord<strong>in</strong>g to the well appreciated<br />

κ ∝ T 3 law <strong>in</strong> crystall<strong>in</strong>e solids aris<strong>in</strong>g from Debye<br />

heat capacity via<br />

κ = CvSℓel,ph/3, (49)<br />

where κ is the thermal conductivity <strong>and</strong> C is the heat capacity<br />

per unit volume, vS is the speed of sound <strong>and</strong> ℓel,ph<br />

15<br />

is the mean free path of phonons <strong>in</strong> the solid (Ashcroft<br />

<strong>and</strong> Merm<strong>in</strong>, 1976). <strong>Thermal</strong> conductivity of glasses follows<br />

the universal ∝ T 2 law, as was discovered by Zeller<br />

<strong>and</strong> Pohl (1971), which dependence is approximately followed<br />

by non-crystall<strong>in</strong>e materials <strong>in</strong> general (Pobell,<br />

1996). These laws are to be contrasted to ∝ T thermal<br />

conductivities of pure normal metals (Wiedemann-Franz<br />

law, c.f., below Eq. (39)). Despite the rapid weaken<strong>in</strong>g<br />

of thermal conductivity toward low temperatures, the dielectric<br />

materials <strong>in</strong> crystall<strong>in</strong>e bulk are relatively good<br />

thermal conductors. One important observation here is<br />

that the absolute value of the bulk thermal conductivity<br />

<strong>in</strong> clean crystall<strong>in</strong>e <strong>in</strong>sulators at low temperatures does<br />

not provide the full basis of thermal analysis without a<br />

proper knowledge of the geometry of the structure, because<br />

the mean free paths often exceed the dimensions<br />

of the structures. For example, <strong>in</strong> pure silicon crystals,<br />

measured at sub-kelv<strong>in</strong> temperatures (Klitsner <strong>and</strong> Pohl,<br />

1987), thermal conductivity κ 10 Wm −1 K −4 T 3 , heat<br />

capacity C 0.6 JK −4 m −3 T 3 <strong>and</strong> velocity vS 5700<br />

m/s imply by Eq. (49) a mean free path of 10 mm,<br />

which is more than an order of magnitude longer than the<br />

thickness of a typical silicon wafer. Therefore phonons<br />

tend to propagate ballistically <strong>in</strong> silicon substrates.<br />

What makes th<strong>in</strong>gs even more <strong>in</strong>terest<strong>in</strong>g, but at the<br />

same time more complex, e.g., <strong>in</strong> terms of practical<br />

thermal design, is that at sub-kelv<strong>in</strong> temperatures the<br />

dom<strong>in</strong>ant thermal wavelength of the phonons, λph <br />

hvS/kBT , is of the order of 0.1 µm, <strong>and</strong> it can exceed<br />

1 µm at the low temperature end of a typical experiment<br />

(see discussion <strong>in</strong> Subs. II.C.2). A direct consequence of<br />

this fact is that the phonon systems <strong>in</strong> mesoscopic samples<br />

cannot typically be treated as three-dimensional, but<br />

the sub-wavelength dimensions determ<strong>in</strong>e the actual dimensionality<br />

of the phonon gas. Metallic th<strong>in</strong> films <strong>and</strong><br />

narrow th<strong>in</strong> film wires, but also th<strong>in</strong> dielectric films <strong>and</strong><br />

wires are to be treated with constra<strong>in</strong>ts due to the conf<strong>in</strong>ement<br />

of phonons <strong>in</strong> reduced dimensions.<br />

The issue of how thermal conductivity <strong>and</strong> heat capacity<br />

of th<strong>in</strong> membranes <strong>and</strong> wires get modified due to<br />

geometrical constra<strong>in</strong>ts on the scale of the thermal wavelength<br />

of phonons has been addressed by several authors<br />

experimentally (Holmes et al., 1998; Leivo <strong>and</strong> Pekola,<br />

1998; Woodcraft et al., 2000) <strong>and</strong> theoretically (see, e.g.,<br />

(Anghel et al., 1998; Kuhn et al., 2004)). The ma<strong>in</strong> conclusion<br />

is that structures with one or two dimensions<br />

d < λph restrict the propagation of (ballistic) phonons<br />

<strong>in</strong>to the rema<strong>in</strong><strong>in</strong>g ”large” dimensions, <strong>and</strong> thereby reduce<br />

the magnitude of the correspond<strong>in</strong>g quantities κ <strong>and</strong><br />

C at typical sub-kelv<strong>in</strong> temperatures, but at the same<br />

time the temperature dependences get weaker.<br />

In the limit of narrow short wires at low temperatures<br />

the phonon thermal conductance gets quantized, as was<br />

experimentally demonstrated by Schwab et al. (2000).<br />

This limit had been theoretically addressed by Angelescu<br />

et al. (1998), Rego <strong>and</strong> Kirczenow (1998) <strong>and</strong> Blencowe<br />

(1999), somewhat <strong>in</strong> analogy to the well-known L<strong>and</strong>auer<br />

result on electrical conduction through quasi-one-

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